Abstract
In this study, covalently cross-linked network strategy has been applied to prepare new triple-shape memory polymers (TSPs) based on poly(l-lactide) (PLA)/poly(ɛ-caprolactone) (PCL) blends. The TSPs were fabricated by adding di-cumyl peroxide, with triallyl isocyanurate as a coagent for performing the cross-linking reaction. The differential scanning calorimetry (DSC) analysis demonstrated that all the PLA/PCL blends show two melting points (Tm,PCL and Tm,PLA), which can be employed as the transition temperature (Ttrans) to induce triple-shape memory behavior. The scanning electron microscopy (SEM) analysis indicated that there are two immiscible morphologies: co-continuous structure and matrix-droplet. The influence of temperature on the crystalline phase changes was analyzed by X-ray diffraction at various temperatures. The results revealed that during the heating–cooling cycle, the degree of crystallinity decreased when the temperature increased and at higher temperature, the crystallization peaks of PCL disappeared. Multiple thermal–mechanical tests were performed and the results showed that the composition ratio of the two phases plays an important role in the triple-shape memory behavior. The results confirmed that the excellent shape memory behavior was obtained for the sample containing 50 wt% PCL.
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Lendlin A, Kelch S (2002) Angew Chem Int Ed 41:2034
Liu C, Qin H, Mather PT (2007) J Mater Chem 17:1543
Abdallah-Elhirtsi S, Fitoussi J, Rashmi BJ, Prashantha K, Farzaneh S, Lacrampe MF, Krawczak P, Tcharkhtchi (2015) Polym Compos 36:1145
Memarian F, Fereidoon A, Ahangari MG, Khonakdar HA (2017) Polym Compos. https://doi.org/10.1002/pc.24387
Rousseau IA (2008) Polym Eng Sci 48:2075
Lei M, Yu K, Lu H, Qi HJ (2017) Polymer 109:216
Bae CY, Park JH, Kim EY, Kim BK (2011) J Mater Chem 21:11288
Voit W, Ware T, Dasari RR, Smith P, Danz L, Simon D, Barlow S, Marder SR, Gall K (2010) Adv Funct Mater 20:162
Zhang S, Yu Z, Govender T, Luo H, Li B (2008) Polymer 49:3205
Raquez JM, Vanderstappen S, Meyer F, Verge P, Alexandre M, Thomassin JM, Jerome C, Dubois P (2011) Chem Eur J 17:10135
Ortega AM, Yakacki CM, Dixon SA, Likos R, Greenberg AR, Gall K (2012) Soft Matter 8:7381
Samuel C, Barrau S, Lefebvre JM, Raquez JM, Dubois P (2014) Macromolecules 47:6791
Wang WS, Ping P, Chen XS, Jing XB (2006) Eur Polym J 42:1240
Pilate F, Mincheva R, Winter JD, Gerbaux P, Wu L, Todd R, Raquez JM, Dubois P (2014) Chem Mater 26:5860
Zhang J, Wu G, Huang C, Niu Y, Chen C, Chen Z, Yang K, Wang Y (2012) J Phys Chem C 116:5835
Zhang MQ, Yang KK, Wang YZ (2015) Chin Chem Lett 26:1221
Zhang T, Wen Z, Hui Y, Yang K, Zhou Q, Wang Y (2015) Polym Chem 6:4177
Pretsch T (2010) Smart Mater Struct 19:015006
Behl M, Lendlein A (2010) J Mater Chem 20:3335
Bellin I, Kelch S, Langer R, Lendlein A (2006) Proc Natl Acad Sci USA 103:18043
Xie T (2011) Polymer 52:4958
Zotzmann J, Behl M, Feng YK, Lendlein A (2010) Adv Funct Mater 20:3583
Ahn SK, Kasi RM (2011) Adv Funct Mater 21:4543
Ware T, Hearon K, Lonnecker A, Wooley KL, Maitland DJ, Voit W (2012) Macromolecules 45:1062
Xie T, Page AK, Eastman SA (2011) Adv Funct Mater 21:2057
Xie T (2010) Nature 464:267
Li J, Liu T, Pan Y, Xia S, Zhang Z, Ding X, Peng Y (2012) Macromol Chem Phys 213:2246
Mohanty AK, Misra M, Hinrichsen G (2000) Macromol Mater Eng 276–277:1
Mohanty AK, Misra M, Drzal LT (2002) J Polym Environ 10:19
Dipa R, Sarkar BK (2001) J Appl Polym Sci 80:1013
Sen T, Reddy HN (2013) Adv Mater Sci Eng 2013:1
Liao HT, Wu CS (2009) Mater Sci Eng A 515:207
Yeh JT, Wu CJ, Tsou CH, Chai WL, Chow JD, Huang CY, Chen KN, Wu CS (2009) Polym Plast Technol Eng 48:571
Radusch HJ, Kolesov I, Gohs U, Heinrich G (2012) Macromol Mater Eng 297:1225
Wu D, Lin D, Zhang J, Zhou W, Zhang M, Zhang Y, Wang D, Liu B (2011) Macromol Chem Phys 212:613
Zhang H, Wang H, Zhong W, Du Q (2009) Polymer 50:1596
Xie H, Cheng CY, Du L, Fan CJ, Deng XY, Yang KK (2016) Macromolecules 49:3845
Zhao Q, Qi HJ, Xie T (2015) Prog Polym Sci 49–50:79
Quynh TM, Mitomo H, Nagasawa N, Wada Y, Yoshii F, Tamada M (2007) Eur Polym J 43:1779
Bai H, Liu H, Bai D, Zheng Q, Wang K, Deng H, Chen F, Fu Q (2014) Polym Chem 5:5985
Li SC, Liu H, Zeng W (2011) J Appl Polym Sci 121:2614
Yang SL, Wu ZH, Yang W, Yang MB (2008) Polym Test 27:957
Shayan M, Azizi H, Ghasemi I, Karrabi M (2015) Carbohydr Polym 124:237
Androsch R, Wundelich B (2005) Polymer 46:12556
Delpouve N, Delbreilh L, Stoclet G, Saiter A, Dargent E (2014) Macromolecules 47:5186
Righetti MC, Tombari E (2011) Thermochim Acta 522:118
Brizzolara D, Cantow HJ, Diederichs K, Keller E, Domb AJ (1996) Macromolecules 29:191
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Molavi, F.K., Ghasemi, I., Messori, M. et al. Design and Characterization of Novel Potentially Biodegradable Triple-Shape Memory Polymers Based on Immiscible Poly(l-lactide)/Poly(ɛ-caprolactone) Blends. J Polym Environ 27, 632–642 (2019). https://doi.org/10.1007/s10924-019-01366-6
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DOI: https://doi.org/10.1007/s10924-019-01366-6