Skip to main content

Zeta Potential Measurement

  • Reference work entry
Encyclopedia of Microfluidics and Nanofluidics

Synonyms

Electrokinetic potential; Surface potential

Definition

Zeta potential is defined as the electrical potential at the shear plane of the electric double layer. Measurement techniques are based on indirect readings obtained during electrokinetic experiments. Typically, the magnitude of the zeta potential varies between \( {\mathrm{0}}\hbox{--}{\mathrm{200}}{\mathrm{mV}} \) where both negative and positive values are possible depending on the electrochemistry of the solid-liquid interface.

Overview

Zeta potentialrefers to the electrokinetic potential at the shear surface of the electric double layer. Along with surface conductance, zeta potential is an important parameter in the study and modeling of a variety of electrokinetic phenomena relevant to microfluidics and Lab-on-a-Chip devices. The zeta potential of a solid-liquid interface depends on a number of factors including the ion concentration, ion valence, pH level and temperature of the solution. For this reason each...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 1,299.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Probstein RF (1994) Physiochemical Hydrodynamics. An Introduction. New York, John Wiley & Sons, Inc.

    Google Scholar 

  2. Hunter RJ (1981) Zeta potential in colloid science: principles and applications. Academic Press, London

    Google Scholar 

  3. Masiliyah JH (1994) Electrokinetic Transport Phenomena. AOSTRA, Edmonton

    Google Scholar 

  4. Hunter RJ (2001) Foundations of Colloid Science. Oxford University Press, Oxford

    Google Scholar 

  5. Sinton D (2004) Microscale flow visualization. Microfluid Nanofluid 1:2–21

    Article  Google Scholar 

  6. Sinton D, Escobedo C, Ren L, Li D (2002) Direct and Indirect Electro-osmotic Flow Velocity Measurements in Microchannels. J Colloid Interf Sci 254:184–189

    Article  Google Scholar 

  7. Sze A, Erickson D, Ren L, Li D (2003) Zeta-Potential Measurement Using Smoluchowski Equation and the Slope of Current-Time Relationship in Electro-osmotic Flow. J Colloid Interface Sci 261, 402-410

    Google Scholar 

  8. Gu Y, Li D (2000) The \( \zeta \)-Potential of Glass Surface in Contact with Aqueous Solutions. J Colloid Interf Sci 226:328–339

    Article  Google Scholar 

  9. Sanders RS, Chow RS, Masilyah JH (1995) Deposition of Bitumen and Asphaltene-Stabilizing Emulsions in an Impinging Jet Cell. J Colloid Interface Sci 174:230–245

    Article  Google Scholar 

  10. Oddy MH, Santiago JG (2004) A method for determining electrophoretic and electro-osmotic mobilities using AC and DC electric field displacements. J Colloid Interface Sci 269:192–204

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2008 Springer-Verlag

About this entry

Cite this entry

Glawdel, T., Ren, C. (2008). Zeta Potential Measurement. In: Li, D. (eds) Encyclopedia of Microfluidics and Nanofluidics. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-48998-8_1702

Download citation

Publish with us

Policies and ethics