Synonyms
Aqueous reaction; Interface catalysis pickering emulsions
Definition
Due to the large reaction interface area, Pickering emulsions are emerging as a new platform to design a variety of aqueous reaction systems. The catalysis efficiency and selectivity can be significantly enhanced with the unique oil/water interface.
Background
Using water as reaction solvent is a long-standing goal in view of the fact that all reactions in living systems occur in water and of its unique properties such as low toxicity, noninflammability, low volatility, high heat capacity, and easy separation from most organics [1, 2]. In past decades, researchers have attempted to utilize water as reaction medium in place of organic solvents. Many important reactions such as hydrogenation, oxidation, hydroformylation, C–C coupling, Diels–Alder cycloadditions, Claisen rearrangements, and Fischer–Tropsch (F-T) synthesis have been carried out in water. Among these reactions, aqueous hydroformylation and...
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Yang, H., Rong, X., Wang, D. (2015). Surface Active Nanoparticles for Interfacial Catalysis. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-29648-2_360
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DOI: https://doi.org/10.1007/978-3-642-29648-2_360
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