Synonyms
Organic field-effect transistor; Organic semiconductor; Plastic electronics
Definition
Polymer: A polymer is a macromolecule with high molecular mass and composed of the repetition of structural units of significantly lower molecular weights. Polymers often possess very different chemical and physical properties compared to the smaller molecules they are composed of.
Transistor: A transistor is a semiconducting device that is used to switch and amplify electronic signals. The electric current flows between two electrodes, source and drain, and is controlled by an electric field applied to a third electrode, the gate.
Historical Background
The field-effect transistor principle was first patented in 1925 by Julius Edgar Lilienfeld, but it would take nearly another quarter of a century until the first working field-effect transistor (FET) based on a germanium crystal was built at Bell Laboratories in 1948 by William Shockley, John Bardeen, and Walter Brattain. Since its...
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Arias AC et al (2010) Materials and applications for large area electronics: solution-based approaches. Chem Rev 110:3–24
Hamilton R et al (2010) Development of polymer semiconductors for field-effect transistor devices in displays. In: Franky So (ed) Organic electronics: materials, processing, devices and applications, CRC Press, Boca Raton, Fl, p 393
Klauk H (2006) Organic electronics, 1st edn. Wiley-VCH, Weinheim
Schroeder BC (2013) New thiophene based semiconducting materials for applications in plastic electronics. Department of Chemistry, Imperial College London, London
Skotheim A, Reynolds JR (2007) Handbook of conducting polymers, 3rd edn. CRC Press, Boca Raton/London
Chochos CL, Choulis SA (2011) How the structural deviations on the backbone of conjugated polymers influence their optoelectronic properties and photovoltaic performance. Prog Polym Sci 36(10):1326–1414
Mei J et al (2013) Integrated materials design of organic semiconductors for field-effect transistors. J Am Chem Soc 135(18):6724–6746
Lei T, Wang J-Y, Pei J (2014) Roles of flexible chains in organic semiconducting materials. Chem Mater 26(1):594–603
Mei J, Bao Z (2014) Side chain engineering in solution-processable conjugated polymers for organic solar cells and field-effect transistors. Chem Mater 26(1):604–615
Peet J et al (2009) The role of processing in the fabrication and optimization of plastic solar cells. Adv Mater 21(14–15):1521–1527
McCulloch I et al. (2012) Design of semiconducting indacenodithiophene polymers for high performance transistors and solar cells. Acc Chem Res 45(5):714–722
Yu C-Y et al (2009) Thiophene/phenylene/thiophene-based low-bandgap conjugated polymers for efficient Near-infrared photovoltaic applications. Chem Mater 21(14):3262–3269
Nielsen CB, McCulloch I (2013) Recent advances in transistor performance of polythiophenes. Progress Polym Sci 38(12):2053–2069
Osaka I, McCullough RD (2008) Advances in molecular design and synthesis of regioregular polythiophenes. Acc Chem Res 41:1202–1214
Kline R et al (2005) Dependence of regioregular poly(3-hexylthiophene) film morphology and field-effect mobility on molecular weight. Macromolecules 38:3312–3319
Ong BS et al (2004) High-performance semiconducting polythiophenes for organic thin-film transistors. J Am Chem Soc 126(11):3378–3379
McCulloch I et al (2009) Semiconducting thienothiophene copolymers: design, synthesis, morphology, and performance in thin-Film organic transistors. Adv Mater 21:1091–1109
Zhang M et al (2007) Field-effect transistors based on a benzothiadiazole–cyclopentadithiophene copolymer. J Am Chem Soc 129(12):3472–3473
Wang S et al (2012) Organic field-effect transistors based on highly ordered single polymer fibers. Adv Mater 24(3):417–420
Zhang WM et al (2010) Indacenodithiophene semiconducting polymers for high-performance, air-stable transistors. J Am Chem Soc 132(33):11437–11439
Nielsen CB, Turbiez M, McCulloch I (2013) Recent advances in the development of semiconducting DPP-containing polymers for transistor applications. Adv Mater 25(13):1859–1880
Li Y et al (2013) High mobility diketopyrrolopyrrole (DPP)-based organic semiconductor materials for organic thin film transistors and photovoltaics. Energy Environ Sci 6(6):1684–1710
Chen Z et al (2012) High-performance ambipolar diketopyrrolopyrrole-thieno[3,2-b]thiophene copolymer field-effect transistors with balanced hole and electron mobilities. Adv Mater 24(5):647–652
Kronemeijer AJ et al (2012) A selenophene-based low-bandgap donor–acceptor polymer leading to fast ambipolar logic. Adv Mater 24(12):1558–1565
Bronstein H et al (2011) Thieno[3,2-b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices. J Am Chem Soc 133:3272–3275
Anthony JE et al (2010) n-type organic semiconductors in organic electronics. Adv Mater 22:3879–3892
Zhan X et al (2011) Rylene and related diimides for organic electronics. Adv Mater 23(2):268–284
Yan H, Chen Z, Zheng Y, Newman C, Quinn JR, Dötz F, Kastler M, Facchetti A (2009) A high-mobility electron-transporting polymer for printed transistors. Nature 457:679–686
Rivnay J et al (2010) Unconventional face-on texture and exceptional in-plane order of a high mobility n-type polymer. Adv Mater 22(39):4359–4363
Author information
Authors and Affiliations
Corresponding authors
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer-Verlag Berlin Heidelberg
About this entry
Cite this entry
Schroeder, B.C., McCulloch, I. (2015). Polymers for Transistors. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-29648-2_13
Download citation
DOI: https://doi.org/10.1007/978-3-642-29648-2_13
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-29647-5
Online ISBN: 978-3-642-29648-2
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics