Skip to main content
Log in

Hydrogen in stress corrosion cracking of X-70 pipeline steels in near-neutral pH solutions

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The effect of hydrogen on the stress corrosion cracking (SCC) for X-70A and X-70B pipeline steels in near-neutral pH environments was studied by monotonic tensile tests on slow strain rate tests (SSRT) machine and cyclic tests on SSRT machine and fatigue machine. The results showed that SCC intensity increased at high cathodic protection potential. Hydrogen charged at high pressure enhanced SCC sensitivity. Cyclic tests under elastic strain condition could not take the specimens to fracture and the hydrogen content was very low. However, when the load was raised to produce plastic deformation, the specimens failed within limited time and there was brittle fracture appeared on the fracture surface. Moreover, the hydrogen content was higher than that under elastic strain condition. The SCC mechanism of X-70A and X-70B pipeline steels in near-neutral pH environments was related to hydrogen accumulation induced by plastic strain.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. A. ORIANI, J. P. HIRTH and M. SMIALOWSKI, “Hydrogen Degradation of Ferrous Alloys” (Noyes Publications, New Jersey, 1985).

    Google Scholar 

  2. R. A. ORIANI, Acta Met. 18 (1970) 147.

    Article  CAS  Google Scholar 

  3. Idem., Ann. Rev. Matr. Sci. 8 (1978) 327.

    CAS  Google Scholar 

  4. E. RICKE, Werkst. Korros. 29 (1978) 106.

    Google Scholar 

  5. J. P. HIRTH, Metall. Trans. 11A (1980) 861.

    CAS  Google Scholar 

  6. H. J. GRABKE, F. GEHRMANN and E. RIECKE, Steel Res. 72 (2001) 225.

    CAS  Google Scholar 

  7. B. CRAIG, in TMS-AIME Conf. Proc. On “Hydrogen Effects on Material Behavior,” edited by N. R. Moody and A. W. Thompson (The Minerals, Metals, and Materials Society, Warrendale, PA, 1990).

    Google Scholar 

  8. R. N. PARKINS, W. K. BLANCHARD Jr. and B. S. DELANTY, Corrosion 50 (1994) 394.

    CAS  Google Scholar 

  9. B. GU, J. LUO and X. MAO, Corrosion 55 (1999) 96.

    CAS  Google Scholar 

  10. J. A. BEAVERS and B. A. HARLE, in Proceedings of International Pipeline Conference, Vol. 1 (ASME, Calgary, Canada, 1996) p. 555.

    Google Scholar 

  11. W. T. CHANDLER and R. J. WALTER, in Hydrogen Embrittlement Testing, ASTM STP 543 (American Society for Testing and Materials, 1974) p. 170.

  12. R. N. PARKINS and E. A. CHARLES, Corrosion 51(7), (1995) 518.

    Google Scholar 

  13. M. BAKER Jr., Inc., “Stress Corrosion Cracking Study,” TTO Number 8, Department of Transportation, Research and Special Programs Administration, Office of Pipeline Safety, January 2005.

  14. G. HERBSLEB, R. K. POEPPERLING and W. SCHWENK, Corrosion 36 (1981) 247.

    Google Scholar 

  15. A. PUNTER, A. T. FIKKERS and G. VANSTAEN, (MP, June, 1992) p. 24.

  16. R. A. ORIANI, J. P. HIRTH and M. SMIALOWSKI, in “Hydrogen Degradation of Ferrous Alloys” (Noyes Publications. Park Ridge, New Jersey, 1985) p. 122.

    Google Scholar 

  17. Y. M. LIANG, P. SOFRONIS and N. ARAVAS, in Proceedings of Chemistry and Electrochemistry of Corrosion and Stress Corrosion Cracking: A Symposium Honoring the Contributions of R. W. Staehle (TMS, 2001) p. 251.

  18. B. Y. FANG, E. H. HAN, J. Q. WANG, Z. Y. ZHU and W. KE, “Effect of Strain Rates and Solution Compositions on SCC in Near-Neutral pH Solutions,” to be submitted.

  19. R. N. PARKINS, “A review of stress corrosion cracking of high pressure gas pipelines” Corrosion/2000; NACE International, 2000, paper No. 00363.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jianqiu Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fang, B., Han, EH., Wang, J. et al. Hydrogen in stress corrosion cracking of X-70 pipeline steels in near-neutral pH solutions. J Mater Sci 41, 1797–1803 (2006). https://doi.org/10.1007/s10853-006-3944-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-3944-5

Keywords

Navigation