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Nitrile Rubber Latex Blends: Preparation, Characterization and Applications

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Rubber Nano Blends

Part of the book series: Springer Series on Polymer and Composite Materials ((SSPCM))

Abstract

Latex blending of desired rubbers with the objective of obtaining an optimized combination of properties is an important research topic in the field of rubber science and technology. This chapter aims to provide an overview of the recent advances toward the development of the nitrile rubber latex-based blends, starting from a general introduction of different types of rubbers commonly used in the rubber latex blending process. Different blend combinations between the nitrile rubber latex and other types of rubber latexes or nanofillers are then reviewed. This is followed by a summary of techniques used for the preparation of rubber latex blends. Next, the characterization of rubber latex blends is presented. Finally, the applications of nitrile rubber latex blends are summarized.

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Abbreviations

ATR:

Attenuated Total Reflection

CBS:

Cyclohexyl Benzthiazyl

CCD:

Charged-Coupled Device

CR:

Chloroprene Rubber

DCA:

Dicholoroacetic Acid

DLS:

Dynamic Light Scattering

DMTA:

Dynamic Mechanical Thermal Analyzer

DRC:

Dry Rubber Content

DSC:

Differential Scanning Calorimetry

DTG:

Derivative Thermogravimetric Analysis

EPDM:

Ethylene Propylene Diene Terpolymer

FTIR:

Fourier Transform Infrared Spectroscopy

GR-N:

Government Rubber-Nitrile

HNBR:

Hydrogenated Nitrile Rubber

HXNBR:

Hydrogenated Carboxylated Nitrile Rubber

MBTS:

Dibenzthiazyl Disulphide

MWCNT:

Multiwalled Carbon Nanotube

Na-MMT:

Sodium Montmorillonite

NBR:

Acrylonitrile–Butadiene Rubber

NR:

Natural Rubber

OMLS:

Organically Modified Layered Silicate

PCN:

Polymer–Clay Nanocomposites

Phr:

Parts Per Hundred Rubber

PVC:

Polyvinyl Chloride

SBR:

Styrene–Butadiene Rubber

SDBS:

Sodium Dodecyl Benzene Sulphonate

SEM:

Scanning Electron Microscopy

SNRL:

Skim Natural Rubber Latex

SR:

Synthetic Rubber

TEM:

Transmission Electron Microscopy

TG:

Thermogravimetry

Tg:

Glass Transition Temperatures

TGA:

Thermogravimetric Analysis

TMQ:

2,2,4-Trimethyl-1,2-Dihydroquinoline

TMTD:

Tetramethyl Thiuram Disulphide

XNBR:

Carboxylated Nitrile Rubber

XRD:

X-Ray Diffraction

References

  1. Wang H, Yang L, Rempel GL (2013) Homogeneous hydrogenation art of nitrile butadiene rubber: a review. Polym Rev 53:192–239

    Article  CAS  Google Scholar 

  2. Hofmann’s Successors. LANXESS. Retrieved from http://lanxess.cn/en/about-lanxess-china/100-years-synthetic-rubber/history-of-synthetic-rubber-cn/hofmann-successors-china/

  3. Nitrile rubber (NBR) (2015) Encyclopaedia Britannica. Retrieved from http://www.britannica.com/technology/nitrile-rubber

  4. Styrene-butadiene rubber (SBR) (2015) Encyclopaedia Britannica. Retrieved from http://www.britannica.com/science/styrene-butadiene-rubber

  5. Musch R, Magg H (2008) 1 Polychloroprene. In: Klingender RC (ed) Handbook of specialty elastomers. CRC Press, Boca Raton, p 15

    Google Scholar 

  6. Keller RW (2008) Hydrogenated nitrile rubber (Chapter 3). In: Klingender RC (2008) Handbook of specialty elastomers. CRC Press, Boca Raton, p 94

    Google Scholar 

  7. Han Y, Su L, Mao L, Zhang L, Yue D (2014) Self-cross-linking hydrogenated nitrile-butadiene rubber latex/polyvinyl chloride emulsion composite film and its properties. Polym Plast Technol Eng 53:306–311

    Article  CAS  Google Scholar 

  8. Keller RW (2008) Hydrogenated nitrile rubber (Chapter 3). In: Klingender RC (2008) Handbook of specialty elastomers. CRC Press, Boca Raton, p 95

    Google Scholar 

  9. Wang H, Rempel GL (2015) Aqueous-phase catalytic hydrogenation of unsaturated polymers. Catal Today 247:117–123

    Article  CAS  Google Scholar 

  10. Laskowska A, Zaborski M, Boiteux G, Gain O, Maniukiewicz W (2014) Ionic elastomers based on carboxylated nitrile rubber (XNBR) and magnesium aluminum layered double hydroxide. eXPRESS. Polym Lett 8:374–386

    Article  CAS  Google Scholar 

  11. Mousa A, Heinrich G, Simon F, Wagenknecht U, Stöckelhuber KW, Dweiri R (2012) Carboxylated nitrile butadiene rubber/hybrid filler composites. Mater Res 15:671–678

    Article  CAS  Google Scholar 

  12. Krynac. LANXESS. Retrieved from http://lanxess.in/en/industries-products-india/industries-india/other-india/krynac-india/

  13. Therban XT. LANXESS. Retrieved from http://therban.com/en/technical-information/carboxylated-technology/

  14. Guo S, von Hellens W, Campomizzi EC, Ferrari L (2003) Therban XT boosts abrasion resistance, adhesion. Rubber Plast News 1–5

    Google Scholar 

  15. Greve H-H (2012) Rubber, 2. Natural. Ullmann’s encyclopedia of industrial chemistry. In: Ullmann’s encyclopedia of industrial chemistry, vol 31, 8th edn. VCH, Weinheim, Germany, p 584

    Google Scholar 

  16. Kew Royal Botanical Gardens. Hevea Brasiliensis (rubber tree). Retrieved from http://www.kew.org/science-conservation/plants-fungi/hevea-brasiliensis-rubber-tree

  17. Greve H-H (2012) Rubber, 2. Natural. Ullmann’s encyclopedia of industrial chemistry. In: Ullmann’s encyclopedia of industrial chemistry, vol 31, 8th edn. VCH, Weinheim, Germany, pp 583–594

    Google Scholar 

  18. Threadingham D, Obrecht W, Wieder W, Wachholz G, Engehausen R (2012) Rubber, 3. Synthetic rubbers, introduction and overview. In: Ullmann’s encyclopedia of industrial chemistry, vol 31, 8th edn. VCH, Weinheim, Germany, pp 597–616

    Google Scholar 

  19. Obrecht W, Lambert JP, Happ M, Oppenheimer-Stix C, Dunn J, Krüger R (2012) Rubber, 4. Emulsion rubbers. In: Ullmann’s encyclopedia of industrial chemistry, vol 31, 8th edn. VCH, Weinheim, Germany, pp 623–646

    Google Scholar 

  20. Neoprene CR (2015) Encyclopaedia Britannica. Retrieved from http://www.britannica.com/science/neoprene

  21. Fischer I, Schmitt WF, Porth H-C, Allsopp MW, Vianello G (2014) Poly(vinyl chloride). Ullmann’s encyclopedia of industrial chemistry, pp 1–30

    Google Scholar 

  22. Moonprasith N, Suchiva K, Tongcher O (2006) Blending in latex form of natural rubber and nitrile latices: a preliminary study of morphology and mechanical properties. In: Material technical seminar, Thailand

    Google Scholar 

  23. Sotiropoulou DD, Avramidou OE, Kalfoglou NK (1993) Property-composition dependence of hydrogenated poly (butadiene-co-acrylonitrile)/poly (vinyl chloride) blends. Polymer 34:2297–2301

    Article  CAS  Google Scholar 

  24. Paul DR, Robeson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49:3187–3204

    Article  CAS  Google Scholar 

  25. Hwang WG, Wei KH, Wu CM (2004) Preparation and mechanical properties of nitrile butadiene rubber/silicate nanocomposites. Polymer 45:5729–5734

    Article  CAS  Google Scholar 

  26. Kader MA, Kim K, Lee YS, Nah C (2006) Preparation and properties of nitrile rubber/montmorillonite nanocomposites via latex blending. J Mater Sci 41:7341–7352

    Article  CAS  Google Scholar 

  27. Sirisinha C, Baulek-Limcharoen S, Thunyarittikorn J (2001) Relationships among blending conditions, size of dispersed phase, and oil resistance in natural rubber and nitrile rubber blends. J Appl Polym Sci 82:1232–1237

    Article  CAS  Google Scholar 

  28. Zhang JP, Liao PQ, Zhou HL, Lin RB, Chen XM (2014) Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers. Chem Soc Rev 43:5789–5814

    Article  CAS  Google Scholar 

  29. Dettinger U, Egelhaaf HJ, Brabec CJ, Latteyer F, Peisert H, Chassé T (2015) FTIR study of the impact of PC [60] BM on the photodegradation of the low band gap polymer PCPDTBT under O2 environment. Chem Mater 27:2299–2308

    Article  CAS  Google Scholar 

  30. Chakraborty S, Bandyopadhyay S, Ameta R, Mukhopadhyay R, Deuri AS (2007) Application of FTIR in characterization of acrylonitrile-butadiene rubber (nitrile rubber). Polym Testing 26:38–41

    Article  CAS  Google Scholar 

  31. Nair KP, Thomas P, Joseph R (2012) Latex stage blending of multiwalled carbon nanotube in carboxylated acrylonitrile butadiene rubber: mechanical and electrical properties. Mater Des 41:23–30

    Article  Google Scholar 

  32. Mailer AG, Clegg PS, Pusey PN (2015) Particle sizing by dynamic light scattering: non-linear cumulant analysis. J Phys Condens Matter 27:145102

    Article  Google Scholar 

  33. Alex R, Nah C (2006) Studies on natural rubber/acrylonitrile butadiene rubber/organoclay nanocomposites. Plast Rubber Compos 35:219–225

    Article  CAS  Google Scholar 

  34. Ohya N, Tanaka Y, Wittisuwannakul R, Koyama T (2000) Activity of rubber transferase and rubber particle size in Hevea latex. J Rubber Res 3:214–221

    CAS  Google Scholar 

  35. Singh AP, Wi SG, Chung GC, Kim YS, Kang HS (2003) The micromorphology and protein characterization of rubber particles in Ficus carica, Ficus benghalensis and Hevea brasiliensis. J Experim Bot 54:985–992

    Article  CAS  Google Scholar 

  36. Haines PJ (2012) Thermogravimetry. In: Thermal methods of analysis: principles, applications and problems. Springer Science & Business Media, Berlin, pp 22–62

    Google Scholar 

  37. Proetto MT, Rush AM, Chien M, Baeza PA, Patterson JP, Thompson MP, Olson NH, Moore CE, Rheingold A, Andolina CM, Millstone JE, Howell S, Browning ND, Evans JE, Gianneschi NC (2014) Dynamics of soft nanomaterials captured by transmission electron microscopy in liquid water. J Am Chem Soc 136:1162–1165

    Article  CAS  Google Scholar 

  38. Hughes L, Hawes C, Monteith S, Vaughan S (2014) Serial block face scanning electron microscopy-the future of cell ultrastructure imaging. Protoplasma 251:395–401

    Article  Google Scholar 

  39. Nah C, Ryu HJ, Han SH, Rhee JM, Lee MH (2001) Fracture behaviour of acrylonitrile-butadiene rubber/clay nanocomposite. Polym Int 50:1265–1268

    Article  CAS  Google Scholar 

  40. Lewan MV (1998) NR/NBR blends—compounding for food contact applications. In: Tinker AJ, Jones KP (eds) Blends of natural rubber. Chapman & Hall, London, pp 94–105

    Google Scholar 

  41. Perera MCS, Ishiaku US, Ishak ZAM (2000) Thermal degradation of PVC/NBR and PVC/ENR50 binary blends and PVC/ENR50/NBR ternary blends studied by DMA and solid state NMR. Polym Degrad Stab 68:393–402

    Article  CAS  Google Scholar 

  42. Noriman NZ, Ismail H (2013) Effect of carbon black/silica hybrid filler on thermal properties, fatigue life, and natural weathering of SBR/recycled NBR blends. Int J Polym Mater Polym Biomater 62:252–259

    Article  CAS  Google Scholar 

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Correspondence to Garry L. Rempel or Hui Wang .

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Rempel, G.L., Wang, H. (2017). Nitrile Rubber Latex Blends: Preparation, Characterization and Applications. In: Markovic, G., P. M., V. (eds) Rubber Nano Blends. Springer Series on Polymer and Composite Materials. Springer, Cham. https://doi.org/10.1007/978-3-319-48720-5_3

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