Skip to main content

Abstract

Bottom blown oxygen copper smelting process, operated at high grade matte (up to 75 wt% Cu) with relatively low (2–3 wt%) Cu in slag, has been commercialized for more than five years at Dongying Fangyuan Nonferrous Metals CO., Ltd. Quenched slag and matte samples have been collected at different operating conditions while the slag temperature was measured by thermocouple. The samples were analysed by X-ray Fluorescence and Electron Probe X-ray Microanalysis. FactSage computational software was used to explain the observations of the industrial samples. The analyses show that the copper loss was closely related to the operation parameters. The Fe/SiO2 in slag and temperature determine the solid proportion, which significantly affects the physical entrained and also chemically dissolved copper in the slag. The present study will be useful in understanding the slag chemistry of bottom blown copper smelting furnace and in optimization of the operating conditions to lower Cu loss in the slag.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 239.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. B. Zhao, Z. Cui, and Z. Wang. “A New Copper Smelting Technology — Bottom Blown Oxygen Furnace Developed at Dongying Fangyuan Nonferrous Metals.” (4th International Symposium on High-Temperature Metallurgical Processing, San Antonio, US, 2013), 3–10.

    Google Scholar 

  2. C. Bale, E. Bélisle, P. Chartrand, S.A. Degterov, G. Eriksson, K. Hack, I.H. Jung, Y.B. Kang, J. Melançon, and A.D. Pelton. “FactSage Thermochemical Software and Databases — Recent Developments.” Calphad, 33(2), 2009: 295–311.

    Article  Google Scholar 

  3. R. Roscoe. “The Viscosity of Suspensions of Rigid Spheres.” British Journal of Applied Physics, 3(8), 1952: 267–269.

    Article  Google Scholar 

  4. I. Imris. “Thermodynamic Study of the Cu-Fe-S-O-SiO2 System.” PhD Thesis, University of Kosice, 1971.

    Google Scholar 

  5. A. Yazawa and M. Kameda. “Fundamental Studies on Copper Smelting (II) Solubilitiesof Constituents of Matte in Slag.” Technical Reports Tohoku University, 19, 1954: 1–22.

    Google Scholar 

  6. A. Geveci and T. Rosenqvist. “Equilibrium Relations between Liquid Copper, Iron–Copper Matte and Iron Silicate Slag at 1250°C.” Trans. Inst. Min. Metall (Mineral Process. Extract. Metall. C), 82, 1973: C193–C201.

    Google Scholar 

  7. M. Nagamori. “Metal Loss to Slag: Part. I. Sulfidic and Oxidic dissolution of copper in fayalite slag from low grade matte.” Metall. Trans., 5, 1974: 531–538.

    Article  Google Scholar 

  8. F.J. Tavera and W.G. Davenport. “Equilibrations of Copper Mattes and Fayalite Slag under Controlled Partial Pressures of SO2.” Metall. Trans. B, 10B, 1979: 237–241.

    Article  Google Scholar 

  9. K.H. Jalkanen. “Copper and Sulphur Solubilities in Silica Saturated Iron Silicate Slags from Copper Mattes.” Scand. J. Metals, 10, 1981: 177–184.

    Google Scholar 

  10. P.J. Mackey. “The Physical Chemistry of Copper Smelting Slags — A Review”, Can. Metall. Q., 21, 1982: 221–260.

    Article  Google Scholar 

  11. A. Yazawa, S. Nakazawa, and Y. Takeda. “Distribution Behaviour of Various Elements in Copper Smelting Systems” (Advances in sulfide smelting, TSM-AIME, Warrendale, PA, US, 1983) 99–117.

    Google Scholar 

  12. R. Shimpo, S. Goto, O. Ogawa, and I. Asakura. “A Study on Equilibrium between Copper Matte and Slag.” Can. Metall. Q., 25, 1986, 113–121.

    Article  Google Scholar 

  13. R. Sridhar, J.M. Toguri, and S. Simeonov. “Copper Losses and Thermodynamic Considerations in Copper Smelting.” Metall. Mater. Trans. B, 28B, 1997: 191–200.

    Article  Google Scholar 

  14. I. Imris, M. Sanchez, and G. Achurra. “Copper Losses to Slags Obtained from the EI Teniente Process.” Mineral Process. Extract. Metall. C (Trans. Inst. Min. Metall.), 114, 2005: C135–C140

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Chen, M., Cui, Z., Zhao, B. (2015). Slag Chemistry of Bottom Blown Copper Smelting Furnace at Dongying Fangyuan. In: Jiang, T., et al. 6th International Symposium on High-Temperature Metallurgical Processing. Springer, Cham. https://doi.org/10.1007/978-3-319-48217-0_33

Download citation

Publish with us

Policies and ethics