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Synthesis of Star Polymers

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Encyclopedia of Polymeric Nanomaterials

Synonyms

Star-branched polymers

Definition

Star polymers are defined as polymers having at least three polymer chains (arms) radiating from a core. If all arms are identical, it is regular or symmetric star, and if all arms or some of them are different, it is miktoarm (mikto coming from the Greek word μικτός, meaning mixed) star or asymmetric star-branched polymer. There are three types of asymmetric star-branched polymers based on (1) molecular weight asymmetry, (2) topological asymmetry, and (3) functional group asymmetry (Fig. 1).

Synthesis of Star Polymers, Fig. 1
figure 17270 figure 17270

Classification of star-branched polymers

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References

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Acknowledgment

The author KR would like to thank Dr. P. K. Zubaidha, Head of Organic Chemistry, School of Chemical Sciences, S. R. T. M. University, Nanded, for her continuous support during the work.

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Correspondence to Nikos Hadjichristidis .

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Hadjichristidis, N., Ratkanthwar, K., Pitsikalis, M., Iatrou, H. (2015). Synthesis of Star Polymers. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-29648-2_38

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