Synonyms
Acetal; Acetal polymer; Acetal resin; Polyformaldehyde
Definition
Polyoxymethylenes are commercially available engineering thermoplastics used in precision parts requiring high mechanical strength, stiffness, toughness in the wide range of temperature and environment.
POM (Polyoxymethylenes)
Polyoxymethylenes (POM) (Eq. 1), sometimes called acetal polymer or acetal resins, are highly crystalline thermoplastic materials exhibiting a broad array of useful properties including high mechanical strength, stiffness, and toughness in the wide range of temperature and environment [1–5]. In many practical applications, POM have replaced metals in a variety of precision parts because of balanced properties as engineering plastics. POM are the first commercial engineering plastic, and they still play an important role in our life. A huge amount of POM is currently manufactured by many companies, and further new high-performance POM are developed.
Historical Part in Industry
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References
Persak KJ, Fleming RA (1986) The history of acetal homopolymer. In: Seymour RB, Kirshenbaum GS (eds) High performance polymers: their origin and development. Elsevier, New York, pp 105–114
Dolce TJ, McAndrew FB (1986) Acetal copolymer, a historical perspective. In: Seymour RB, Kirshenbaum GS (eds) High performance polymers: their origin and development. Elsevier, New York, pp 115–124
Serle AG (1985) Acetals. In: Margolis JM (ed) Engineering thermoplastics, properties and applications. Marcel Dekker, New York, pp 151–175
Forschirm A, McAndrew FB (1996) Acetal resins. In: Salamone JC (ed) Polymeric materials encyclopedia, vol 1. CRC Press, New York, pp 6–11
Masamoto J (1993) Modern polyacetals. Prog Polym Sci 18:1–84
Staudinger H (1920) Uber polymerisation. Ber dtsch Chem Ges A/B 53:1073–1085
MacDonald RN (1956) Polyoxymethylens. US Patent 2,768,994
Walling CT, Brown F, Bartz KW (1962) Copolymers. US Patent 3,027,352
Vogl O (2000) Addition polymers of aldehydes. J Polym Sci Part A: Polym Chem 38:2293–2299
Smith MB, March J (1992) March’s advanced organic chemistry, reactions, mechanisms, and structure, 5th edn. Wiley-Interscience, New York, pp 465–468
Ofstead EA (1990) Polyacetals. In: Kroschwitz JI (ed) Concise encyclopedia of polymer science and engineering. Wiley-Interscience, New York, p 746
Hefferman MJ, Murthy N (2005) Polyketal nanoparticles: a new pH-sensitive biodegradable drug delivery vehicle. Bioconjug Chem 16:1340–1342
Heller J, Penhale DWH, Helwing RF (1980) Preparation of polyacetals by the reaction of divinyl ethers and polyols. J Polym Sci Polym Lett Ed 18:293–297
Zhang H, Ruckenstein E (2000) Self-polyaddition of hydroxyalkyl vinyl ethers. J Polym Sci Part A Polym Chem 38:3751–3760
Hashimoto T, Ishizuka K, Umehara A, Kodaira T (2002) Synthesis of polyacetals with various main-chain structures by the self-polyaddition of vinyl ethers with a hydroxyl function. J Polym Sci Part A Polym Chem 40:4053–4064
Hashimoto T, Umehara A, Urushisaki M, Kodaira T (2004) Synthesis of a new degradable polyurethane elastomer containing polyacetal soft segments. J Polym Sci Part A Polym Chem 42:2766–2773
Hashimoto T, Meiji H, Urushisaki M, Sakaguchi T, Kawabe K, Tsuchida C, Kondo K (2012) Degradable and chemically recyclable epoxy resins containing acetal linkages: synthesis, properties, and application for carbon fiber-reinforced plastics. J Polym Sci Part A Polym Chem 50:3674–3681
Falco EE, Patel M, Fisher JP (2008) Recent developments in cyclic acetal biomaterials for tissue engineering applications. Pharm Res 25:2348–2356
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Hashimoto, T., Sakaguchi, T. (2015). POM (Polyoxymethylenes), Polyacetals. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-29648-2_256
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