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Certified Reference Materials in Inorganic Trace Analysis

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Handbook of Trace Analysis

Abstract

One of the characteristic phenomena in the chemical sciences of the second half of the twentieth and the beginning of twenty-first century was rapid development in the analytical chemistry of traces. New purity standards for materials emerged at the beginning of the atomic era. Uranium used as a fuel in nuclear reactors and other materials useed in nuclear technology had to be as fully free as possible of certain elements (e.g., Dy, Gd) that have a high cross-section for the absorption of thermal neutrons. The requirement that the concentration of these and other elements (e.g., in nuclear-grade uranium) should not exceed a few milligrams per kilogram caused fast progress in such techniques as emission spectrography, spectrophotometry, and neutron activation analysis (NAA), as well as in separation and preconcentration methods for elements. Progress in electronics and the advent of semiconductor technology increased purity requirements in the materials sciences. At the same time, progress in the biomedical sciences drew attention to the role of trace elements essential for life (Co, Cu, Fe, I, Mn, Mo, Ni, Se, Sn) or that are toxic (As, Cd, Hg, Pb). The determination of these elements in tissues, body fluids, and so on is often the basis for medical diagnosis and therapy. On the other hand, ecological movements have focused on global environmental pollution. As a result, monitoring of several chemical compounds and trace elements in water, air, soil, and food has become the daily work of several laboratories. In our times, more and more frequently it seems that determination of the total concentration of a given element in the investigated object is not sufficient. The determination of various physical and chemical forms of an element (i.e., speciation analysis) is often required. In this period of globalization, rapid growth of international trade, and introduction of international standards, many important decisions (administrative, medical, commercial, technological, and those concerning environment protection) depend on the results of chemical analyses.

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References

  1. ISO/IEC Guide 99:2007: International vocabulary of metrology – Basic and general concepts and associated terms (VIM3). ISO, Geneva (2007)

    Google Scholar 

  2. Dybczyński, R.: Reference materials and their role in quality assurance in inorganic trace analysis: problems of quality of trace analysis in the investigations of natural environment. In: Kabata-Pendias, A., Szteke, B. (eds.) (in Polish) Wyd. Edukacyjne Zofii Dobkowskiej, Warsaw (1998)

    Google Scholar 

  3. von Lehmden, D.J., Jungers, R.H., Lee Jr., R.E.: Determination of trace elements in coal, fly ash, fuel oil, and gasoline. Preliminary comparison of selected analytical techniques. Anal. Chem. 46, 239–245 (1974)

    Article  Google Scholar 

  4. Dybczyński, R., Veglia, A., Suschny, O.: Milk powder (A-11): A new IAEA reference material for trace and other element analysis. In: Bratter, P., Schramel, P. (eds.) Trace Element Analytical Chemistry in Medicine and Biology, pp. 657–674. de Gruyter, New York (1980)

    Google Scholar 

  5. Byrne, A.R., Camara-Rica, C., Cornelis, R., De Goeij, J.J.M., Iyengar, G.V., Kirkbright, G., Knapp, G., Parr, R.M., Stoeppler, M.: Results of a co-ordinated programme to improve the certification of IAEA milk powder A-11 and animal muscle H-4 for eleven “difficult trace elements”. Fresen. Z. Anal. Chem. 326, 723–729 (1987)

    Article  CAS  Google Scholar 

  6. Zeiller, E., Strachnov, V., Dekner, R.: Intercomparison study IAEA-155 on the determination of inorganic constituents in whey powder IAEA/AL/034. IAEA, Vienna (1990)

    Google Scholar 

  7. Dybczyński, R., Polkowska-Motrenko, H., Szopa, Z., Samczyński, Z.: New Polish certified reference materials for multielement inorganic trace analysis. Fresen. J. Anal. Chem. 345, 99–104 (1993)

    Article  Google Scholar 

  8. Dybczyński, R., Polkowska-Motrenko, H., Samczyński, Z., Szopa, Z.: Preparation and certification of the Polish reference material oriental tobacco leaves (CTA-OTL-1) for inorganic trace analysis. Raporty IChTJ Seria A nr. 1/96 (1996)

    Google Scholar 

  9. Dybczyński, R., Danko, B., Kulisa, K., Maleszewska, E., Polkowska-Motrenko, H., Samczyński, Z., Szopa, Z.: Preparation and certification of the Polish reference material: mixed Polish herbs (INCT-MPH-2) for inorganic trace analysis. Raporty IChTJ Seria A, nr 4/2002 (2002)

    Google Scholar 

  10. Dybczyński, R., Danko, B., Kulisa, K., Chajduk-Maleszewska, E., Polkowska-Motrenko, H., Samczyński, Z., Szopa, Z.: Final certification of two new reference materials for inorganic trace analysis. Chem. Anal. (Warsaw) 49, 143–158 (2004)

    Google Scholar 

  11. Polkowska-Motrenko, H., Dybczyński, R., Chajduk, E., Danko, B., Kulisa, K., Samczyński, Z., Sypuła, M., Szopa, Z.: Polish reference material: corn flour (INCT-CF-3) for inorganic trace analysis – preparation and certification. Raporty IChTJ, Seria A, nr, 3/2006 (2006)

    Google Scholar 

  12. Polkowska-Motrenko, H., Dybczyński, R.S., Chajduk, E., Danko, B., Kulisa, K., Samczyński, Z., Sypuła, M., Szopa, Z.: New Polish certified reference materials for inorganic trace analysis: corn flour (INCT-CF-3) and soya bean flour (INCT-SBF-4). Chem. Anal. (Warsaw) 52, 361–376 (2007)

    CAS  Google Scholar 

  13. Samczyński, Z., Dybczyński, R.S., Polkowska-Motrenko, H., Chajduk, E., Pyszynska, M., Danko, B., Czerska, E., Kulisa, K., Doner, K., Kalbarczyk, K.: Preparation and certification of the new Polish reference material oriental basma tobacco leaves (INCT-OBTL-5) for inorganic trace analysis. Institute of Nuclear Chemistry and Technology, Warsaw (2011)

    Google Scholar 

  14. Samczyński, Z., Dybczyński, R.S., Polkowska-Motrenko, H., Chajduk, E., Pyszynska, M., Danko, B., Czerska, E., Kulisa, K., Doner, K., Kalbarczyk, K.: Preparation and certification of the new Polish reference material Polish Virginia tobacco leaves (INCT-PVTL-6) for inorganic trace analysis. Institute of Nuclear Chemistry and Technology, Warsaw (2011)

    Google Scholar 

  15. Dybczyński, R.: Considerations on the accuracy of determination of some essential and/or toxic elements in biological materials. Chem. Anal. (Warsaw) 47, 325–334 (2002)

    Google Scholar 

  16. Versieck, J.: Collection and manipulation of samples for trace element analysis: Quality assurance considerations. In: Quality assurance in biomedical neutron activation analysis. IAEA-TECDOC-323. IAEA, Vienna, pp. 71–82 (1984)

    Google Scholar 

  17. Emons, H., Falgelj, A., van der Veen, A.M.H., Watters, R.: New definitions on reference materials. Accred. Qual. Assur. 10, 576–578 (2006)

    Article  CAS  Google Scholar 

  18. ISO Guide 30:1981: Terms and definitions used in connection with reference materials. ISO, Geneva, pp. 1–5 (1981)

    Google Scholar 

  19. ISO Guide 99:1993: International vocabulary of basic and general terms in metrology (VIM2). ISO, Geneva (1993)

    Google Scholar 

  20. Koeber, R., Linsinger, T.P.J., Emons, H.: An approach for more precise statements of metrological traceability on reference material certificates. Accred. Qual. Assur. 15, 255–262 (2010)

    Article  Google Scholar 

  21. Emons, H.: Policy for the statement of metrological traceability on certificates of ERMÛ certified reference materials. ERM http://www.erm-crm.org/ERM_products/policy_on_traceability/Documents/erm_traceability_statement_policy_final_5_may_2008.pdf. Accessed 15 May 20015

  22. Taylor, J.K.: Standard reference materials. In: Handbook for SRM users, NBS Special Publication. U.S. Government Printing Office, Washington, DC (1993)

    Google Scholar 

  23. Konieczka, P., Namieśnik, J.: Quality assurance and quality control in the analytical chemical laboratory: a practical approach. CRC, Boca Raton (2009)

    Book  Google Scholar 

  24. Gawlik, B.M., Linsinger, T., Kramer, G.N., Lamberty, A., Schimmel, H.: Organic contaminants in water – conceptual considerations for the production of liquid reference materials in support of the new water framework directive. Fresen. J. Anal. Chem. 371, 565–569 (2001)

    Article  CAS  Google Scholar 

  25. Cali, J.P., Plebanski, T.: Standard reference materials: guide to United States reference materials. National Bureau of Standards Special Publication 260–57. U.S. Government Printing Office, Washington, DC (1978)

    Google Scholar 

  26. ISO Guide 30:1992: Terms and definitions used in connection with reference materials. ISO, Geneva (1992)

    Google Scholar 

  27. ISO Guide 30:1992: Amendments 1:2008, Revision of definitions for reference materials. ISO, Geneva (2008)

    Google Scholar 

  28. ISO Guide 31:2000: Contents of certificates and labels. ISO, Geneva (2000)

    Google Scholar 

  29. ISO Guide 32:1997: Calibration in analytical chemistry and use of CRMs. ISO, Geneva (1997)

    Google Scholar 

  30. ISO Guide 33:2000: Uses of CRMs. ISO, Geneva (2000)

    Google Scholar 

  31. ISO Guide 34:2009: General requirements for the competence of reference material producers. ISO, Geneva (2009)

    Google Scholar 

  32. ISO Guide 35:2006: Reference materials – general and statistical principles for certification. ISO, Geneva (2006)

    Google Scholar 

  33. ISO/IEC 17025:2005: General requirements for the competence of testing and calibration laboratories. ISO, Geneva (2005)

    Google Scholar 

  34. www.ichtj.waw.pl

  35. Dybczyński, R.: Preparation and use of reference materials for quality assurance in inorganic trace analysis. Food Addit. Contam. 19, 928–938 (2002)

    Article  Google Scholar 

  36. Dybczyński, R., Polkowska-Motrenko, H., Samczyński, Z.: History, achievements and present time of production of CRMs for inorganic trace analysis in Poland. In: Proceedings of the 1st Scientific Conference, Reference materials in measurement and technology, part 1. (Federal Agency on Technical Regulating and Metrology) 10–14 Sept 2013, Ekaterinburg, Russia (2013)

    Google Scholar 

  37. Polkowska-Motrenko, H., Dybczyński, R., Chajduk, E.: Certification of reference materials for inorganic trace analysis, the INCT approach. Accred. Qual. Assur. 15, 245–250 (2010)

    Article  CAS  Google Scholar 

  38. Dybczyński, R., Polkowska-Motrenko, H., Samczyński, Z., Szopa, Z.: Two new Polish geological-environmental reference materials: apatite concentrate (CTA-AC-1) and fine fly ash (CTA-FFA-1). Geostand Newslett 15, 163–185 (1991)

    Article  Google Scholar 

  39. Dybczyński, R., Danko, B., Kulisa, K., Maleszewska, E., Polkowska-Motrenko, H., Samczyński, Z., Szopa, Z.: Preparation and certification of the Polish reference material: tea leaves (INCT-TL-1) for inorganic trace analysis. Raporty IChTJ Seria A, nr 3 (2002)

    Google Scholar 

  40. Polkowska-Motrenko, H., Dybczyński, R.: Activities of the INCT, Warsaw, in the domain of quality assurance for inorganic trace analysis. J. Radioanal. Nucl. Chem. 269, 339–345 (2006)

    Article  CAS  Google Scholar 

  41. Dybczyński, R., Danko, B., Polkowska-Motrenko, H.: NAA study on homogeneity of reference materials and their suitability for microanalytical techniques. J. Radioanal. Nucl. Chem. 245, 97–104 (2000)

    Article  Google Scholar 

  42. Dybczyński, R., Kulisa, K., Polkowska-Motrenko, H., Samczyński, Z., Szopa, Z., Wasek, M.: Neutron activation analysis as a tool for checking homogeneity of certified reference materials. Chem. Anal. (Warsaw) 42, 815–825 (1997)

    Google Scholar 

  43. Dybczyński, R., Polkowska-Motrenko, H., Samczyński, Z., Szopa, Z.: Virginia tobacco leaves (CTA-VTL-2) – new Polish CRM for inorganic trace analysis including microanalysis. Fresen. J. Anal. Chem. 360, 384–387 (1998)

    Article  Google Scholar 

  44. Samczyński, Z., Dybczyński, R.S., Polkowska-Motrenko, H., Chajduk, E., Pyszynska, M., Danko, B., Czerska, E., Kulisa, K., Doner, K., Kalbarczyk, K.: Two new reference materials based on tobacco leaves: certification for over a dozen of toxic and essential elements. ScientificWorldJournal 2012, Article ID 216380 (2012). doi:10.1100/2012/216380

    Google Scholar 

  45. Dybczyński, R.: Comparison of the effectiveness of various procedures for the rejection of outlying results and assigning consensus values in interlaboratory programs involving determination of trace elements or radionuclides. Anal. Chim. Acta 117, 53–70 (1980)

    Article  Google Scholar 

  46. Dybczyński, R.S., Danko, B., Polkowska-Motrenko, H., Samczyński, Z.: RNAA in metrology: a highly accurate (definitive) method. Talanta 71, 529–536 (2007)

    Article  Google Scholar 

  47. Dybczyński, R.S., Polkowska-Motrenko, H., Chajduk, E., Danko, B., Pyszynska, M.: Recent advances in ratio primary reference measurement procedures (definitive methods) and their use in certification of reference materials and controlling assigned values in proficiency testing. J. Radioanal. Nucl. Chem. 302, 1295–1302 (2014). doi:10.1007/s10967-014-3607-y

    Article  Google Scholar 

  48. Dybczyński, R.S.: 50 years of adventures with neutron activation analysis with the special emphasis on radiochemical separations. J. Radioanal. Nucl. Chem. 303, 1067–1090 (2015). doi:10.1007/s10967-014-3822-6

    Article  Google Scholar 

  49. Kratochvil, B., Wallace, D., Taylor, J.K.: Sampling for chemical analysis. Anal. Chem. 56, 113R–129R (1984)

    Article  CAS  Google Scholar 

  50. Dybczyński, R., Danko, B., Polkowska-Motrenko, H.: Some difficult problems still existing in the preparation and certification of CRMs. Fresen. J. Anal. Chem. 370, 126–130 (2001)

    Article  Google Scholar 

  51. Ingamells, C.O., Switzer, P.: A proposed sampling constant for use in geochemical analysis. Talanta 20, 547–568 (1973)

    Article  CAS  Google Scholar 

  52. Ingamells, C.O.: A further note on the sampling constant equation. Talanta 25, 731–732 (1978)

    Article  CAS  Google Scholar 

  53. Stoeppler, M., Kurfürst, U., Grobecker, K.H.: Der Homogenitätsfaktor als Kenngrösse für pulverisirte Festproben. Fresen. Z. Anal. Chem. 322, 687–691 (1985)

    Article  CAS  Google Scholar 

  54. Linsinger, T.P.J., Pauwels, J., Van der Veen, A., Schimmel, H., Lamberty, A.: Homogeneity and stability of reference materials. Accred. Qual. Assur. 6, 20–25 (2001)

    Article  CAS  Google Scholar 

  55. Ellison, S.L.R., Burke, S., Walker, R.F., Heydorn, K., Mansson, M., Pauwels, J., Wegscheider, W., te Nijenhius, B.: Uncertainty for reference materials certified by interlaboratory study: recommendations of an international study group. Accred. Qual. Assur. 6, 274–277 (2001)

    Article  Google Scholar 

  56. van der Veen, A.M.H., Linsinger, T., Schimmel, H., Lamberty, A., Pauwels, J.: Uncertainty calculations in the certification of reference materials. 4. Characterisation and certification. Accred. Qual. Assur. 6, 290–294 (2001)

    Article  Google Scholar 

  57. Pauwels, J., Lamberty, A., Schimmel, H.: Quantification of the expected shelf-life of certified reference materials. Fresen. J. Anal. Chem. 361, 395–399 (1998)

    Article  CAS  Google Scholar 

  58. Linsinger, T., Pauwels, J., Lamberty, A., Schimmel, H., Van der Veen, A., Siekmann, L.: Estimating the uncertainty of stability for matrix CRMs. Fresen. J. Anal. Chem 370, 183–188 (2001)

    Article  CAS  Google Scholar 

  59. Gellert, W., Kustner, H., Hellwich, M., Kasner, H. (eds.): Mathematics at a glance. Compendium. VEB Bibliographisches Institute, Leipzig (1975)

    Google Scholar 

  60. Linsinger, T.: Comparison of a measurement result with the certified value. ERM application note 1 (2005). ERM, Geel. https://ec.europa.eu/jrc/sites/default/files/erm_application_note_1_en.pdf. Accessed 15 May 2015

  61. Ellison, S.L.R., Williams, A. (eds.): Eurachem/CITAC guide: quantifying uncertainty in analytical measurement, 3rd edn. http://www.eurachem.org (2002)

  62. Chajduk, E., Polkowska-Motrenko, H., Dybczyński, R.S.: A definitive RNAA method for selenium determination in biological samples. Uncertainty evaluation and assessment of degree of accuracy. Accred. Qual. Assur. 13, 443–451 (2008)

    Article  CAS  Google Scholar 

  63. Bulska, E.: Chemical metrology. the art of carrying out measurements (in Polish), p. 191. Malamut, Warsaw (2008)

    Google Scholar 

  64. COMAR. International database for reference materials. BAM, Berlin. www.comar.bam.de (2006). Accessed 15 May 2015

  65. Eurachem Guide: The selection and use of reference materials (2002). www.eurachem.org

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Authors and Affiliations

  1. Laboratory of Nuclear Analytical Methods, Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195, Warsaw, Poland

    Rajmund S. Dybczyński & Halina Polkowska-Motrenko

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  1. Rajmund S. Dybczyński
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  2. Halina Polkowska-Motrenko
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Correspondence to Rajmund S. Dybczyński .

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  1. Department of Inorganic, Analytical Chemistry & Electrochemistry, Silesian University of Technology, Gliwice, Poland

    Irena Baranowska

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Dybczyński, R.S., Polkowska-Motrenko, H. (2016). Certified Reference Materials in Inorganic Trace Analysis. In: Baranowska, I. (eds) Handbook of Trace Analysis. Springer, Cham. https://doi.org/10.1007/978-3-319-19614-5_4

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