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Mechanochemical promotion with molybdenum and catalytic activity of skeletal nickel catalysts in hydrogenation reactions

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Abstract

The possibility of mechanochemical promotion of skeletal nickel catalysts has been shown with the use of mechanical Ni−Al−Mo alloys as Raney nickel precursors in hydrogenation reactions. The mechanochemical promotion makes it possible to introduce molybdenum atoms into the catalyst lattice in the form of a solid solution. These catalysts are more active than pyrometallurgical ones. The increased activity of the catalysts in explained by changes in the structure and energetic state of the catalyst surface

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Kutateladze 18, 630128, Novosibirsk, Russia

    G. V. Golubkova & O. I. Lomovsky

  2. Ivanovo State Chemical Technological Academy, F. Engels, 7, Ivanovo, Russia

    I. N. Bazanova, V. P. Gostikin & L. G. Nischenkova

Authors
  1. G. V. Golubkova
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  2. I. N. Bazanova
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  3. V. P. Gostikin
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  4. L. G. Nischenkova
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  5. O. I. Lomovsky
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Golubkova, G.V., Bazanova, I.N., Gostikin, V.P. et al. Mechanochemical promotion with molybdenum and catalytic activity of skeletal nickel catalysts in hydrogenation reactions. React Kinet Catal Lett 67, 169–175 (1999). https://doi.org/10.1007/BF02475844

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  • DOI: https://doi.org/10.1007/BF02475844

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