Skip to main content

Transition Metal Containing Polymers

  • Reference work entry
  • First Online:
Encyclopedia of Polymeric Nanomaterials

Synonyms

Conjugated polymers; Transition metals

Definition

Transition metal-containing polymers are macromolecules that contain transition metal complex moieties at the side and/or main chains.

Introduction

Organometallic chemistry has made remarkable progress since the discovery of ferrocene in 1951 [1]. Transition metal complexes and catalysts play important role in chemical industry as well as in academic field. Ziegler-Natta catalyst found in 1950s is a monumental landmark in transition metal chemistry, which provides humankind polyolefin, an indispensable material in modern civilization. Most of synthetic polymers consist of main group elements including C, H, N, O, F, Si, P, S, and Cl. In accordance with the progress of transition metal catalyst chemistry, various polymers containing transition metals have been synthesized, and they are finding applications as polymer catalysts, redox-active materials, electron-conductive materials, photo and electroluminescent materials,...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 1,299.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 1,699.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Kealy TJ, Pauson PL (1951) A new type of organo-iron compound. Nature 168:1039–1040

    CAS  Google Scholar 

  2. Arimoto FS, Haven AC Jr (1955) Derivatives of dicyclopentadienylironl. J Am Chem Soc 77:6295–6297

    CAS  Google Scholar 

  3. Cowan DO, Park J, Pittman CU Jr, Sasaki Y, Mukherjee TK, Diamond NA (1972) Organic solid state. VII. Semiconducting polymers. Mixed valence ferrocene-ferrocenium polymers. J Am Chem Soc 94:5110–5112

    CAS  Google Scholar 

  4. Chujo Y (ed) (2011) Conjugated polymer synthesis. Wiley VCH, Weinheim

    Google Scholar 

  5. Müllen K, Reynolds JR, Masuda T (eds) (2013) Conjugated polymers. Royal Society of Chemistry, Cambridge, UK

    Google Scholar 

  6. Fujikura Y, Sonogashira K, Hagihara N (1975) Preparation and UV spectra of some oligomer-complexes composed of platinum group metals and conjugated poly-yne systems. Chem Lett 1067–1070

    Google Scholar 

  7. Takahashi S, Kariya M, Yatake T, Sonogashira K, Hagihara N (1978) Studies of poly-yne polymers containing transition metals in the main Chain. 2. Synthesis of poly[trans-bis(tri-n-butylphosphine)platinum 1,4-butadiynediyl] and evidence of a rodlike structure. Macromolecules 11:1063–1066

    Google Scholar 

  8. Takahashi S, Murata E, Kariya M, Sonogashira K, Hagihara N (1979) A new liquid-crystalline material. Transition metal-poly(yne) polymers. Macromolecules 12:1016–1017

    Google Scholar 

  9. Irwin MJ, Manojlović-Muir L, Muir KW, Puddephatt RJ, Yufit DS (1997) Trigold triacetylides: polymerization through gold···gold bonding or bridging ligands. Chem Commun 219–220. doi:10.1039/A607214C

    Google Scholar 

  10. Lohmeijer BGG, Schubert US (2004) Expanding the supramolecular polymer LEGO system: nitroxide-mediated living free-radical polymerization as a tool for mono- and telechelic polystyrenes. J Polym Sci Part A Polym Chem 42:4016–4027

    CAS  Google Scholar 

  11. Jiang B, Yang S-W, Barbini DC, Jones Jr WE (1998) Synthesis of soluble conjugated metalloporphyrin polymers with tunable electronic properties. Chem Commun 213–214

    Google Scholar 

  12. Nielsen KT, Spanggaard H, Krebs FC (2005) Synthesis, light harvesting, and energy transfer properties of a zinc porphyrin linked poly(phenyleneethynylene). Macromolecules 38:1180–1189

    Google Scholar 

  13. Schacher FH, Rupar PA, Manners I (2012) Functional block copolymers: nanostructured materials with emerging applications. Angew Chem Int Ed 51:7898–7921

    CAS  Google Scholar 

  14. Ni Y, Rulkens R, Manners I (1996) Transition metal-based polymers with controlled architectures: well-defined poly(ferrocenylsilane) homopolymers and multiblock copolymers via the living anionic ring-opening polymerization of silicon-bridged [1]ferrocenophanes. J Am Chem Soc 118:4102–4114

    CAS  Google Scholar 

  15. Kim KT, Vandermeulen GWM, Winnik MA, Manners I (2005) Organometallic-polypeptide block copolymers: synthesis and properties of poly(ferrocenyldimethylsilane)-b-poly-(γ-benzyl-l-glutamate). Macromolecules 38:4958–4961

    CAS  Google Scholar 

  16. Raez J, Manners I, Winnik MA (2002) Nanotubes from the self-assembly of asymmetric crystalline-coil poly(ferrocenylsilane-siloxane) block copolymers. J Am Chem Soc 124:10381–10395

    CAS  Google Scholar 

  17. Yashima E, Maeda K, Iida H, Furusho Y, Nagai K (2009) Helical polymers: synthesis, structures, and functions. Chem Rev 109:6102–6211

    CAS  Google Scholar 

  18. Schwartz E, Koepf M, Kitto HJ, Nolte RJM, Rowan AE (2011) Helical poly(isocyanides): past, present and future. Polym Chem 2:33–47

    CAS  Google Scholar 

  19. Sato T, Terao K, Teramoto A, Fujiki M (2003) Molecular properties of helical polysilylenes in solution. Polymer 44:5477–5495

    CAS  Google Scholar 

  20. Hill DJ, Mio MJ, Prince RB, Hughes TS, Moore JS (2001) A field guide to foldamers. Chem Rev 101:3893–4011

    CAS  Google Scholar 

  21. Shiotsuki M, Sanda F, Masuda T (2011) Polymerization of substituted acetylenes and features of the formed polymers. Polym Chem 2:1044–1058

    CAS  Google Scholar 

  22. Sakurai S, Ohira A, Suzuki Y, Fujito R, Nishimura T, Kunitake M, Yashima E (2004) Synthesis and property of helical poly(phenylacetylene)s bearing chiral ruthenium complexes and real space imaging of meso- and nanoscopic structures by atomic force microscopy. J Polym Sci Part A Polym Chem 42:4621–4640

    Google Scholar 

  23. Sanda F, Araki H, Masuda T (2005) Synthesis of Ru–coordinating helical polymer and its utilization as a catalyst for asymmetric hydrogen-transfer reaction. Chem Lett 34:1642–1643

    Google Scholar 

  24. Hida N, Takei F, Onitsuka K, Shiga K, Asaoka S, Iyoda T, Takahashi S (2003) Helical, chiral polyisocyanides bearing ferrocenyl groups as pendants: synthesis and properties. Angew Chem Int Ed 42:4349–4352

    CAS  Google Scholar 

  25. D’Amato R, Fratoddi I, Cappotto A, Altamura P, Delfini M, Bianchetti C, Bolasco A, Polzonetti G, Russo MV (2004) Organometallic platinum(II) and palladium(II) polymers containing 2,6-diethynyl-4-nitroaniline bridging spacer and related dinuclear model complexes. Organometallics 23:2860–2869

    Google Scholar 

  26. Zhang H-C, Huang W-S, Pu L (2001) Biaryl-based macrocyclic and polymeric chiral (salophen)Ni(II) complexes: synthesis and spectroscopic study. J Org Chem 66:481–487

    CAS  Google Scholar 

  27. Maeda T, Takeuchi T, Furusho Y, Takata T (2004) Design and synthesis of chiral poly(binaphthyl salen zinc complex) and application of the asymmetric field based on its helical conformation to a catalytic asymmetric reaction. J Polym Sci Part A Polym Chem 42:4693–4703

    CAS  Google Scholar 

  28. Readers who need more detailed information on transition metal-containing polymers, see Abd-El-Aziz, AS, Manners, I (eds) (2007) Frontiers in transition metal-containing polymers. Wiley-Interscience, Hoboken

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Fumio Sanda .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer-Verlag Berlin Heidelberg

About this entry

Cite this entry

Sanda, F. (2015). Transition Metal Containing Polymers. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-29648-2_383

Download citation

Publish with us

Policies and ethics