Abstract
Undoubtedly, the advanced green composites have replaced the use of many conventional mineral based or naturally occurring single materials in wide spread industrial applications including aerospace, automotive, locomotive, chemical and biomedical industries. Specially, the reinforced natural rubber nanocomposites have drawn the attention of the research as well as industrial worlds greatly because of their superior thermal and mechanical properties without major compromise of transperancy/clarity. This chapter presents the preparation of rubber nanocomposites, characterization techniques, and the properties of the developed nanocomposites such as mechanical and thermal characteristics along with the recent applications of these nanocomposites. The rubber nanocomposite (RNC) have found their niche commercially in the tyre and sports industries providing reduced weight and energy dissipation, and enhanced air retention to the applied products.
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References
Ahmed K (2015) Hybrid composites prepared from Industrial waste: Mechanical and swelling behavior. J Adv Res 6(2):225–232
Ahmed K, Nizami SS (2014) Reinforcement of natural rubber hybrid composites based on marble sludge/Silica and marble sludge/rice husk derived silica. J Adv Res 5(2):165–173
Ajayan PM, Stephan O, Colliex C, Trauth D (1994) Aligned carbon nanotube arrays formed by cutting a polymer resin-nanotube composite. Science 265:1212–1214
Al-Hartomy OA, Al-Ghamdi AA, Al-Salamy F, Dishovsky N, Slavcheva D, El-Tantawy F (2012) Properties of natural rubber-based composites containing fullerene. Int J Polym Sci, Article ID 967276, 8 p
Anand KA, Jose TS, Alex R, Joseph R, Anoop AK, Sunil JT, Rosamma A, Rani J (2010) Natural rubber-carbon nanotube composites through latex compounding. Int J Polym Mater 59:33–44
Anoop AK, Jose S, Alex TR, Joseph R (2009) Natural rubber-carbon nanotube composites through latex compounding. Int J Polym Mater 59:33–44
Atieh MA, Girun N, Mahdi ES, Tahir H, Guan CT, Alkhatib MF, Ahmadun FR, Baik DR (2006) Effect of multi-wall carbon nanotubes on the mechanical properties of natural rubber. Fuller Nanotub Carbon Nanostruct 14:641–649
Atieh MA, Nazir N, Yusof F, Fettouhi M, Ratnam CT, Alharthi M, Abu-Ilaiwi F, Mohammed K, Al-Amer A (2010) Fuller Nanotub Carbon Nanostruct 18:56–71
Aziz AA, Ismail NI, Su M NS, Rusop CM (2012) Characterization of functionalized multi-walled carbon nanotubes in pre-vulcanized natural rubber latex. AIP Conf Proc 1455:124–130
Bahl K, Miyoshi T, Jana SC (2014) Hybrid fillers of lignin and carbon black for lowering of viscoelastic loss in rubber compounds. Polymer 55(16):3825–3835
Baik J, Kang S-J, Hwang H-N, Hwang C-C, Kim K-J, Kim B, An K-S, Park C-Y, Shin H-J (2012) Chemical functionalization of epitaxial graphene on SiC using tetra(4-carboxyphenyl)porphine. Surf Sci 606:481–484
Barrie CL, Griffiths PC et al (2004) Rheology of aqueous carbon black dispersions. J Colloid Interface Sci 272(1):210–217
Becerril HA, Mao J, Liu Z, Stoltenberg RM, Bao Z, Chen Y (2008) Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2(3):463–470
Bethune DS, Klang CH, de Vries MS, Gorman G, Savoy R, Vazquez J, Beyers R (1993) Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls. Nature 363(6430):605–607
Bhattacharyya AR, Sreekumar TV, Liu T, Kumar S, Ericson LM, Hauge RH, Smalley RE (2003) Crystallization and orientation studies in polypropylene/single wall carbon nanotube composite. Polymer 44(8):2373–2377
Bhattacharyyaa S, Sinturela C, Bahloula O, Saboungia M, Thomas S, Salvetata J (2008) Improving reinforcement of natural rubber by networking of activated carbon nanotubes. Carbon 46:1037–1045
Bin YZ, Kitanaka M, Zhu D, Matsuo M (2003) Development of highly oriented polyethylene filled with aligned carbon nanotubes by Gelation/Crystallization from solutions. Macromolecules 36(16):6213–6219
Birkett PR et al (1992) Preparation and characterization of C 60Br 6 and C 60Br 8. Nature 357(6378):479–481
Bokobza L, Belin C (2007) Effect of strain on the properties of a styrene-butadiene rubber filled with multiwall carbon nanotubes. J Appl Polymer Sci 105(4):2054–2061
Bokobza L, Kolodziej M (2006) On the use of carbon nanotubes as reinforcing fillers for elastomeric materials. Polymer Int 55(9):1090–1098
Broda J (2003) Polymorphism in Polypropylene Fibers. J Appl Polym Sci 89(12):3364–3370
Brodie BC (1859) Philos Trans R Soc Lon 149:249–259
Bubert H, Haiber S, Brandl W, Marginean G, Heintze M, Brüser V (2003) Characterization of the uppermost layer of plasma-treated carbon nanotubes. Diam Relat Mater 12(3–7):811–815
Bunshah RF, Jou S, Prakash S, Doerr HJ, Isaacs L, Wehrsig A, Yeretzian C, Cynn H, Diederich F (1992) Fullerene formation in sputtering and electron beam evaporation processes. J Phys Chem 96(17):6866–6869
Buseck PR, Tsipursky SJ, Hettich R (1992) Fullerenes from the geological environment. Science 257(5067):215–217
Calixto CMF, Mendes RK, deOliveira AC, Ramos LA, Cervini P, Cavalheiro ÉTG (2007) Development of graphite-polymer composites as electrode materials. Mater Res 10(2):109–114
Cami J, Bernard-Salas J, Peeters E, Malek SE (2010) Detection of C60 and C70 in a young planetary nebula. Science 329(5996):1180–1182
Cataldo F (2000) The role of fullerene-like structures in carbon black and their interaction with dienic rubber. Fuller Sci Technol 8(1–2):105–112
Cataldo F (2005) Fullerene-like structures as interaction sites between carbon black and rubber. Macromol Symp 228(1):91–98
Cataldo F, Abbati G, Santini A, Padella F (2003) Evidences of rubber grafting on activated carbon surfaces containing fullerene like structures. Fuller Nanotub Carbon Nanostruct 11(4):395–408
Chai Y, Guo T, Jin C, Haufler RE, Felipe Chibante LP, Fure J, Lihong Wang J, Alford M, Smalley RE (1991) Fullerenes with metals inside. J Phys Chem 95(20):7564–7568
Chen XH, Song H-H (2004) Multi walled carbon nanotubes filled SBR rubber composites. New Carbon Mater 19:214–218
Chen J, Hamon MA, Hu H, Chen Y, Rao AM, Eklund PC, Haddon RC (1998) Solution properties of single-walled carbon nanotubes. Science 282:95–98
Chen GZ, Shaffer MSP, Coleby D, Dixon G, Zhou W, Fray DJ, Windle AH (2000) Carbon nanotube and polypyrrole composites: Coating and doping. Adv Mater 12(7):522–526
Chen S, Yu H, Ren W, Zhang Y (2009) Thermal degradation behavior of hydrogenated nitrile-butadiene rubber (HNBR)/clay nanocomposite and HNBR/clay/carbon nanotubes nanocomposites. Thermochim Acta 491:103–108
Chibante LPF, Andreas Thess JM, Alford MD, Diener RE, Smalle RE (1993) Solar generation of the fullerenes. J Phys Chem 97(34):8696–8700
Chow L (1994) CVD method of producing and doping of fullerene. U.S. Patent, 5, 510, 098
Coleman JN, Khan U, Gun’ko YK (2006a) Mechanical reinforcement of polymers using carbon nanotubes. Adv Mater 18:689–705
Coleman JN, Khan U, Blau WJ, Gun’ko YK (2006b) Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44:1624–1652
Das A, Stöckelhuber KW, Jurk R, Fritzsche J, Klüppel M, Heinrich G (2009) Coupling activity of ionic liquids between diene elastomers and multi-walled carbon nanotubes. Carbon 47:3313–3321
De Falco A, Goyanes S, Rubiolo GH, Mondragon I, Marzocca A (2007) Carbon nanotubes as reinforcement of styrene-butadiene rubber. Appl Surf Sci 254(1):262–265
Deng J, Ding X, Zhang W, Peng Y, Wang J, Long X, Li P, Chan ASC (2002) Carbon nanotube-polyaniline hybrid materials. Eur Polym J 38:2497–2501
Dror Y, Salalha W, Khalfin RL, Cohen Y, Yarin AL, Zussman E (2003) Carbon nanotubes embedded in oriented polymer nanofibers by electrospinning. Langmuir 19(17):7012–7020
Dua V, Surwade SP, Ammu S, Agnihotra SR, Jain S, Roberts KE, Park S, Ruoff RS, Manohar SK (2010) All-organic vapor sensor using inkjet-printed reduced graphene oxide. Angew Chem Int Ed 49(12):2154–2157
Eitan A, Jiang K, Dukes D, Andrews R, Schadler LS (2003) Surface modification of multiwalled carbon nanotubes: toward the tailoring of the interface in polymer composites. Chem Mater 15(16):3198–3201
Emery JD, Wang QH, Zarrouati M, Fenter P, Hersam MC, Bedzyk MJ (2011) Structural analysis of PTCDA monolayers on epitaxial graphene with ultra-high vacuum scanning tunneling microscopy and high-resolution X-ray reflectivity. Surf Sci 605:1685–1693
Endo M, Noguchi T, Ito M, Takeuchi K, Hayashi T, Kim YA, Wanibuchi T, Jinnai H, Terrones M, Dresselhaus MS (2008) Extreme-performance rubber nanocomposites for probing and excavating deep oil resources using multi-walled carbon nanotubes. Adv Funct Mater 18:3403–3409
Eswaraiah V, Jyothirmayee AS, Ramaprabhu SS (2011) Top down method for synthesis of highly conducting graphene by exfoliation of graphite oxide using focused solar radiation. J Mater Chem 21:6800–6803
Fakhru’l-Razi A, Atieh MA, Girun N, Chuah TG, Sadig E-S, Biak DRA (2006) Effect of multi-wall carbon nanotubes on the mechanical properties of natural rubber. Compos Struct 75(1–4):496–500
Fan Z-J, Kai W, Yan J, Wei T, Zhi L-J, Feng J, Yue-ming R, Li-Ping S, Wei F (2010) Facile synthesis of graphene nanosheets via Fe reduction of exfoliated graphite oxide. ACS Nano 5(1):191–198
Fanga Q, Song B, Tee T-T, Sin LT, Hui D, Bee S-T (2014) Investigation of dynamic characteristics of nano-size calcium carbonate added in natural rubber vulcanizate. Compos B Eng 60:561–567
Fields CL, Pitts JR, Hale MJ, Bingham C, Lewandowski A, King DE (1993) Formation of fullerenes in highly concentrated solar flux. J Phy Chem 97(34):8701–8702
Foelske-Schmitz A, Weingarth D, Kötz R (2011) Quasi in situ XPS study of electrochemical oxidation and reduction of highly oriented pyrolytic graphite in [1-ethyl-3-methylimidazolium][BF4] electrolytes. Electrochim Acta 56:10321
Fowler PW, Ceulemans A (1995) Electron deficiency of the fullerenes. J Phy Chem 99(2):508–510
Fu X, Qutubuddin S (2001) Polymer–clay nanocomposites: exfoliation of organophilic montmorillonite nanolayers in polystyrene. Polymer 42(2):807–813
Ganguli S, Roy AK, Anderson DP (2008) Improved thermal conductivity for chemically functionalized exfoliated graphite/epoxy composites. Carbon 46:806–817
Gao W, Alemany LB, Ci LJ, Ajayan PM (2009) New insights into the structure and reduction of graphite oxide. Nat Chem 1(5):403–408
Gao X, Jang J, Nagase S (2010) Hydrazine and thermal reduction of graphene oxide: reaction mechanisms, product structures, and reaction design. J Phys Chem C 114:832–842
Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183
Girun N, Ahmadun FR, Rashid SA, Atieh MA (2007) Multi-wall carbon nanotubes/styrene butadiene rubber (SBR) nanocomposite. Fuller Nanotub Carbon Nanostruct 15(3):207–214
Gong X, Liu J, Baskaran S, Voise RD, Young S (2000) Surfactant-assisted processing of carbon nanotube/polymer composites. Chem Mater 12:1049–1052
Gong L, Kinloch IA, Young RJ, Riaz I, Jalil R, Novoselov KS (2010) Interfacial stress transfer in a graphene monolayer nanocomposite. Adv Mater 22:2694–2697
Gorga RE, Cohen RE (2004) Toughness enhancements in poly(methyl methacrylate) by Addition of oriented multiwall carbon nanotube. J Polym Sci Part B Polym Phys 42(14):2690–2702
Grunlan JC, Kim YS, Ziaee S, Wei X, Abdel-Magid B, Tao K (2006) Thermal and mechanical behavior of carbon-nanotube-filled latex. Macromol Mater Eng 291:1035–1043
Hare JP, Kroto HW, Taylor R (1991) Preparation and UV/visible spectra of fullerenes C60 and C70. Chem Phys Lett 177:394–398
Hirsch A (2009) Unzipping carbon nanotubes: A peeling method for the formation of graphene nanoribbons. Ang Chem Int Ed 48:6594–6596
Iijima S (1980) Direct observation of the tetrahedral bonding in graphitized carbon black by high resolution electron microscopy. J Cryst Growth 50(3):675–683
Iijima S (1991) Helical microtubules of graphite carbon. Nature 354:56–58
Iijima S, Ichihashi T (1993) Single-shell carbon nanotubes of 1-nm diameter. Nature 363(6430):603–605
Iwasa Y (2010) Superconductivity: Revelations of the fullerenes. Nature 466(7303):191–192
Jacob M, Thomas S, Varughese KT (2004) Natural rubber composites reinforced with sisal/oil palm hybrid fibers: Tensile and cure characteristics. J Appl Polym Sci 93(5):2305–2312
Jacob M, Varughese KT, Thomas S (2006) Dielectric characteristics of sisal–oil palm hybrid biofibre reinforced natural rubber biocomposites. J Mater Sci 41(17):5538–5547
Jada A, Ridaoui H, Vidal L, Donnet J-B (2014) Control of carbon black aggregate size by using polystyrene-polyethylene oxide non ionic diblock copolymers. Coll Surf A 458:187–194
Jang J, Bae J, Yoon SH (2003) A study on the effect of surface treatment of carbon nanotubes for liquid crystalline epoxide-carbon nanotube composites. J Mater Chem 13(4):676–681
Jeong H-K, Lee YP, Jin MH, Kim ES, Bae JJ, Lee YH (2009) Thermal stability of graphite oxide. Chem Phys Lett 470(4):255–258
Jia Z, Wang Z, Xu C, Liang J, We B, Wu D, Zhu S (1999) Study on poly(methyl methacrylate)/carbon nanotube composites. Mater Sci Eng 271:395–400
Jung H, Yang SJ, Kim T, Kang JH, Park CR (2013) Ultrafast room-temperature reduction of graphene oxide to graphene with excellent dispersibility by lithium naphthalenide. Carbon 63:165–174
Jurkowska B, Jurkowski B, Kamrowski P, Pesetskii SS, Koval VN, Pinchuk LS, Olkhov YA (2006) Properties of fullerene-containing natural rubber. J Appl Polym Sci 100(1):390–398
Kai W, Hirota Y, Hua L, Inoue Y (2008) Thermal and mechanical properties of a poly(ϵ-caprolactone)/graphite oxide composite. J Appl Polym Sci 107(3):1395–1400
Kalaitzidou K, Fukushima H, Drzal LT (2007) A new compounding method for exfoliated graphite polypropylene nanocomposites with enhances flexural properties and lower percolation threshold. Compos Sci Technol 67:2045–2051
Kamath G, Baker GA (2012) In silico free energy predictions for ionic liquid-assisted exfoliation of a graphene bilayer into individual graphene nanosheets. Phys Chem Chem Phys 14:7929
Kanking S, Niltui P, Wimolmala E, Sombatsompop N (2012) Use of bagasse fiber ash as secondary filler in silica or carbon black filled natural rubber compound. Mater Des 41:74–82
Khalid M, Ismail AF, Ratnam CT, Faridah Y, Rashmi W, Al Khatib MF (2010) Effect of radiation dose on the properties of natural rubber nanocomposite. Radiat Phys Chem 79:1279–1285
Kim YA, Hayashi T, Endo M, Gotoh Y, Wada N, Seiyama J (2006) Fabrication of aligned carbon nanotube-filled rubber composite. Scr Mater 54:31–35
Kim D, Yang SJ, Kim YS, Jung H, Park CR (2012a) Simple and costeffective reduction of graphite oxide by sulfuric acid. Carbon 50(9):3229–3232
Kim TA, Kim HS, Lee SS, Park M (2012b) Single-walled carbon nanotube/silicone rubber composites for compliant electrodes. Carbon 50:444–449
Kinloch AJ, Mohammed RD et al (2005) The effect of silica nano particles and rubber particles on the toughness of multiphase thermosetting epoxy polymers. J Mater Sci 40(18):5083–5086
Kohjiya S, Ikeda Y (eds) (2014) Chemistry, manufacture and applications of natural rubber. Elsevier Science, Amsterdam
Kolodziej M, Bokobza L, Bruneel JL (2007) Investigations on natural rubber filled with multiwall carbon nanotubes. Compos Interfaces 14(3):215–228
Kratschmer W (1990) Solid C60: a new form of carbon. Nature 347(6291):354–358
Kroto HW, Heath JR, O’Brien SC, Curl RF, Smalley RE (1985) C60: Buckminsterfullerene. Nature 318:162–163
Kueseng K, Jacob KI (2006) Natural rubber nanocomposites with SiC nanoparticles and carbon nanotubes. Eur Polym J 42(1):220–227
Li Y, Shimizu H (2007) High-shear processing induced homogenous dispersion of pristine multiwalled carbon nanotubes in a thermoplastic elastomer. Polymer 48(8):2203–2207
Li X, Magnuson CW, Venugopal A, Tromp RM, Hannon JB, Vogel EM, Colombo L, Ruoff RS (2011) Large-area graphene single crystals grown by lowpressure chemical vapor deposition of methane on copper. J Am Chem Soc 133:2816
Lopez-Manchado MA, Biagiotti J, Valentini L, Kenny JM (2004) Dynamic mechanical and raman spectroscopy studies on interaction between single-walled carbon nanotubes and natural rubber. J Appl Polym Sci 92(5):3394–3400
Lv R, Cui T, Jun MS, Zhang Q, Cao A, Su DS, Zhang Z, Yoon SH, Miyawaki J, Mochida I, Kang F (2011) Open-ended N-doped carbon nanotube–graphene hybrid nanostructures as high-performance catalyst support. Adv Funct Mater 21:999
Masenelli-Varlot K, Chazeau L, Gauthier C, Bogner A, Cavaillé JY (2009) The relationship between the electrical and mechanical properties of polymer-nanotube composites and their microstructure. Compos Sci Technol 69:1533–1539
Matos CF, Galembeck F, Zarbin Aldo JG (2012) Multifunctional materials based on iron/iron oxide-filled carbon nanotubes/natural rubber composites. Carbon 50:4685–4695
Mitchell CA, Bahr JL, Arepalli S, Tour JM, Krishnamoorti R (2002) Dispersion of functionalized carbon nanotubes in polystyrene. Macromolecules 35:8825–8830
Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205
Muszynski R, Seger B, Kamat P (2008) Decorating graphene sheets with gold nanoparticles. J Phys Chem C 2008(112):5263–5266
Nair KP, Thomas P, Joseph R (2012) Latex stage blending of multiwalled carbon nanotube in carboxylated acrylonitrile butadiene rubber: Mechanical and electrical properties. Mater Des 41:23–30
Nazlia G, Fakhru’l-Razi A, Suraya AR, Muataz AA (2007) Multi-wall carbon nanotubes/styrene butadiene rubber (SBR) nanocomposite. Fuller Nannotub Carbon Nanostruct 15:207–214
Nomani MWK, Shishir R, Qazi M, Diwan D, Shields VB, Spencer MG, Tompa GS, Sbrockey NM, Koley G (2010) Highly sensitive and selective detection of NO2 using epitaxial graphene on 6H-SiC. Sens Actuators B Chem 150:301–307
Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197
Park S, An J, Jung I, Piner RD, An SJ, Li X, Velamakanni A, Ruoff RS (2009) Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents. Nano Lett 9:1593–1597
Park JH, Mitchel WC, Grazulis L, Eyink K, Smith HE, Hoelscher JE (2011a) Role of extended defected SiC interface layer on the growth of epitaxial graphene on SiC. Carbon 49:631–635
Park S, An J, Potts JR, Velamakann A, Murali S, Ruoff RS (2011b) Hydrazine-reduction of graphite and graphene oxide. Carbon 49:3019–3023
Paul DR, Robeson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49:3187–3204
Pei S, Zhao J, Du J, Ren W, Cheng H-M (2010) Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon 48(15):4466–4474
Peng Z, Feng C, Luo Y, Li Y, Kong LX (2010) Self-assembled natural rubber/multi-walled carbon nanotube composites using latex compounding techniques. Carbon 48:4497–4503
Petcu S, Cauchetier M, Armand X, Voicu I, Alexandrescu R (2000) Formation of fullerenes in the laser-pyrolysis of benzene. Combust Flame 122(4):500–507
Peters G, Jansen M (1992) A new fullerene synthesis. Angew Chem Int Ed Engl 31(2):223–224
Potschke P, Fornes TD, Paul DR (2002) Rheological behaviors of multiwalled carbon nanotube/polycarbonate composites. Polymer 43:3247–3255
Potts JR, Shankar O, Du L, Ruoff RS (2012) Processing–morphology–property relationships and composite theory analysis of reduced graphene oxide/natural rubber nanocomposites. Macromolecules 45:6045–6055
Potts JR, Shankar O, Murali S, Du L, Ruoff RS (2013) Latex and two-roll mill processing of thermally-exfoliated graphite oxide/natural rubber nanocomposites. Compos Sci Technol 74:166–172
Praveen S, Chattopadhyay PK, Albert P, Dalvi VG, Chakraborty BC, Chattopadhyay S (2009) Synergistic effect of carbon black and nanoclay fillers in styrene butadiene rubber matrix: Development of dual structure. Compos A Appl Sci Manuf 40(3):309–316
Prud’Homme RK, Ozbas B, Aksay IA, Register RA, Adamson DH (2010) Functional graphene-rubber nanocomposites. WO 2008045778 A1
Qian D, Dickey EC, Andrews R, Rantell T (2000) Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites. Appl Phys Lett 76(20):2868–2870
Rafiee MA, Rafiee J, Wang Z, Song HH, Yu ZZ, Koratkar N (2009) Enhanced mechanical properties of nanocomposites at low graphene content. ACS Nano 3(12):3884–3890
Rattanasom N, Saowapark T, Deeprasertkul C (2007) Reinforcement of natural rubber with silica/carbon black hybrid filler. Polym Testing 26(3):369–377
Reina A, Jia X, Ho J, Nezich D, Son H, Bulovic V, Dresselhaus MS, Kong J (2009) Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett 9(1):30–35
Reznikova LL, Smorygo LN, Tikhomirov AF, Ol’shevskij OI (1992) Electric conducting rubber for computer hardware. Elektrotekhnika 6(7):65–66
Ruoff RS, Tse DS, Malhotra R, Lorents DC (1993) Solubility of fullerene (C60) in a variety of solvents. J Phys Chem 97(13):3379–3383
Safadi B, Andrews R, Grulke EA (2002) Multiwalled carbon nanotube polymer composites: synthesis and characterization of thin films. J Appl Polym Sci 84(14):2660–2669
Scott LT (2004) Methods for the chemical synthesis of fullerenes. Angew Chem Int Ed 43(38):4994–5007
Scotti R, Conzatti L, D’Arienzo M, Di Credico B, Giannini L, Hanel T, Stagnaro P, Susanna A, Tadiello L, Morazzoni F (2014) Shape controlled spherical (0D) and rod-like (1D) silica nanoparticles in silica/styrene butadiene rubber nanocomposites: Role of the particle morphology on the filler reinforcing effect. Polymer 55(6):1497–1506
Shaffer MSP, Windle AH (1999) Fabrication and characterization of carbon nanotube/poly(vinyl alcohol) composites. Adv Mater 11:937–941
Shaffer MSP, Fan X, Windle AH (1998) Load transfer in carbon nanotube epoxy composites. Carbon 36:1603–1612
Shang NG, Papakonstantinou P, Sharma S, Lubarsky G, Li M, McNeill DW, Quinn AJ, Zhou W, Blackley R (2012) Controllable selective exfoliation of highquality graphene nanosheets and nanodots by ionic liquid assisted grinding. Chem Commun 48:1877
Shanmugharaj AM, Bae JH, Lee KY, Noh WH, Lee SH, Ryu SH (2007) Physical and chemical characteristics of multiwalled carbon nanotubes functionalized with aminosilane and its influence on the properties of natural rubber composites. Compos Sci Technol 67(9):1813–1822
Si Y, Samulski ET (2008) Synthesis of water soluble graphene. Nano Lett 8:1679–1682
Siochi EJ, Working DC, Park C, Lillehei PT, Rouse JH, Topping CC, Bhattacharyya AR, Kumar S (2004) Melt processing of SWCNT-polyimide nanocomposite fibers. Compos Part B Eng 35(5):439–446
Stankovich S, Dikin DA, Dommett Geoffrey H B, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS (2006) Graphene-based composite materials. Nature 442:282–286
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45(7):1558–1565
Star A, Stoddart JF, Steuerman D, Diehl M, Boukai A, Wong EW, Yang X, Chung S-W, Choi H, Heath JR (2001) Preparation and properties of polymer-wrapped single-walled carbon nanotubes. Angew Chem Int Ed 40:1721–1725
Staudenmaier L (1898) Verfahren zur darstellung der graphitsaure. Ber Dtsch Chem Ges 31:1481–1487
Steurer P, Wissert R, Thomann R, Mulhaupt R (2009) Functionalized graphenes and thermoplastic nanocomposites based upon expanded graphite oxide. Macromol Rapid Commun 30(4–5):316–327
Subramaniam K, Das A, Heinrich G (2011) Development of conducting polychloroprene rubber using imidazolium based ionic liquid modified multiwalled carbon nanotubes. Compos Sci Technol 71:1441–1449
Sui G, Zhong W, Yang X, Zhao S (2007) Processing and material characteristics of a carbon-nanotube-reinforced natural rubber. Macromol Mater Eng 292(9):1020–1026
Sui G, Zhong W, Yang X, Zhao SH (2008a) Curing kinetics and mechanical behavior of natural rubber reinforced with pretreated carbon nanotubes. Mater Sci Eng A 485:524–531
Sui G, Zhong W, Yang X, Yu H, Zhao SH (2008b) Preparation and properties of natural rubber composites reinforced with pretreated carbon nanotubes. Polym Adv Technol 19:1543–1549
Taguet A, Cassagnau P (2014) Structuration, selective dispersion and compatibilizing effect of (nano)fillers in polymer blends. Prog Polym Sci 39(8):1526–1563
Tang WZ, Santare MH, Advani SG (2003) Melt processing and mechanical property characterization of multi-walled carbon nanotube/high density polyethylene (MWNT/ HDPE) composite films. Carbon 41(14):2779–2785
Taylor R, Langley GJ, Kroto HW, Walton DRM (1993) Formation of C60 by pyrolysis of naphthalene. Nature 366(6457):728–731
Terrill ER, Centea M, Evans LR, MacIsaac JD Jr (2010). Dynamic mechanical properties of passenger and light truck tire treads. Akron Rubber Development Laboratory, Inc., Transportation Research Center Inc., National Highway Traffic Safety Administration. Report No. DOT HS 811 270
Terrones M, Botello-Méndez AR, Campos-Delgado J, López-Urías F, Vega-Cantú YI, Rodríguez-Macías FJ, Elías AL, Muñoz-Sandoval E, Cano-Márquez AG, Charlier J-C, Terrones H (2010) Graphene and graphite nanoribbons: Morphology, properties, synthesis, defects and applications. Nano Today 5:351–372
Thomas S, Stephen R (2010) Rubber Nanocomposites: Preparation, Properties and Applications. Wiley, New York
Thostenson ET, Li C, Chou TW (2005) Nanocomposites in context. Compos Sci Technol 65:491–516
Thrower AP (1999) Editorial. Carbon 37(11):1677–1678
Tian M, Cheng L, Liang W, Liqun Z (2006) Overall properties of fibrillar silicate/styrene–butadiene rubber nanocomposites. J Appl Polym Sci 101(5):2725–2731
Tung VC, Allen MJ, Yang Y, Kaner RB (2009) High-throughput solution processing of large-scale graphene. Nat Nanotechnol 4(1):25–29
van der Merwe EM, Prinsloo LC, Mathebula CL, Swart HC, Coetsee E, Doucet FJ (2014) Surface and bulk characterization of an ultrafine South African coal fly ash with reference to polymer applications. Appl Surf Sci 317:73–83
Vandervorst P, Lei CH, Lin Y, Dupont O, Dalton AB, Sun YP, Keddie JL (2006) The fine dispersion of functionalized carbon nanotubes in acrylic latex coatings. Prog Org Coat 57:91–97
Wang JD, Zhu YF, Zhou XW, Sui G, Liang J (2006) Preparation and mechanical properties of natural rubber powder modified by carbon nanotubes. J Appl Polym Sci 100(6):4697–4702
Wang G, Yang J, Park J, Gou X, Wang B, Liu H (2008) Facile synthesis and characterization of graphene nanosheets. J Phys Chem C 112(22):8192–8195
Wang P, Geng S, Ding T (2010a) Effects of carboxyl radical on electrical resistance of multi-walled carbon nanotube filled silicone rubber composite under pressure. Compos Sci Technol 70:1571–1573
Wang D, Fujinami S, Nakajima K, Niihara K, Inukai S, Ueki H, Magario A, Noguchi T, Endo M, Nishi T (2010b) Production of a cellular structure in carbon nanotube/natural rubber composites revealed by nanomechanical mapping. Carbon 48:3708–3714
Wang D, Fujinami S, Nakajima K, Niihara K, Inukai S, Ueki H, Magario A, Noguchi T, Endo M, Nishi T (2010c) Visualization of nanomechanical mapping on polymer nanocomposites by AFM force measurement. Polymer 51:2455–2459
Wang X, Fulvio PF, Baker GA, Veith GM, Unocic RR, Mahurin SM, Chi M, Dai S (2010d) Direct exfoliation of natural graphite into micrometre size few layers graphene sheets using ionic liquids. Chem Commun 46:4487
Wu J, Huang G, Li H, Wu S, Liu Y, Zheng J (2013) Enhanced mechanical and gas barrier properties of rubber nanocomposites with surface functionalized graphene oxide at low content. Polymer 54:1930–1937
Xiao Q, He S, Liu L, Guo X, Shi K, Du Z, Zhang B (2008) Coating of multiwalled carbon nanotubes with crosslinked silicon-containing polymer. Compos Sci Technol 68:321–328
Yadav BC, Kumar R (2008) Structure, properties and applications of fullerene. Int J Nanotechnol Appl 2:15–24
Yoshie K-i, Kasuya S, Eguchi K, Yoshida T (1992) Novel method for C60 synthesis: A thermal plasma at atmospheric pressure. Appl Phys Lett 61(23):2782–2783
Zhan Y, Wu J, Xia H, Yan N, Fei G, Yuan G (2011) Dispersion and exfoliation of graphene in rubber by an ultrasonically-assisted latex mixing and in situ reduction process. Macromol Mater Eng 296(7):590–602
Zhang W, Cui J, Tao C-A, Wu Y, Li Z, Ma L, Wen Y, Li G (2009) A strategy for producing pure single-layer graphene sheets based on a confined self-assembly approach. Angew Chem Int Ed 48:5864–5868
Zhang HB, Zheng WG, Yan Q, Yang Y, Wang JW, Lu ZH, Ji GY, Yu ZZ (2010) Electrically conductive polyethylene terephthalate/graphene nanocomposites prepared by melt compounding. Polymer 51:1191–1196
Zhao Q, Tannenbaum R, Jacob KJ (2006) Carbon nanotubes as Raman sensors of vulcanization in natural rubber. Carbon 44(9):1740–1745
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Khalid, M., Ratnam, C.T., Walvekar, R., Ketabchi, M.R., Hoque, M.E. (2017). Reinforced Natural Rubber Nanocomposites: Next Generation Advanced Material. In: Jawaid, M., Salit, M., Alothman, O. (eds) Green Biocomposites. Green Energy and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-49382-4_14
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