Skip to main content

Solvent-Free Extraction: Myth or Reality?

  • Chapter
  • First Online:
Alternative Solvents for Natural Products Extraction

Part of the book series: Green Chemistry and Sustainable Technology ((GCST))

Abstract

One of the many environmental challenges faced by Extraction field is the widespread use of organic solvents. With a solvent based extraction the solvent necessarily has to be separated from the final extract. A large number of these solvents are toxic that pose a risk to workers and community members and virtually all of them are classified as volatile organic compounds (VOCs) that contribute to smog. In this context, the development of solvent-free extraction processes is of great interest in order to modernize classical processes making them cleaner, safer and easier to perform. This chapter presents a picture of current knowledge on innovative solvent-free methods of natural products extraction. It provides the necessary theoretical background and some details about extraction using the most innovative, rapid and green techniques such as microwaves, instant controlled pressure drop (DIC) process and Pulsed Electric Field (PEF): the technique, the mechanism and some applications.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 54.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Wan PJ, Hron RJ, Dowd MK, Kuk MS, Conkerton EJ (1995) Alternative hydrocarbon solvents for cottonseed extraction: plant trials. J Am Oil Chem Soc 72:661–664

    Article  CAS  Google Scholar 

  2. Hanmoungjai P, Pyle L, Niranjan K (2000) Extraction of rice bran oil using aqueous media. J Chem Technol Biotechnol 75:348–352

    Article  CAS  Google Scholar 

  3. Gedye R, Smith F, Westaway K, Ali H, Baldisera L, Laberge L, Rousell J (1986) Tetrahedron Lett 27:279–282

    Article  CAS  Google Scholar 

  4. Ganzler K, Salgó A, Valkó K (1986) J Chromatogr A 371:299–306

    Article  CAS  Google Scholar 

  5. Chemat F, Abert Vian M, Visinoni F (2010) Microwave hydro-diffusion for isolation of natural products. United States Patent, US 0,062,121

    Google Scholar 

  6. Abert Vian M, Fernandez X, Visioni F, Chemat F (2008) Microwave hydrodiffusion and gravity, a new technique for extraction of essential oils. J Chromatogr A 1190:14–17

    Article  Google Scholar 

  7. Bousbia N, AbertVian M, Ferhat MA, Meklati BY, Chemat F (2009) A new process for extraction of essential oil from citrus peels: microwave hydrodiffusion and gravity. J Food Eng 90:409–413

    Article  Google Scholar 

  8. Bousbia N, AbertVian M, Ferhat MA, Peticolas E, Meklati BY, Chemat F (2009) Comparison of two isolation methods for essential oil from rosemary leaves: hydrodistillation and microwave hydrodiffusion and gravity. Food Chem 14:355–362

    Article  Google Scholar 

  9. Zill-e-Huma M, Abert-Vian JF, Maingonnat FC (2009) Clean recovery of antioxidant flavonoids from onions: optimising solvent free microwave extraction method. J Chromatogr A 1216:7700–7707

    Article  CAS  Google Scholar 

  10. Zill-e-Huma, Abert-Vian M, Fabiano-Tixier AS, Elmaataoui M, Dangles O, Chemat F (2011) A remarkable influence of microwave extraction: enhancement of antioxidant activity of extracted onion varieties. Food Chem 127:1472–1480

    Article  CAS  Google Scholar 

  11. Périno-Issartier S, Zill-e-Huma, Abert-Vian M, Chemat F (2010) Solvent free microwave-assisted extraction of antioxidants from sea buckthorn (Hippophae rhamnoides) food by-products. Food Bioprocess Technol 4:1020–1028

    Article  Google Scholar 

  12. Allaf K, Vidal P (1989) Feasibility study of a new process of drying/swelling by instantaneous decompression toward vacuum of in pieces vegetables in view of a rapid re-hydration. Gradient Activity Plotting, University of Technology of Compiegne UTC N° CR/89/103, industrial SILVA-LAON partner

    Google Scholar 

  13. Allaf K, Louka N, Parent F, Bouvier J, Forget M (1999) Method for processing materials to change their texture, apparatus therefor, and resulting materials. United States Patent, US 5,855,941

    Google Scholar 

  14. Ben Amor B, Allaf K (2009) Impact of texturing using instant pressure drop treatment prior to solvent extraction of anthocyanins from Malaysian Roselle (Hibiscus sabdariffa). Food Chem 115(3):820–825

    Google Scholar 

  15. Amor BB, Lamy C, Andre P, Allaf K (2008) Effect of instant controlled pressure drop treatments on the oligosaccharides extractability and microstructure of Tephrosia purpurea seeds. J Chromatogr A 1213(2):118–124

    Article  Google Scholar 

  16. Berka-Zougali B, Hassani A, Besombes C, Allaf K (2010) Extraction of essential oils from Algerian myrtle leaves using instant controlled pressure drop technology. J Chromatogr A 1217(40):6134–6142

    Article  CAS  Google Scholar 

  17. Besombes C, Berka-Zougali B, Allaf K (2010) Instant controlled pressure drop extraction of lavandin essential oils: fundamentals and experimental studies. J Chromatogr A 1217(44):6807–6815

    Article  CAS  Google Scholar 

  18. Kristiawan M, Sobolik V, Allaf K (2008) Isolation of Indonesian cananga oil using multi-cycle pressure drop process. J Chromatogr A 1192:306–318

    Article  CAS  Google Scholar 

  19. Allaf T, Allaf K (2014) Instant controlled pressure drop (D.I.C.) in food processing. Springer, New York

    Book  Google Scholar 

  20. Puértolas E, López N, Condón S, Álvarez I, Raso J (2010) Potential applications of PEF to improve red wine quality. Trends Food Sci Technol 21(5):247–255

    Article  Google Scholar 

  21. Grimi N, Praporscic I, Lebovka N, Vorobiev E (2007) Selective extraction from carrot slices by pressing and washing enhanced by pulsed electric fields. Sep Purif Technol 58(2):267–273

    Article  CAS  Google Scholar 

  22. Toepfl S, Heinz V, Knorr D (2005) Overview of pulsed electric field processing for food. In: Emerging technologies for food processing. Academic, London, pp 69–97

    Chapter  Google Scholar 

  23. Corrales M, Toepfl S, Butz P, Knorr D, Tauscher B (2008) Extraction of anthocyanins from grape by-products assisted by ultrasonics, high hydrostatic pressure or pulsed electric fields: a comparison. Innov Food Sci Emerg Technol 9(1):85–91

    Article  CAS  Google Scholar 

  24. Lebovka N, Vorobiev E, Chemat F (eds) (2011) Enhancing extraction processes in the food industry. CRC Press, Cambridge

    Google Scholar 

  25. Vorobiev E, Lebovka N (eds) (2008) Electrotechnologies for extraction from food plants and biomaterials. Springer, New York

    Google Scholar 

  26. Jaeger H, Schulz A, Karapetkov N, Knorr D (2009) Protective effect of milk constituents and sublethal injuries limiting process effectiveness during PEF inactivation of Lb. rhamnosus. Int J Food Microbiol 134(1–2):154–161

    Article  CAS  Google Scholar 

  27. Roodenburg B, Morren J, (Iekje) Berg HE, de Haan SWH (2005) Metal release in a stainless steel pulsed electric field (PEF) system: part II. The treatment of orange juice; related to legislation and treatment chamber lifetime. Innov Food Sci Emerg Technol 6(3):337–345

    Article  CAS  Google Scholar 

  28. Roodenburg B et al (2010) Conductive plastic film electrodes for Pulsed Electric Field (PEF) treatment – a proof of principle. Innov Food Sci Emerg Technol 11(2):274–282

    Article  CAS  Google Scholar 

  29. Grimi N, Lebovka NI, Vorobiev E, Vaxelaire J (2009) Effect of a pulsed electric field treatment on expression behavior and juice quality of chardonnay grape. Food Biophys 4(3):191–198

    Article  Google Scholar 

  30. Loginova KV, Shynkaryk MV, Lebovka NI, Vorobiev E (2010) Acceleration of soluble matter extraction from chicory with pulsed electric fields. J Food Eng 96(3):374–379

    Article  Google Scholar 

  31. Schilling S et al (2007) Effects of pulsed electric field treatment of apple mash on juice yield and quality attributes of apple juices. Innov Food Sci Emerg Technol 8(1):127–134

    Article  CAS  Google Scholar 

  32. Boussetta N, Lebovka N, Vorobiev E, Adenier H, Bedel-Cloutour C, Lanoisellé J-L (2009) Electrically assisted extraction of soluble matter from chardonnay grape skins for polyphenol recovery. J Agric Food Chem 57(4):1491–1497

    Article  CAS  Google Scholar 

  33. Turk MF, Baron A, Vorobiev E (2010) Effect of pulsed electric fields treatment and mash size on extraction and composition of apple juices. J Agric Food Chem 58(17):9611–9616

    Article  CAS  Google Scholar 

  34. Puértolas E, Saldaña G, Alvarez I, Raso J (2010) Effect of pulsed electric field processing of red grapes on wine chromatic and phenolic characteristics during aging in oak barrels. J Agric Food Chem 58(4):2351–2357

    Article  Google Scholar 

  35. Loginova KV, Vorobiev E, Bals O, Lebovka NI (2011) Pilot study of countercurrent cold and mild heat extraction of sugar from sugar beets, assisted by pulsed electric fields. J Food Eng 102(4):340–347

    Article  Google Scholar 

  36. Yin Y, Cui Y, Ding H (2008) Optimization of betulin extraction process from Inonotus Obliquus with pulsed electric fields. Innov Food Sci Emerg Technol 9(3):306–310

    Article  CAS  Google Scholar 

  37. Guderjan M, Tepfl S, Angersbach A, Knorr D (2005) Impact of pulsed electric field treatment on the recovery and quality of plant oils. J Food Eng 67(3):281–287

    Article  Google Scholar 

  38. Fincan M, DeVito F, Dejmek P (2004) Pulsed electric field treatment for solid-liquid extraction of red beetroot pigment. J Food Eng 64(3):381–388

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Farid Chemat .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Vian, M.A., Allaf, T., Vorobiev, E., Chemat, F. (2014). Solvent-Free Extraction: Myth or Reality?. In: Chemat, F., Vian, M. (eds) Alternative Solvents for Natural Products Extraction. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-43628-8_2

Download citation

Publish with us

Policies and ethics