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Definition
Ethyl formate is among the largest organic molecules unambiguously detected by radio astronomers in the interstellar medium. It is also called ethyl methanoate. Ethyl formate is partly responsible for the flavor of raspberries, and it has the characteristic odor of rum.
History
The trans conformer of ethyl formate was detected in the Galactic Center molecular cloud Sagittarius B2(N) by Belloche et al. (2009), who suggest that it may be produced by surface reactions on interstellar dust grains, perhaps involving precursors such as methyl formate and ethanol (for the definition of conformers, see isomer). More recently, the gauche conformer has also been detected, in a line survey of the Orion molecular cloud (Tercero et al. 2013). Ethyl formate is the second formate, after methyl formate, to be detected in the interstellar medium. Its isomer methyl acetate (CH3COOCH3) has also been recently detected in a molecular cloud in the Milky Way.
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References and Further Reading
Belloche A, Garrod RT, Müller HSP, Menten KM, Comito C, Schilke P (2009) Increased complexity in interstellar chemistry: detection and chemical modeling of ethyl formate and n-propyl cyanide in Sagittarius B2(N). Astron Astrophys 499:215–232
Tercero B, Kleiner I, Cernicharo J, Nguyen HVL, López A, Muñoz Caro GM (2013) Discovery of methyl acetate and gauche ethyl formate in Orion. Astrophys J 770:L13–L19
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© 2014 Springer-Verlag Berlin Heidelberg
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Irvine, W.M. (2014). Ethyl Formate. In: Amils, R., et al. Encyclopedia of Astrobiology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-27833-4_5103-1
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DOI: https://doi.org/10.1007/978-3-642-27833-4_5103-1
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Publisher Name: Springer, Berlin, Heidelberg
Online ISBN: 978-3-642-27833-4
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