Abstract
Heavy metals have seriously affected the quality of water, soil, and marine ecosystems. More economical, efficient and effective water purification and desalination methods need to be developed to remove persistent heavy metal ion contamination, especially in drinking water. Among low-cost methods with different degree of effectiveness for heavy metal ion removal highlighted in this chapter are the agro-based biosorbents and biopolymers based on cellulose, chitosan, and alginate. Factors influencing the efficiency of nanofiber membranes and packed-bed adsorbers have been addressed. Different types of composite ion exchangers are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Inglehart R, Norris, P (2003) Rising tide: gender equality and cultural change around the world. Cambridge University Press
Grimm NB et al (2008) Global change and the ecology of cities. Science 319(5864):756–760
Organization WH (1992) WHO commission on health and environment: report of the panel on industry
Flower SRL (2015) Environmental pollution-especially air pollution-and public health
Förstner U, Wittmann GT (2012) Metal pollution in the aquatic environment. Springer Science & Business Media
Mushak P (2007) Hormesis and its place in nonmonotonic dose–response relationships: some scientific reality checks. Environ Health Perspect 115(4):500
Mishra MK (2013) A study of intermetallics in Cu–Sn system and development of Sn–Zn based lead free solders
Matte TD, Landrigan PJ, Baker EL (1992) Occupational lead exposure. Hum Lead Exposure 155–168
Choudhary R et al (2016) Equipment-free, single-step, rapid, “on-site” kit for visual detection of lead ions in soil, water, bacteria, live cells, and solid fruits using fluorescent cube-shaped nitrogen-doped carbon dots. ACS Sustain Chem Eng 4(10):5606–5617
Mudgal V et al (2010) Effect of toxic metals on human health. Open Nutr J 3(1):94–99
Harikumar P et al (2011) Study on the leaching of mercury from compact fluorescent lamps using stripping voltammetry. J Toxicol Environ Health Sci 3(1):008–013
Lokeshappa B et al (2012) Assessment of toxic metals in agricultural produce. Food Public Health 2(1):24–29
Pais I, Jones JB Jr (1997) The handbook of trace elements. CRC Press
Soetan K, Olaiya C, Oyewole O (2010) The importance of mineral elements for humans, domestic animals and plants—a review. Afr J Food Sci 4(5):200–222
Underwood E (2012) Trace elements in human and animal nutrition: Elsevier
Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manage 92(3):407–418
Ngah WW, Hanafiah M (2008) Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. Biores Technol 99(10):3935–3948
Barakat M (2011) New trends in removing heavy metals from industrial wastewater. Arab J Chem 4(4):361–377
Daneshfozoun S, Abdullah M, Abdullah B (2017) Preparation and characterization of magnetic biosorbent based on oil palm empty fruit bunch fibers, cellulose and Ceiba pentandra for heavy metal ions removal. Ind Crops Prod 105:93–103
Omri A, Benzina M (2012) Removal of manganese (II) ions from aqueous solutions by adsorption on activated carbon derived a new precursor: ziziphus spina-christi seeds. Alexandria Eng J 51(4):343–350
Omorogie M (2014) Adsorption of some toxic metal ions onto west african boxwood (naucleadiderrichii, merrill) seed epicarp doped with nanoparticles
Mondal DK, Nandi BK, Purkait M (2013) Removal of mercury (II) from aqueous solution using bamboo leaf powder: equilibrium, thermodynamic and kinetic studies. J Environ Chem Eng 1(4):891–898
Reddy DHK et al (2012) Optimization of Cd(II), Cu(II) and Ni(II) biosorption by chemically modified Moringa oleifera leaves powder. Carbohyd Polym 88(3):1077–1086
Li X et al (2013) Adsorption, concentration, and recovery of aqueous heavy metal ions with the root powder of Eichhornia crassipes. Ecol Eng 60:160–166
Munagapati VS et al (2010) Biosorption of Cu(II), Cd(II) and Pb(II) by acacia leucocephala bark powder: kinetics, equilibrium and thermodynamics. Chem Eng J 157(2–3):357–365
Reddy DHK et al (2011) Biosorption of Ni(II) from aqueous phase by Moringa oleifera bark, a low cost biosorbent. Desalination 268(1–3):150–157
Sarin V, Pant KK (2006) Removal of chromium from industrial waste by using eucalyptus bark. Biores Technol 97(1):15–20
Feng N et al (2011) Biosorption of heavy metals from aqueous solutions by chemically modified orange peel. J Hazard Mater 185(1):49–54
Saha R et al (2013) Removal of hexavalent chromium from water by adsorption on mosambi (Citrus limetta) peel. Res Chem Intermed 39(5):2245–2257
Bhattacharya P et al (2013) Potential of biosorbent developed from fruit peel of Trewia nudiflora for removal of hexavalent chromium from synthetic and industrial effluent: Analyzing phytotoxicity in germinating Vigna seeds. J Environ Sci Health Part A 48(7):706–719
Iqbal M, Saeed A, Kalim I (2009) Characterization of adsorptive capacity and investigation of mechanism of Cu2+, Ni2+ and Zn2+ adsorption on mango peel waste from constituted metal solution and genuine electroplating effluent. Sep Sci Technol 44(15):3770–3791
Zheng L et al (2010) Equilibrium and kinetic studies of adsorption of Cd(II) from aqueous solution using modified corn stalk. J Hazard Mater 176(1–3):650–656
Zheng L et al (2010) Removal of cadmium (II) from aqueous solution by corn stalk graft copolymers. Biores Technol 101(15):5820–5826
Wong K et al (2003) Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions. Chemosphere 50(1):23–28
Ahalya N, Kanamadi R, Ramachandra T (2005) Biosorption of chromium (VI) from aqueous solutions by the husk of Bengal gram (Cicer arientinum). Electron J Biotechnol 8(3):0–0
Oliveira WE et al (2008) Untreated coffee husks as biosorbents for the removal of heavy metals from aqueous solutions. J Hazard Mater 152(3):1073–1081
Alomá I et al (2012) Removal of nickel (II) ions from aqueous solutions by biosorption on sugarcane bagasse. J Taiwan Inst Chem Eng 43(2):275–281
Velazquez-Jimenez LH, Pavlick A, Rangel-Mendez JR (2013) Chemical characterization of raw and treated agave bagasse and its potential as adsorbent of metal cations from water. Ind Crops Prod 43:200–206
Martín-Lara MÁ et al (2010) Modification of the sorptive characteristics of sugarcane bagasse for removing lead from aqueous solutions. Desalination 256(1–3):58–63
Khoramzadeh E, Nasernejad B, Halladj R (2013) Mercury biosorption from aqueous solutions by sugarcane bagasse. J Taiwan Inst Chem Eng 44(2):266–269
Boota R, Bhatti HN, Hanif MA (2009) Removal of Cu(II) and Zn(II) using lignocellulosic fiber derived from Citrus reticulata (Kinnow) waste biomass. Sep Sci Technol 44(16):4000–4022
Daneshfozoun S, Abdullah B, Abdullah MA (2014) Heavy metal removal by oil palm empty fruit bunches (OPEFB) biosorbent. In: Applied mechanics and materials. Trans Tech Publications
Daneshfozoun S, Abdullah B, Abdullah MA (2016) The effects of oil palm empty fruit bunch sorbent sizes on plumbum (II) ion sorption. In: Advanced materials research. Trans Tech Publications
Nazir MS, Ajab H, Raza MR, Abdullah MA (2018) Surface modification of cellulose fibers from oil palm empty fruit bunches for heavy metal ion sorption and diesel desulphurization. Desalin Water Treat 107: 241–256
Ajab H, Dennis JO, Abdullah MA (2018) Synthesis and characterization of cellulose and hydroxyapatite-carbon electrode composite for trace plumbum ions detection and its validation in blood serum. Int J Biol Macromol 113:376–385
Kaur R et al (2012) Biosorption the possible alternative to existing conventional technologies for sequestering heavy metal ions from aqueous streams: a review. Univ J Environ Res Technol 2(4)
Wei W et al (2016) Biosorption of Pb(II) from aqueous solution by extracellular polymeric substances extracted from Klebsiella sp. J1: adsorption behavior and mechanism assessment. Sci Rep 6:31575
Sargın İ (2015) Preparation of chitosan microcapsules and investigation of its metal adsorption properties. Selçuk Üniversitesi Fen Bilimleri Enstitüsü
Homagai PL (2018) Studies on the development of natural cation exchanger for heavy metals removal
Zhang YHP (2013) Next generation biorefineries will solve the food, biofuels, and environmental trilemma in the energy–food–water nexus. Energy Sci Eng 1(1):27–41
Dax D et al (2013) Amphiphilic spruce galactoglucomannan derivatives based on naturally-occurring fatty acids. BioResources 8(3):3771–3790
Wang J et al (2013) Collagen/cellulose hydrogel beads reconstituted from ionic liquid solution for Cu(II) adsorption. Carbohyd Polym 98(1):736–743
Abbas A et al (2017) Design, characterization and evaluation of hydroxyethylcellulose based novel regenerable supersorbent for heavy metal ions uptake and competitive adsorption. Int J Biol Macromol 102:170–180
Abbas A et al (2017) Modified hydroxyethylcellulose: a regenerable super-sorbent for Cd2+ uptake from spiked high-hardness groundwater. Cellul Chem Technol 51(1–2):167–174
Kweon D-K et al (2001) Adsorption of divalent metal ions by succinylated and oxidized corn starches. Carbohyd Polym 46(2):171–177
Song X et al (2006) Preparation and properties of octenyl succinic anhydride modified early indica rice starch. Starch-Stärke 58(2):109–117
Marcazzan M et al (1999) An ESR assay for α-amylase activity toward succinylated starch, amylose and amylopectin. J Biochem Biophys Methods 38(3):191–202
Yamaguchi R et al (1981) Preparation of partially N-succinylated chitosans and their cross-linked gels. Carbohyd Res 88(1):172–175
Rinaudo M (2006) Chitin and chitosan: properties and applications. Prog Polym Sci 31(7):603–632
Kumar MNR (2000) A review of chitin and chitosan applications. React Funct Polym 46(1):1–27
Shukla SK et al (2013) Chitosan-based nanomaterials: a state-of-the-art review. Int J Biol Macromol 59:46–58
Sorlier P et al (2001) Relation between the degree of acetylation and the electrostatic properties of chitin and chitosan. Biomacromol 2(3):765–772
Miretzky P, Cirelli AF (2009) Hg(II) removal from water by chitosan and chitosan derivatives: a review. J Hazard Mater 167(1–3):10–23
Dash M et al (2011) Chitosan—a versatile semi-synthetic polymer in biomedical applications. Prog Polym Sci 36(8):981–1014
Jayakumar R et al (2005) Graft copolymerized chitosan—present status and applications. Carbohyd Polym 62(2):142–158
Ryu SW et al (2004) Synthesis of well-defined high-density branched polymers carrying two branch chains in each repeating unit by coupling reaction of benzyl bromide-functionalized polystyrenes with polymer anions comprised of two polymer segments. Macromolecules 37(17):6291–6298
Lavanya R et al (2017) Adsorptive removal of copper (II) and lead (II) using chitosan-g-maleic anhydride-g-methacrylic acid copolymer. Int J Biol Macromol 104:1495–1508
Razzaz A et al (2015) J Taiwan Inst Chem Eng
Kumar I, Natrayasamy V (2017) Development of multivalent metal ion imprinted chitosan biocomposites for phosphate sorption
Sargın İ, Arslan G, Kaya M (2016) Efficiency of chitosan–algal biomass composite microbeads at heavy metal removal. React Funct Polym 98:38–47
Pereao O et al (2017) Electrospinning: polymer nanofibre adsorbent applications for metal ion removal. J Polym Environ 25(4):1175–1189
Karthik R, Meenakshi S (2015) Removal of Cr(VI) ions by adsorption onto sodium alginate-polyaniline nanofibers. Int J Biol Macromol 72:711–717
Lim S-F et al (2009) Removal of copper by calcium alginate encapsulated magnetic sorbent. Chem Eng J 152(2–3):509–513
Dogan H (2012) Preparation and characterization of calcium alginate-based composite adsorbents for the removal of Cd, Hg, and Pb ions from aqueous solution. Toxicol Environ Chem 94(3):482–499
Davis TA, Volesky B, Mucci A (2003) A review of the biochemistry of heavy metal biosorption by brown algae. Water Res 37(18):4311–4330
Chang C, Zhang L (2011) Cellulose-based hydrogels: present status and application prospects. Carbohyd Polym 84(1):40–53
Lee KY et al (2009) Electrospinning of polysaccharides for regenerative medicine. Adv Drug Deliv Rev 61(12):1020–1032
Huang Z-M et al (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol 63(15):2223–2253
Elsabee MZ, Naguib HF, Morsi RE (2012) Chitosan based nanofibers, review. Mater Sci Eng C 32(7):1711–1726
Ramakrishna S et al (2006) Electrospun nanofibers: solving global issues. Mater Today 9(3):40–50
Ahmed S, Ikram S (2015) Chitosan & its derivatives: a review in recent innovations. Int J Pharm Sci Res 6(1):14
Shariful MI et al (2017) Adsorption of divalent heavy metal ion by mesoporous-high surface area chitosan/poly (ethylene oxide) nanofibrous membrane. Carbohyd Polym 157:57–64
Habiba U et al (2017) Chitosan/(polyvinyl alcohol)/zeolite electrospun composite nanofibrous membrane for adsorption of Cr6+, Fe3+ and Ni2+. J Hazard Mater 322:182–194
Mohamed RR, Elella MHA, Sabaa MW (2017) Cytotoxicity and metal ions removal using antibacterial biodegradable hydrogels based on N-quaternized chitosan/poly (acrylic acid). Int J Biol Macromol 98:302–313
Gupta V et al (2009) Low-cost adsorbents: growing approach to wastewater treatment—a review. Crit Rev Environ Sci Technol 39(10):783–842
Goel J et al (2005) Removal of lead (II) by adsorption using treated granular activated carbon: batch and column studies. J Hazard Mater 125(1–3):211–220
Han R et al (2009) Characterization and properties of iron oxide-coated zeolite as adsorbent for removal of copper (II) from solution in fixed bed column. Chem Eng J 149(1–3):123–131
Taty-Costodes VC et al (2005) Removal of lead (II) ions from synthetic and real effluents using immobilized Pinus sylvestris sawdust: adsorption on a fixed-bed column. J Hazard Mater 123(1–3):135–144
Chen JP, Wang X (2000) Removing copper, zinc, and lead ion by granular activated carbon in pretreated fixed-bed columns. Sep Purif Technol 19(3):157–167
Mohammed N et al (2016) Continuous flow adsorption of methylene blue by cellulose nanocrystal-alginate hydrogel beads in fixed bed columns. Carbohyd Polym 136:1194–1202
Mojumdar S, Varshney K, Agrawal A (2006) Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ 10(1):89–97
Mojumdar S et al (2006) Synthetic and ion-exchange studies on a lead selective acrylamide thorium (IV) phosphate hybrid fibrous ion exchanger. Res J Chem Environ 10:85–89
Varshney K, Agrawal A, Mojumdar S (2007) Pyridine based cerium (IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim 90(3):731–734
Varshney K, Agrawal A, Mojumdar S (2007) Pyridine based thorium (IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim 90(3):721–724
Shahadat M et al (2012) Synthesis, characterization, photolytic degradation, electrical conductivity and applications of a nanocomposite adsorbent for the treatment of pollutants. RSC Adv 2(18):7207–7220
Pouliot Y, Conway V, Leclerc P-L (2014) Separation and concentration technologies in food processing. In: Food processing: principles and applications, pp. 33–60
Camacho LM et al (2013) Advances in membrane distillation for water desalination and purification applications. Water 5(1):94–196
Drioli E, Macedonio EF (2010) Membrane research, membrane production and membrane application in China
Wu Y et al (2015) The effects of multi-functional groups from PVA and ternary multisilicon copolymer on diffusion dialysis. Sep Purif Technol 141:124–131
Gizli N, Çınarlı S, Demircioğlu M (2012) Characterization of poly (vinylchloride) (PVC) based cation exchange membranes prepared with ionic liquid. Sep Purif Technol 97:96–107
Kaushal S et al (2017) Synthesis and characterization of a tin (IV) antimonophosphate nano-composite membrane incorporating 1-dodecyl-3-methylimidazolium bromide ionic liquid. RSC Adv 7(21):12561–12569
Ray SS, Okamoto M (2003) Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog Polym Sci 28(11):1539–1641
Pavlidou S, Papaspyrides C (2008) A review on polymer–layered silicate nanocomposites. Prog Polym Sci 33(12):1119–1198
Kaur M, Srivastava A (2002) Photopolymerization: a review. J Macromol Sci Part C Polym Rev 42(4):481–512
Fuchs Y, Soppera O, Haupt K (2012) Photopolymerization and photostructuring of molecularly imprinted polymers for sensor applications—a review. Anal Chim Acta 717:7–20
Bayram I, Oral A, Şirin K (2013) Synthesis of poly(cyclohexene oxide)-montmorillonite nanocomposite via in situ photoinitiated cationic polymerization with bifunctional clay. J Chem 2013
Maruyama SA et al (2017) Synthesis, cation exchange and dehydration/rehydration of sodium gordaite: NaZn4(OH)6(SO4)Cl · 6H2O. Appl Clay Sci 146:100–105
Kulkarni VV, Golder AK, Ghosh PK (2018) Synthesis and characterization of carboxylic cation exchange bio-resin for heavy metal remediation. J Hazard Mater 341:207–217
Maity J, Ray SK (2018) Removal of Pb(II) from water using a bio-composite adsorbent-A systematic approach of optimizing synthesis and process parameters by response surface methodology. J Environ Manage 209:112–125
Jain CK, Malik DS, Yadav AK (2016) Applicability of plant based biosorbents in the removal of heavy metals: a review. Environ Process 3(2):495–523
Raftery R, O’Brien FJ, Cryan S-A (2013) Chitosan for gene delivery and orthopedic tissue engineering applications. Molecules 18(5):5611–5647
Matsumoto H, Tanioka A (2011) Functionality in electrospun nanofibrous membranes based on fiber’s size. Surface Area, and Molecular Orientation. 1:249–264
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Nazir, M.S., Tahir, Z., Akhtar, M.N., Abdullah, M.A. (2019). Biosorbents and Composite Cation Exchanger for the Treatment of Heavy Metals. In: Inamuddin, Ahamed, M., Asiri, A. (eds) Applications of Ion Exchange Materials in the Environment. Springer, Cham. https://doi.org/10.1007/978-3-030-10430-6_7
Download citation
DOI: https://doi.org/10.1007/978-3-030-10430-6_7
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-10429-0
Online ISBN: 978-3-030-10430-6
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)