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Hydrogen Effects on Mechanical and Toughness Properties of Pipeline Steels

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TMS 2023 152nd Annual Meeting & Exhibition Supplemental Proceedings (TMS 2023)

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Abstract

This paper reviews commonly used hydrogen charging methods and effects of hydrogen on Charpy toughness. Preliminary ex-situ Charpy tests of electrolytically pre-charged specimens of three pipe steels were performed at room temperature. The gaseous hydrogen charging method is directly applicable to hydrogen pipelines but the lack of testing capability has limited its utilizations in R&D and qualification. The electrolytic charging method can be convenient and appropriate for investigating the effects of hydrogen especially if correlations between current density or potential and gaseous pressure are established. Preliminary experimental results have shown that the Charpy absorbed energy (CVN) of the electrolytically pre-charged specimens were lower than those of uncharged specimens by 8–20% for the steels investigated. Based on the load–deflection curves, the effects of hydrogen on Charpy toughness were to facilitate fracture initiation from the notch and accelerate fracture propagation after fracture initiation. In-situ Charpy and fracture toughness testing at slow rates would be more suitable for pipeline applications than impact testing.

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References

  1. Report prepared by the International Energy Agency for the G20, Japan, "The Future of Hydrogen Seizing today's opportunities," 2019.

    Google Scholar 

  2. https://www.nrcan.gc.ca/climate-change-adapting-impacts-and-reducing-emissions/canadas-green-future/the-hydrogen-strategy/23080

  3. Hagen AB, Alvaro A (2020) Report: Hydrogen influence on mechanical properties in pipeline steel. SINFEF Industry, Trondheim, Norway

    Google Scholar 

  4. Gangloff RP, Somerday BP (eds) (2012) Gaseous hydrogen embrittlement of materials in energy technologies Volume 1: The problem, its characterisation and effects on particular alloy classes, Cambridge: Woodhead Publishing Limited

    Google Scholar 

  5. Gangloff RP, Somerday BP (eds) (2012) Gaseous hydrogen embrittlement of materials in energy technologies Volume 2: Mechanisms, modelling and future develoments, Cambridge: Woodhead Publishing Limited

    Google Scholar 

  6. Lynch SP (2012) Hydrogen embrittlement phenomena and mechanisms. Corros Rev 30:105–123

    Article  CAS  Google Scholar 

  7. Traidia A, Chatzidouros E, Jouiad M (2018) Review of hydrogen-assisted cracking models for application to service lifetime prediction and challenges in the oil and gas industry. Corros Rev 36(4):323–347

    Article  CAS  Google Scholar 

  8. Dwivedi SK, Vishwakarma M (2018) Hydrogen embrittlement in different materials: a review. Int J Hydrogen Energy 43:21603–21616

    Article  CAS  Google Scholar 

  9. Li X, Ma X, Zhang J, Akiyama E, Wang Y, Song X (2020) Review of hydrogen embrittlement in metals: hydrogen diffusion, hydrogencharacterization, hydrogen embrittlement mechanism and prevention. Acta Metallurgica Sinica (English Letters) 33:759–773

    Article  CAS  Google Scholar 

  10. Tyson W (1979) Hydrogen in metals. Can Metall Q 18:1–11

    Article  CAS  Google Scholar 

  11. Zhao Y, Seok M-Y, Choi I-C, Lee Y-H, Park S-J, Ramamurty U, Suh J-Y, Jang J-I (2015) The role of hydrogen in hardening/softening steel: Influence of the charging process. Scripta Mater 107:46–49

    Article  CAS  Google Scholar 

  12. Dpover T, Hajilou T, Wan D, Wang D, Barnoush A, Verbeken K (2019) Assessment of the potential of hydrogen plasma charging as compared to conventional electrochemical hydrogen charging on dual phase steel. Mater Sci Eng, A 754:613–621

    Article  Google Scholar 

  13. Moro I, Briottet L, Lemoine P, Andrieu E, Blanc C, Odemer G (2010) Hydrogen embrittlement susceptibility of a high strength steel X80. Mater Sci Eng, A 527:7252–7260

    Article  Google Scholar 

  14. Boot T, Riemslag T, Reinton E, Liu P, Walters CL, Popovich V (2021) Assessing the susceptibility of existing pipelines to hydrogen embrittlement. In: TMS 2021 150th annual meeting & exhibition supplemental proceedings, the minerals, metals & materials series. Springer, Cham

    Google Scholar 

  15. Nguyen TT, Heo HM, Park J, Nahm SH, Beak UB (2021) Fracture properties and fatigue life assessment of API X70 pipeline steel under the efffect of an environment containing hydrogen. J Mech Sci Technol 35(4):1445–1455

    Article  Google Scholar 

  16. Marchi CS, Somerday BP, Robinson SL (2007) Permeability, solubility and diffusivity of hydrogen isotopes in statinless steels at high gas pressures. Int J Hydrogen Energy 32:100–116

    Article  Google Scholar 

  17. Fang B, Han E-H, Wang J, Zhu Z, Ke W (2006) Hydrogen in stress corrosion cracking of X-70 pipeline steels in near-neutral pH solutions. J Mater Sci 41:1797–1803

    Article  CAS  Google Scholar 

  18. Marchi CS, Somerday BP, Tang X, Schiroky GH (2008) Effects of alloy composition and strain hardening on tensile fracture of hydrogen-precharged type 316 stainless steels. Int J Hydrogen Energy 33:889–904

    Article  Google Scholar 

  19. Nagao A, Smith CD, Dadfarnia M, Sofronis P, Robertson IM (2012) The role of hydrogen in hydrogen embrittlement fracture of lath martensitic steel. Acta Mater 60:5182–5189

    Article  CAS  Google Scholar 

  20. Ohtsuka N, Shindo Y, Makita A (2010) Evaluation of hydrogen embrittlement and temper embrittlement by key curve method in instrumented Charpy test. EPJ Web of Conferences 6:14004

    Article  Google Scholar 

  21. Venezuela J, Tapia-Bastidas C, Zhou Q, Depover T, Verbeken K, Gray E, Liu Q, Liu Q, Zhang M, Atrens A (2018) Determination of the equivalent hydrogen fugacity during electrochemical charging of 3.5NiCrMoV steel. Corros Sci 132:90–106

    Article  CAS  Google Scholar 

  22. Baek UB, Lee HM, Baek SW, Nahm SH (2015) Hydrogen embrittlement for X-70 pipeline steel in high pressure hydrogen gas. In: Proceedings of the ASME 2015 pressure vessels and piping conference, July 19–23, 2015, Boston, Massachusetts, USA, PVP2015-45475

    Google Scholar 

  23. Meng B, Gu C, Zhang L, Zhou C, Li X, Zhao Y, Zheng J, Chen X, Han Y (2017) Hydrogen effects on X80 pipeline steel under high-pressure natural gas/hydrogen mixtures. Int J Hydrogen Energy 42:7404–7412

    Article  CAS  Google Scholar 

  24. Nanninga NE, Levy YS, Drexler ES, Condon RT, Stevenson AE, Slifka AJ (2012) Comparison of hydrogen embrittlement in three pipeline steels in high pressure gaseous hydrogen environments. Corros Sci 59:1–9

    Article  CAS  Google Scholar 

  25. Cialone HJ, Scott PM, Holbrook JH, Sieradzki K, Bandyopadhyay N (1984) Hydrogen effects on conventional pipeline steels. Hydrogen Energy Progress 4:1855–1867

    CAS  Google Scholar 

  26. Oriani RA, Josephic PH (1972) Testing of the decohesion theory of hydrogen-induced crack propagation. Scr Metall 6:681–688

    Article  CAS  Google Scholar 

  27. Jacobs AJ, Chandler WT (1975) Inhibition of hydrogen environment embrittlement by SO2. Scripta Metall 9:767–769

    Article  CAS  Google Scholar 

  28. Robinson SL (1977) Hydrogen compatibility of structural materials for energy storage and transmission applications. Sandia National Laboratories Report SAND77-8240, Livermore, CA

    Google Scholar 

  29. Somerday BP, Marchi CS (2006) Effects of hydrogen gas on steel vessels and pipelines," Sandia National Laboratories Report SAND2006-1526P, Livermore, CA

    Google Scholar 

  30. Nibur KA, Somerday BP, Marchi CS, Foulk JW III, Dadfarnia M, Sofronis P, Hayden GA (2010) Measurement and interpretation of threshold stress intensity factors for steels in high-pressure hydrogen gas. Sandia National Laboratories Report SAND2010-4633, Livermore, CA

    Google Scholar 

  31. Jack TA, Pourazizi R, Ohaeri E, Szpunar J, Zhang J, Qu J (2020) Investigation of the hydrogen induced carcking behavior of API 5L X65 pipeline steel. Int J Hydrogen Energy 45(35):17671–17684

    Article  CAS  Google Scholar 

  32. Cai L, Bai G, Gao X, Li Y, Hou Y (2022) Experimental investigation on the hydrogen embrittlement characteristics and mechanism of natural gas-hydrogen transportation pipeline steels. Mater Res Express 9:046512

    Article  Google Scholar 

  33. Cauwels M, Depraetere R, Waele WD, Hertele S, Depover T, Verbeken K (2022) Influence of electrochemical hydrogenation parameters on microstructures prone to hydrogen-induced cracking. J Nat Gas Sci Eng 101:104533

    Article  CAS  Google Scholar 

  34. Fassina P, Bolzoni F, Fumagalli G, Lazzari L, Vergani L, Sciuccati A (2011) Influence of hydrogen and low temperature on pipeline steels mechanical behaviour. Procedia Eng 10:3226–3234

    Article  CAS  Google Scholar 

  35. Hardie D, Charles EA, Lopez AH (2006) Hydrogen embrittlement of high strength pipeline steels. Corros Sci 48:4378–4385

    Article  CAS  Google Scholar 

  36. Zhou C, Ye B, Song Y, Cui T, Xu F, Zhang L (2019) Effects of internal hydrogen and surface-absorbed hydrogen on the hydrogen embrittlement of X80 pipeline steel. Int J Hydrogen Energy 44:22547–22558

    Article  CAS  Google Scholar 

  37. Li X (2016) Hydrogen effects on X80 steel mechanical properties measured by tensile and impact testing. University of South Florida: USF Tampa Graduate Theses and Dissertations

    Google Scholar 

  38. Dong CF, Liu ZY, Li XG, Cheng YF (2009) Effects of hydrogen-charging on the susceptibility of X100 pipeline steel to hydrogen-induced cracking. Int J Hydrogen Energy 34:9879–9884

    Article  CAS  Google Scholar 

  39. Chatzidouros EV, Papazoglou VJ, Tsiourva TE, Pantelis DI (2011) Hydrogen effect on fracture toughness of pipeline steel welds, with in situ hydrogen charging. Int J Hydrogen Energy 36:12626–12643

    Article  CAS  Google Scholar 

  40. Nagao A, Hayashi K, Ol K, Mitao S (2012) Effect of uniform distribution of fine cementite on hydrogen embrittlement of low carbon martensitic steel plates. ISIJ Int 52:213–221

    Article  CAS  Google Scholar 

  41. Guan K, Szpunar JA, Matocha K, Wang D (2017) Study on temper embrittlement and hydrogen embrittlement of a hydrogenation reactor by small punch test. Materials 10:671

    Article  Google Scholar 

  42. Nguyen LTH, Hwang J-S, Kim M-S, Kim J-H, Kim S-K, Lee J-M (2019) Charpy impact properties of hydrogen-exposed 316L stainless steel at ambient and cryogenic temperatures. Metals 9:625

    Article  CAS  Google Scholar 

  43. Mehta ML, Burke J (1975) Role of hydrogen in stress corrosion cracking of austenitic strainless steels. Corrosion 31(3):108–110

    Article  CAS  Google Scholar 

  44. Wang M, Akiyama E, Tsuzaki K (2007) Effect of hydrogen on the fracture behavior of high strength steel during slow strain rate test. Corros Sci 49:4081–4097

    Article  CAS  Google Scholar 

  45. Oriani RA (1970) The diffusion and trapping of hydrogen in steel. Acta Metall 18:147–157

    Article  CAS  Google Scholar 

  46. Podgurski HH, Oriani RA (1972) Nitrogenation of Fe-Al alloys. III: Absorption of hydrogen in nitrogenated Fe-Al alloys. Metall Trans 3:2055–2063

    Article  CAS  Google Scholar 

  47. Kumnick AJ, Johnson HH (1975) Steady state hydrogen transport through zone refined irons. Metall Trans A 6A:1087–1091

    Article  CAS  Google Scholar 

  48. Atrens A, Mezzanotte D, Fiore NF, Genshaw MA (1980) Electrochemical studies of hydrogen diffusion and permeability in Ni. Corros Sci 20(5):673–684

    Article  CAS  Google Scholar 

  49. Liu Q, Atrens AD, Shi Z, Verbeken K, Atrens A (2014) Determination of the hydrogen fugacity during electrolytic charging of steel. Corros Sci 87:239–258

    Article  CAS  Google Scholar 

  50. Venezuela J, Gray E, Liu Q, Zhou Q, Tapia-Bastidas C, Zhang M, Atrens A (2017) Equivalent hydrogen fugacity during electrochemical charging of some martensitic advanced high-strength steels. Corros Sci 127:45–58

    Article  CAS  Google Scholar 

  51. Liu Q, Gray E, Venezuela J, Zhou Q, Tapia-Bastidas C, Zhang M, Atrens A (2018) Equivalent hydrogen fugacity during electrochemical charging of 980DP steel determined by thermal desorption spectroscopy. Adv Eng Mater 20(1):1700469

    Article  Google Scholar 

  52. Escobar DP, Minambres C, Duprez L, Verbeken K, Verhaege M (2011) Internal and surface damage of multiphase steels and pure iron after electrochemical hydrogen charging. Corros Sci 53:3166–3176

    Article  Google Scholar 

  53. CSA Z245.1-18 (2018) Steel pipe, Canadian Standards Association

    Google Scholar 

  54. API Specification 5L (2018) Line pipe, 46th edn. American Petroleum Institute

    Google Scholar 

  55. Xu K (2012) Hydrogen embrittlement of carbon steels and their welds. In: Gaseous hydrogen embrittlement of materials in energy technologies, vol 1. Oxford, Woodhead Publishing, pp 526–561

    Google Scholar 

  56. ASME B31.12-2019 (2019) Hydrogen piping and pipelines. ASME International

    Google Scholar 

  57. Kpemou AM, Guy P, Julien C (2021) Influence of hydrogen embrittlement on ductile-brittle transition temperature determined on mini-Charpy specimens made in X65 steel. J Fail Anal Prev 21:2290–2304

    Article  Google Scholar 

  58. Fayet AP (1966) Influence of hydrogen on the mechanical properties of Charpy V - notch specimens of low carbon steel, Technical Report, Stanford University, Department of Materials Science

    Google Scholar 

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Acknowledgements

The authors would like to express their appreciation to Jie Liang, Chao Shi, Lin Yang, David Saleh, and Renata Zavadil of CanmetMATERIALS, Natural Resources Canada for their technical assistance.

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Correspondence to Xin Pang .

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Pang, X., Xu, S. (2023). Hydrogen Effects on Mechanical and Toughness Properties of Pipeline Steels. In: TMS 2023 152nd Annual Meeting & Exhibition Supplemental Proceedings. TMS 2023. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-22524-6_87

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