Atomic Symbol: Tl
Atomic Number: 81
Atomic Weight: 204.3833 (2)
Isotopes and Abundances: 203Tl (29.524%) and 205Tl (70.476%)
1 Atm Melting Point: 577 K
1 Atm Boiling Point: 1746 K
Common Valences: +1 and +3
Ionic Radii: 164 pm (+1), 102.5 pm (+3)
Pauling Electronegativity: 1.62
First Ionization Energy: 589.4 kJ mol−1
Chondritic (CI) Abundance: 0.143 ppm
Silicate Earth Abundance: 0.004 ppm
Crustal Abundance: 0.5 ppm
Seawater Abundance: 10–20 ng/l
Core Abundance: 0.03 ppm
Introduction
Thallium (Tl) is a soft blue-grey metal that is present in trace quantities in the Earth’s crust and is highly toxic either as a metal or as one of many compounds. It was first discovered in 1861 by William Crookes, and Tl metal was first isolated in 1862 by both Crookes and Claude-August Lamy (Peter and Viraraghavan 2005). Thallium has an atomic number of 81, atomic weight of 204.37, and is in group 13 of the periodic table. It has two oxidation states...
References
Flegal, A. R., and Patterson, C. C., 1985. Thallium concentrations in seawater. Marine Chemistry, 15(4), 327–331.
Galván-Arzate, S., & SantamarÃa, A. (1998). Thallium toxicity. Toxicology letters, 99(1), 1–13.
Heinrichs, H., Schulz-Dobrick, B., and Wedepohl, K. H., 1980. Terrestrial geochemistry of Cd, Bi, Tl, Pb, Zn and Rb. Geochimica et Cosmochimica Acta, 44(10), 1519–1533.
Jakubowska, M., Pasieczna, A., Zembrzuski, W., Świt, Z., and Lukaszewski, Z., 2007. Thallium in fractions of soil formed on floodplain terraces. Chemosphere, 66(4), 611–618.
Karlsson, U., Karlsson, S., & Düker, A. (2006). The effect of light and iron (II)/iron (III) on the distribution of Tl (I)/Tl (III) in fresh water systems. Journal of Environmental Monitoring, 8(6), 634–640.
Kazantzis, G., 2000. Thallium in the environment and health effects. Environmental Geochemistry and Health, 22(4), 275–280.
LaCoste, C., Robinson, B., and Brooks, R., 2001. Uptake of thallium by vegetables: Its significance for human health, phytoremediation, and phytomining. Journal of Plant Nutrition, 24(8), 1205–1215.
Nielsen, S. G., and Rehkämper, M., 2012. Thallium isotopes and their application to problems in earth and environmental science. In Handbook of Environmental Isotope Geochemistry. Berlin/Heidelberg: Springer, pp. 247–269.
Peter, A. J., and Viraraghavan, T., 2005. Thallium: a review of public health and environmental concerns. Environment International, 31(4), 493–501.
Rehkämper, M., and Nielsen, S. G., 2004. The mass balance of dissolved thallium in the oceans. Marine Chemistry, 85(3), 125–139.
Shaw, D. M., 1952. The geochemistry of thallium. Geochimica et Cosmochimica Acta, 2(2), 118–154.
Tremel, A., Masson, P., Sterckeman, T., Baize, D., and Mench, M., 1997. Thallium in French agrosystems – I. Thallium contents in arable soils. Environmental Pollution, 95(3), 293–302.
Wedepohl, K. H., 1995. The composition of the continental crust. Geochimica et cosmochimica Acta, 59(7), 1217–1232.
Zhou, T. F., Fan, Y., Yuan, F., Wu, M. A., Hou, M. J., Voicu, G., … & Yue, S. C., 2005. A preliminary geological and geochemical study of the Xiangquan thallium deposit, eastern China: the world’s first thallium-only mine. Mineralogy and Petrology, 85(3–4), 243–251.
Acknowledgments
Prepared by LLNL under Contract DE-AC52-07NA27344.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this entry
Cite this entry
Wimpenny, J. (2016). Thallium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_52-1
Download citation
DOI: https://doi.org/10.1007/978-3-319-39193-9_52-1
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Online ISBN: 978-3-319-39193-9
eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences