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An Overview of Physical (Particulate) Sunscreens

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Particulate Products

Part of the book series: Particle Technology Series ((POTS,volume 19))

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Abstract

Skin is constantly assaulted by sun exposure and terrestrial solar ultraviolet radiation (UVR) is a major factor deleterious to our health. The most reliable approach to sun protection is to cover up the skin by using a thin film of a topical sunscreen formulation containing active chemical ingredients that absorb, scatter or reflect the incident UVR to reduce the direct penetration and effect of UV exposure. Physical (particulate) actives are very stable and benign. From a regulatory perspective, zinc oxide and titanium dioxide are the only ones universally allowed as sunscreen actives. The development of sunscreen formulations containing ZnO and TiO2 requires knowledge of their optical properties as these dictate both the resulting aesthetics and the efficacy of the final sunscreen product and, thereby, acceptance by the user; these factors critically impact the economics of commercial sunscreen manufacturing and sales. The optical properties are uniquely related to the particle size (distribution) and particle morphology (e.g., surface area) of the two oxides. Precise measurement of these parameters is therefore a critical metric in formulating sunscreen products. X-ray disc centrifugation, acoustic attenuation spectroscopy and nuclear magnetic resonance relaxation are useful techniques that can be used to characterize fundamental properties of particulate suspensions at concentrations that are commercially relevant.

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References

  1. Ahmadi, T.S., et al.: Science 272, 1924 (1996)

    Article  ADS  Google Scholar 

  2. Allen, T.: Particle Size Measurement, 4th edn. Chapman and Hall, London (1990)

    Book  Google Scholar 

  3. Armstrong, B.K., Kricker, A.: Cancer Surveys – Skin Cancer, pp. 133–153. Imperial Cancer Research, Oxford (1996)

    Google Scholar 

  4. ASTM D2805-11: Standard Test Method for Hiding Power of Paints by Reflectometry. ASTM, Philadelphia (2011)

    Google Scholar 

  5. Becher, P.: Encyclopedia of Emulsion Technology, 2nd edn. Marcel Dekker, New York (1985)

    Google Scholar 

  6. Beck, I., et al.: Int. J. Cosmet. Sci. 3, 139–152 (1981)

    Article  Google Scholar 

  7. Birmingham, D.J.: Prog. Dermatol. 3, 1–8 (1968)

    Google Scholar 

  8. Black, H.S., et al.: Photochem. Photobiol. 40, 29–47 (1997)

    Article  Google Scholar 

  9. Buckley, H.E.: Crystal Growth. Wiley, New York (1951)

    Google Scholar 

  10. Butler, H.: Poucher’s Perfumes, Cosmetics and Soaps, 10th edn. Kluwer Publisher, Dordrecht (2000)

    Book  Google Scholar 

  11. Daniel, F.K.: Natl. Paint, Varn. Lacquer Assoc. Sci. Sect. Circ. No.744, (1950)

    Google Scholar 

  12. Deflandre, A., Lang, G.: Int. J. Cosmet. Sci. 10, 53–62 (1988)

    Article  Google Scholar 

  13. de Laat, J.M., de Gruijl, F.R.: Cancer Surv. 26, 173–191 (1996)

    Google Scholar 

  14. Derry, J.M., McLean, W.M., Freeman, J.B.: J. Parenter. Enteral Nutr. 7(2), 131–135 (1982)

    Article  Google Scholar 

  15. Diffey, B.L., Robson, J.: J. Soc. Cosmet. Chem. 40, 127–133 (1989)

    Google Scholar 

  16. Diffey, B.L.: Int. J. Cosmet. Sci. 16, 47–52 (1994)

    Article  Google Scholar 

  17. Dukhin, A.S., Goetz, P.J.: Ultrasound for Characterizing Colloids. Elsevier, Amsterdam (2002)

    Google Scholar 

  18. Dussert, A.S., Goori, E., Hemmerle, J.: Int. J. Cosmet. Sci. 19, 119–129 (1997)

    Article  Google Scholar 

  19. ec.europa.eu/nanotechnology/

    Google Scholar 

  20. Epstein, J.H.: In: Smith, K.C. (ed.) The Science of Photobiology, 2nd edn, pp. 155–192. CRC Press, Boca Raton (1989)

    Chapter  Google Scholar 

  21. Everett, D.H.: Basic Principles of Colloid Science. RSC Publications, London (1988)

    Google Scholar 

  22. Fairhurst, D., Mitchnick, M.A.: In: Lowe, N.J., Shaath, N.A., Pathak, M.A. (eds.) Sunscreens: Development, Evaluation and Regulatory Aspects, 2nd edn. Marcel Dekker, New York (1997)

    Google Scholar 

  23. Fairhurst, D., Dukhin, A.S., Klein, K.: ACS Symposium Series 472, Chapter 16 249 (2004)

    Google Scholar 

  24. Fairhurst, D., Prescott, S.: Spectrosc. Eur. 23(4), 13–16 (2011)

    Google Scholar 

  25. Federal Register: Sunscreen Drug Products for Over-the-Counter Human Use; Tentative Final Monographs: Proposed Rule, The Code of Federal Regulations, 21 CFR Part 352, pp. 28–33. FDA, Washington, DC (1998)

    Google Scholar 

  26. Federal Register: Final Rule: Testing and Labeling Requirements, 21 CFR 201.327, 17 June 2011

    Google Scholar 

  27. Garland, C.F., et al.: AEP 3, 103–110 (1993)

    Google Scholar 

  28. Grady, L.D.: J. Soc. Cosmet. Chem. 1(1), (1947)

    Google Scholar 

  29. Groves, G.A.: Drug Cosmet. Ind. 37(2), 155 (1994)

    MathSciNet  Google Scholar 

  30. Harry, R.G.: The Principles and Practice of Modern Cosmetics, vol. 2. Leonard Hill, London (1963)

    Google Scholar 

  31. Herman, J.R., et al.: Geolphys. Res. Letter 23, 2117 (1996)

    Article  ADS  Google Scholar 

  32. Hubbs, A.F., et al.: Toxicol. Pathol. 39(2), 301–324 (2011)

    Article  Google Scholar 

  33. Hunter, R.J.: Zeta Potential in Colloid Science. Academic, London (1981)

    Google Scholar 

  34. James, R.O., Parkes, G.A.: In: Matijevic, E. (ed.) Surface and Colloid Science, vol. II. Wiley, New York (1980)

    Google Scholar 

  35. Kaidby, K.H.: In: Lowe, N.J., Shaath, N.A. (eds.) Sunscreens: Development, Evaluation and Regulatory Aspects. Marcel Dekker, New York (1990)

    Google Scholar 

  36. Kerker, M.: The Scattering of Light and Other Electromagnetic Radiation. Academic, New York (1969)

    Google Scholar 

  37. Kobayashi, M., Kalreis, W.: Sun Products: Protection and Tanning, pp. 142–146. Allured Publishing, Carol Stream (1998)

    Google Scholar 

  38. Kochevar, I.E.: In: Gilchrist, B.A. (ed.) Photodamage, pp. 201–220. Blackwell Science, Cambridge (1995)

    Google Scholar 

  39. Kosmulski, M.: Surface Charging and Points of Zero Charge. CRC Press, Boca Raton (2009)

    Book  Google Scholar 

  40. Lambourne, R. (ed.): Paint and Surface Coatings; Theory and Practice. Ellis Horwood, Chichester (1987)

    Google Scholar 

  41. Laskowski, J.S., Ralston, J.D. (eds.): Colloid Chemistry in Mineral Processing. Elsevier, New York (1992)

    Google Scholar 

  42. Lowe, N.J., Weingarten, D., Wortzman, M.: J. Dermatol. Surg. Oncol. 17, 744–746 (1991)

    Article  Google Scholar 

  43. Lowe, N.J., Friedlander, J.: In: Lowe, N.J., Shaath, N.A., Pathak, M.A. (eds.) Sunscreens: Development, Evaluation and Regulatory Aspects, 2nd edn. Marcel Dekker, New York (1997)

    Google Scholar 

  44. Lowell, S., Shields, J.E.: Powder Surface Area and Porosity. Chapman Hall, London (1984)

    Book  Google Scholar 

  45. Maciel, G.E.: In: Grant, D.M., Harris, R.K. (eds.) Encyclopedia of Nuclear Magnetic Resonance. Wiley, New York (1996)

    Google Scholar 

  46. Marlow, B.J., Fairhurst, D., Pendse, H.P.: Langmuir 4, 611–626 (1983)

    Article  Google Scholar 

  47. McFadyen, P.: In: Freer, R. (ed.) Nanoceramics. Institute of Materials, London (1993)

    Google Scholar 

  48. Merkus, H.G.: Particle Size Measurements; Fundamentals, Practice, Quality. Springer, Netherlands (2009).

    Google Scholar 

  49. Mitchnick, M.A.: Sun Products: Protection and Tanning. C&T Ingredient Resource Series. Allured Publishing, Carol Stream (1998)

    Google Scholar 

  50. Mitchnick, M.A., Fairhurst, D., Pinnell, S.R.: J. Am. Acad. Dermatol. 40, 85–90 (1999)

    Article  Google Scholar 

  51. Mollet, H., Grubenmann, A.: Formulation Technology. Wiley-VCH, Weinheim (2001)

    Google Scholar 

  52. Orchard, S.R.: Oil Color Chem. Assoc. 51, 44 (1968)

    Google Scholar 

  53. Parfitt, G.D., Sing, K.S.W. (eds.): Characterization of Powder Surfaces. Academic, London (1976)

    Google Scholar 

  54. Parfitt, G.D. (ed.): Dispersion of Powders in Liquids. Applied Science, New York (1981)

    Google Scholar 

  55. Pathak, M.A., Fitzpatrick, T.B.: In: Fitzpatrick, T.B. (ed.) Dermatology in General Medicine, 4th edn, pp. 1689–1717. McGraw-Hill, New York (1993)

    Google Scholar 

  56. Race, S., Fairhurst, D., Brozel, M.: US Patent, 7,417,426, 26 Aug 2008

    Google Scholar 

  57. Reiger, M.M.: Cosmet. Toil. 108(12), 43 (1993)

    Google Scholar 

  58. Riegelman, S., Penna, R.: J. Soc. Cosmet. Chem. 11, 280–291 (1960)

    Google Scholar 

  59. Roberts, J.: In: Auerbach, P. (ed.) Management of Wilderness and Environmental Emergencies, 2nd edn. Mosby, St. Louis (1989)

    Google Scholar 

  60. Sayre, R.M.: Arch. Dermatol. 12(2), 745–746 (1986)

    Article  Google Scholar 

  61. Sayre, R.M., Dowdy, J.C.: Photodermatol. Photoimmunaol. Photoderm. 38, (1998)

    Google Scholar 

  62. Schlossman, M.L. (ed.): The Chemistry and Manufacture of Cosmetics, Vol. II, Formulating, 2nd edn. Allured Publishing, Carol Stream (2000)

    Google Scholar 

  63. Smijs, T.G.M., Bouwstra, J.A.: in J. Biomed. Nanotechnology 6(5), 469–484 (2010)

    Google Scholar 

  64. Solomon, H., Hawthorne, G.: Chemistry of Pigments and Fillers. Wiley, New York (1983)

    Google Scholar 

  65. Stenberg, C., Larko, O.: Arch. Dermatol. 121, 1400–1402 (1985)

    Article  Google Scholar 

  66. Szczurko, C., et al.: Photodermatol. Photoimmunol. Photomed. 10, 144–147 (1994)

    Google Scholar 

  67. Tadros, T.F.: Solid–Liquid Dispersions. Academic, New York (1987)

    Google Scholar 

  68. Tscharnuter, W.W., Weiner, B.B., Fairhurst, D.: ACS Symposium Series 472, Chapter 14, 184 (1991)

    Google Scholar 

  69. Tyrell, R.M.: Photochem. Photobiol. 63, 380–386 (1996)

    Article  Google Scholar 

  70. Urbach, F.: In: Urbach, F. (ed.) Biological Responses to Ultraviolet Radiation, pp. 1–6. Valdenmar Publishing, Overland Park (1992)

    Google Scholar 

  71. Wamer, W.G., Yin, J.J., Wei, R.R.: Free Radic. Biol. Med. 23, 851–858 (1997)

    Article  Google Scholar 

  72. Weiner, B.B.: In: Barth, H. (ed.) Modern Methods of Particle Sizing, pp. 93–116. Wiley-Interscience, New York (1984)

    Google Scholar 

  73. Wenniger, J.A., McEwen, G.N.: Cosmetic Ingredient Handbook, 2nd edn. CTFA, Washington, DC (1992)

    Google Scholar 

  74. Wiseman, T.J.: In: Parfitt, G.D., Sing, K.S.W. (eds.) Characterization of Powder Surfaces. Academic, London (1976)

    Google Scholar 

  75. www.fda.gov/nanotechnology/

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Fairhurst, D. (2014). An Overview of Physical (Particulate) Sunscreens. In: Merkus, H., Meesters, G. (eds) Particulate Products. Particle Technology Series, vol 19. Springer, Cham. https://doi.org/10.1007/978-3-319-00714-4_14

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