Skip to main content

Near-Infrared Reflectance Spectroscopy

Methodology and Potential for Predicting Trace Elements in Plants

  • Protocol
Phytoremediation

Part of the book series: Methods in Biotechnology ((MIBT,volume 23))

Abstract

Near-infrared spectroscopy (NIRS) has been applied for decades to the analysis of agrifood products, and in recent years its use has been extended to the determination of mineral species and trace elements in organic and inorganic matrices. The near-infrared region (NIR) spectrum contains physical and chemical information of the product being analyzed. The spectral information has its origin in the different vibrational modes of the molecules caused by their interaction with the electromagnetic radiation absorbed at wavelengths between 750 and 2500 nm. The use of chemometrics allows the relevant information contained in the NIR spectra to be extracted to develop calibration models that permit the prediction of the composition of unknown samples. The technique is rapid and, in contrast to the standard techniques of analysis, can be performed at a low analytical cost and without using chemicals. In addition, those error sources related with laboratory analysis are avoided. The control of those sources of error specific to the NIR analysis leads to equations of high accuracy and precision. The application of NIRS to the determination of arsenic, lead, copper, and zinc in wild and cultivated plant species has revealed its potential in the screening of these elements for phytoremediation purposes.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Protocol
USD 49.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Norris, K. H. (1996) History of NIR. J. Near Infrared Spectrosc. 4, 31–37.

    CAS  Google Scholar 

  2. Williams, P. C. (1995) Near infrared technology in Canada. NIR News 6, 12–13.

    Google Scholar 

  3. Blanco, M. and Villarroya, I. (2002) NIR spectroscopy: a rapid-response analytical tool. Trends Anal. Chem. 21, 240–250.

    Article  CAS  Google Scholar 

  4. Murray, I. and Williams, P. C. (1987) Chemical principles of near infra-red technology.In: Near-Infrared Technology in the Agricultural and Food Industries, (Williams, P. C. and Norris, K.eds.), American Association of Cereal Chemists Inc., St. Paul, MN, pp. 17–34.

    Google Scholar 

  5. Ciurczak, E. (1992) Principles of near-infrared spectroscopy. In: Handbook of Near-Infrared Analysis, (Burns, D. A. and Ciurczak, E. Weds.), Dekker Inc., New York, pp. 7–11.

    Google Scholar 

  6. Osborne, B. G., Fearn, T., and Hindle, P. H. (1993) Practical NIR Spectroscopy with Applications in Food and Beverage Analysis. Longman Scientific and Technical, Essex, England.

    Google Scholar 

  7. Shenk, J. S., Westerhaus, M. O., and Hoover, M. R. (1979) Analysis of forages by infrared reflectance. J. Dairy Sci. 62, 807–812.

    Article  CAS  Google Scholar 

  8. Shenk, J. S., Landa, I., Hoover, M. R., and Westerhaus, M. O. (1981) Description and evaluation of a near infrared reflectance spectroscopy computer for forage and grain analysis. Crop. Sci. 21, 355–358.

    Article  CAS  Google Scholar 

  9. García-Ciudad, A., García-Criado, B., and Ponton San Emeterio, C. (1985) Determination of fluoride in plant samples by a potentiometric method and nearinfrared reflectance spectroscopy. Comm. Soil Sci. Plant Anal. 16, 1107–1122.

    Article  Google Scholar 

  10. McClure, W. F., Crowell, B., Stanfield, D. L., Mohapatra, S., Morimoto, S., and Batten, G. (2002) Near infrared technology for precision environmental measurements: part 1. Determination of nitrogen in green-and dry-grass tissue. J. Near Infrared Spectrosc. 10, 177–185.

    Article  CAS  Google Scholar 

  11. Morón, A. and Cozzolino, D. (2002) Determination of macro-elements in alfalfa and white clover by near-infrared reflectance spectroscopy. J. Agr. Sci. 139, 413–423.

    Article  Google Scholar 

  12. Sauvage, L., Frank, D., Stearne, J., and Millikan, M. B. (2002) Trace metal studies of selected white wines: an alternative approach. Anal. Chim. Acta 458, 223–230.

    Article  CAS  Google Scholar 

  13. Font, R., Del Río, M., and De Haro, A. (2002) Use of near infrared spectroscopy to evaluate heavy metal content in Brassica juncea plants cultivated on the polluted soils of the Guadiamar river area. Fresen. Environ. Bull. 11, 777–781.

    CAS  Google Scholar 

  14. Font, R., Del Río, M., Vélez, D., Montoro, R., and De Haro, A. (2004) Use of nearinfraredspectroscopy for determining the total arsenic content in prostrate amaranth. Sci. Total Environ. 327, 93–104.

    Article  CAS  Google Scholar 

  15. Shenk, J. S., Workman, J. J., Jr., and Westerhaus, M. O. (1992) Application of NIR spectroscopy to agricultural products. In: Handbook of Near-Infrared Analysis, (Burns, D. A. and Ciurczak, E. Weds.), Dekker Inc., New York, pp. 383–431.

    Google Scholar 

  16. Clark, D. H., Mayland, H. F., and Lamb, R. C. (1987) Mineral analysis of forages with near infrared reflectance spectroscopy. Agron. J. 79, 485–490.

    Article  CAS  Google Scholar 

  17. Grill, E., Winnacker, E. L., and Zenk, M. H. (1987) Phytochelatins, a class of heavy-metal-binding peptides from plants, are functionally analogous to metallothioneins. Proc. Natl. Acad. Sci. 84, 439–443.

    Article  CAS  Google Scholar 

  18. Hartley-Whitaker, J., Ainsworth, G., and Meharg, A. A. (2001) Copper-and arsenateinducedoxidative stress in Holcus lanatus L. clones with different sensitivity. Plant Cell Environ. 24, 713–722.

    Article  CAS  Google Scholar 

  19. Simola, L. K. (1977) The effect of lead, cadmium, arsenate and fluoride ions on the growth and fine structure of Sphagnum nemoreum in aseptic culture. Can. J. Bot. 90, 375–405.

    Google Scholar 

  20. Meeta-Jain, R. P. and Gadre, R. P. (1997) Effect of As on chlorophyll and protein contents and enzymatic activities in greening maize leaves. Water Air Soil Pollut. 93, 109–115.

    Google Scholar 

  21. Williams, P. C. (1992) Samples, sample preparation, and sample selection. In: Handbook of Near-Infrared Analysis, (Burns, D. A. and Ciurczak, E. Weds.), Dekker Inc., New York, pp. 281–315.

    Google Scholar 

  22. Williams, P. C. and Norris, K. H. (1983) Effect of mutual interactions on the estimation of protein and moisture in wheat. Cereal Chem. 60, 202–207.

    Google Scholar 

  23. Williams, P. C., Norris, K. H., and Zarowski, W. S. (1982) Influence of temperature on estimation of protein and moisture in wheat. Cereal Chem. 59, 473–477.

    Google Scholar 

  24. Shenk, J. S. and Westerhaus, M. (1991) Population definition, sample selection, and calibration procedures for near infrared reflectance spectroscopy. Crop Sci. 31,469–474.

    Article  Google Scholar 

  25. Shenk, J. S. and Westerhaus, M. (1991) Population structuring of near infraredspectra and modified partial least squares regression. Crop Sci. 31, 1548–1555.

    Article  CAS  Google Scholar 

  26. Williams, P. C. and Sobering, D. C. (1996) How do we do it: a brief summary ofthe methods we use in developing near infrared calibrations. In: Near Infrared Spectroscopy: The Future Waves, (Davies, A. M. C. and Williams, P. C.eds.), NirPublications, Chichester, UK, pp. 185–188.

    Google Scholar 

  27. Giese, A. T. and French, C. S. (1955) The analysis of overlapping spectral absorptionbands by derivative spectrophotometry. Appl. Spectrophot. 9, 78–96.

    Article  CAS  Google Scholar 

  28. Barnes, R. J., Dhanoa, M. S., and Lister, S. J. (1989) Standard normal variate transformationand de-trending of near-infrared diffuse reflectance spectra. Appl. Spectrosc. 43, 772–777.

    Article  CAS  Google Scholar 

  29. Martens, H. and Naes, T. (1989) Multivariate Calibration. John Wiley and Sons, New York, NY.

    Google Scholar 

  30. Workman, J. J.,Jr. (1992) Nir spectroscopy calibration basics. In: Handbook of Near-Infrared Analysis, (Burns, D. A. and Ciurczak, E. W.eds.), Dekker Inc., NewYork, NY, pp. 247–280.

    Google Scholar 

  31. Shenk, J. S. and Westerhaus, M. O. (1996) Calibration the ISI way. In: NearInfrared Spectroscopy: The Future Waves, (Davies, A. M. C. and Williams, P. C.eds.), Nir Publications, Chichester, UK, pp. 198–202.

    Google Scholar 

  32. Williams, P. C. (1987) Variables affecting near-infrared reflectance spectroscopicanalysis. In: Near-Infrared Technology in the Agricultural and Food Industries,(Williams, P. C. and Norris, K.eds.), American Association of Cereal Chemists,Inc., St. Paul, MN, pp. 143–167.

    Google Scholar 

  33. Shenk, J. S. and Westerhaus, M. O. (1993) Near infrared reflectance analysis withsingle-and multiproduct calibrations. Crop Sci. 33, 582–584.

    Article  CAS  Google Scholar 

  34. Font, R., Del Río, M., Fernández, J. M., and De Haro, A. (2003). Acid detergentfiber analysis in oilseed Brassicas by near-infrared spectroscopy. J. Agr. FoodChem. 51, 2917–2922.

    Article  CAS  Google Scholar 

  35. Clark, D. H., Cary, E. E., and Mayland, H. F. (1989) Analysis of trace elements inforages by near infrared reflectance spectroscopy. Agron. J. 81, 91–95.

    Article  CAS  Google Scholar 

  36. Dunn, B. W., Beecher, H. G., Batten, G. D., and Ciavarella, S. (2002) The potentialof near infrared reflectance spectroscopy for soil analysis-a case study fromthe Riverine Plain of south-eastern Australia. Aust. J. Exp. Agr. 42, 607–611.

    Article  Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2007 Humana Press Inc., Totowa, NJ

About this protocol

Cite this protocol

Font, R., del Río-Celestino, M., de Haro-Bailón, A. (2007). Near-Infrared Reflectance Spectroscopy. In: Willey, N. (eds) Phytoremediation. Methods in Biotechnology, vol 23. Humana Press. https://doi.org/10.1007/978-1-59745-098-0_17

Download citation

  • DOI: https://doi.org/10.1007/978-1-59745-098-0_17

  • Publisher Name: Humana Press

  • Print ISBN: 978-1-58829-541-5

  • Online ISBN: 978-1-59745-098-0

  • eBook Packages: Springer Protocols

Publish with us

Policies and ethics