Table A1 Chemical characteristics of natural waters
From: Aqueous solutions
Environment | pH range | Eh range (V) | Major ions (in order of abundance) | Dissolved organic carbon (mg/l) |
---|---|---|---|---|
Rainwater | Â | Â | Â | Â |
 Continental | 4–6 | Oxic | SO2− 4, Ca2+, Cl− NO− 3, Na+, K+, NH+ 4, Mg2+ | ? |
 Marine and coastal | 5–6 | Oxic | Cl−, Na+, SO2− 4, Mg2+, Ca2+, K+, NO− 3, NH+ 4 | ? |
Rivers | 5–9 | 0.3–0.5 | HCO− 3, Ca2+, H4SiO4, SO2− 4, Cl−, Na+, Mg2+, K+ | <1–>30 |
Lakes | Â | Â | Â | Â |
 Fresh | 5–9 | −0.1–0.5 | HCO− 3, Ca+ 2, H4SiO4, SO2− 4, Cl−, Na+, Mg2+, K+ | <1–>100 |
 Saline | 5–10 | −0.1–0.5 | Cl−, Na+, SO2− 4, HCO− 3, Mg2+, K+, Ca+ 2, H4SiO4 | <1–>100 |
Shallow groundwater | 6–8.5 | −0.1–0.45 | HCO− 3, SO2− 4, Ca2+ Na+, Cl−, Mg2+, K+, Ca2+,H4SiO4, K+ | <1–20 |
Marine | 7.5–8.4 | 0.2–0.4 | Cl−, Na+, SO2− 4, Mg2+, Ca2+, K+ | <0.1–3 |
Evaporative marine | 7.5–9.0 | Oxic or anoxic | As for marine then inc. Mg2+ with mineral ppt. | ? |
Brackish marine | 7.5–8.4 | Oxic or anoxic | As for marine | ? |
Deep connate groundwater | 6.0–8.0 | −0.25–0.4 | Cl−, Na+, K+, SO2− 4, Ca2+, Mg2+, | <10–4500 |