Abstract
We have prepared potassium intercalated 1,2;8,9-dibenzopentacene films under vacuum conditions. The evolution of the electronic excitation spectra upon potassium addition as measured using electron energy-loss spectroscopy clearly indicate the formation of particular doped phases with compositions K x dibenzopentacene (x = 1, 2, 3). Moreover, the stability of these phases as a function of temperature has been explored. Finally, the electronic excitation spectra also give insight into the electronic ground state of the potassium doped 1,2;8,9-dibenzopentacene films.
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References
N.B. Hannay, T.H. Geballe, B.T. Matthias, K. Andres, P. Schmidt, D. MacNair, Phys. Rev. Lett. 14, 225 (1965)
N. Emery, C. Hérold, M. d’Astuto, V. Garcia, C. Bellin, J.F. Marêché, P. Lagrange, G. Loupias, Phys. Rev. Lett. 95, 087003 (2005)
A. Hebard, M. Rosseinsky, R. Haddon, D. Murphy, S. Glarum, T. Palastra, A. Ramirez, A. Kortan, Nature 350, 600 (1991)
O. Gunnarson, Alkali Doped Fullerides (World Scientific, Singapore, 2004)
K. Tanigaki, T. Ebbesen, S. Saito, J. Mizuki, J. Tsai, Y. Kubo, S. Kuroshima, Nature 352, 222 (1991)
A.Y. Ganin, Y. Takabayashi, Y.Z. Khimyak, S. Margadonna, A. Tamai, M.J. Rosseinsky, K. Prassides, Nat. Mater. 7, 367 (2008)
A.Y. Ganin et al., Nature 466, 221 (2010)
T. Palstra, O. Zhou, Y. Iwasa, P. Sulewski, R. Fleming, B. Zegarski, Solid State Commun. 93, 327 (1995)
M. Craciun, S. Rogge, M. den Boer, S. Margadonna, K. Prassides, Y. Iwasa, A. Morpurgo, Adv. Mater. 18, 320 (2006)
H. Rauf, T. Pichler, M. Knupfer, J. Fink, H. Kataura, Phys. Rev. Lett. 93, 096805 (2004)
M.F. Craciun, G. Giovannetti, S. Rogge, G. Brocks, A.F. Morpurgo, J. van den Brink, Phys. Rev. B 79, 125116 (2009)
R. Mitsuhashi et al., Nature 464, 76 (2010)
X. Wang, R. Liu, Z. Gui, Y. Xie, Y. Yan, J. Ying, X. Luo, X. Chen, Nat. Commun. 2, 507 (2011)
P.L. de Andres, A. Guijarro, J.A. Vergés, Phys. Rev. B 84, 144501 (2011)
Y. Kubozono et al., Phys. Chem. Chem. Phys. 13, 16476 (2011)
M. Xue, T. Cao, D. Wang, Y. Wu, H. Yang, X. Dong, J. He, F. Li, G.F. Chen, Sci. Rep. 2, 1 (2012)
Y. Takabayashi et al., Science 323, 1585 (2009)
P.J. Benning, D.M. Poirier, T.R. Ohno, Y. Chen, M.B. Jost, F. Stepniak, G.H. Kroll, J.H. Weaver, J. Fure, R.E. Smalley, Phys. Rev. B 45, 6899 (1992)
F. Stepniak, P.J. Benning, D.M. Poirier, J.H. Weaver, Phys. Rev. B 48, 1899 (1993)
J. Weaver, P. Benning, F. Stepniak, D. Poirier, J. Phys. Chem. Solids 53, 1707 (1992)
D.M. Poirier, D.W. Owens, J.H. Weaver, Phys. Rev. B 51, 1830 (1995)
M. Knupfer, D.M. Poirier, J.H. Weaver, Phys. Rev. B 49, 8464 (1994)
M.J. Rosseinsky, J. Mater. Chem. 5, 1497 (1995)
T. Pichler, R. Winkler, H. Kuzmany, Phys. Rev. B 49, 15879 (1994)
H. Kuzmany, R. Winkler, T. Pichler, J. Phys.: Condens. Matter 7, 6601 (1995)
R. Schuster, M. Knupfer, H. Berger, Phys. Rev. Lett. 98, 037402 (2007)
F. Roth, A. König, R. Kraus, M. Grobosch, T. Kroll, M. Knupfer, Eur. Phys. J. B 74, 339 (2010)
M. Knupfer, T. Pichler, M.S. Golden, J. Fink, M. Murgia, R.H. Michel, R. Zamboni, C. Taliani, Phys. Rev. Lett. 83, 1443 (1999)
J. Fink, Adv. Electron. Electron Phys. 75, 121 (1989)
R. Egerton, Electron Energy-Loss Spectroscopy in the Electron Microscope, 2nd edn. (Springer, 1996)
F. Roth, A. König, R. Kraus, M. Knupfer, J. Chem. Phys. 128, 194711 (2008)
F. Roth, M. Gatti, P. Cudazzo, M. Grobosch, B. Mahns, B. Büchner, A. Rubio, M. Knupfer, New J. Phys. 12, 103036 (2010)
M. Knupfer, T. Pichler, M.S. Golden, J. Fink, A. Rinzler, R.E. Smalley, Carbon 37, 733 (1999)
M. Knupfer, J. Fink, J. Armbruster, H. Romberg, Z. Phys. B 98, 9 (1995)
M. Knupfer, Surf. Sci. Rep. 42, 1 (2001)
K. Flatz, M. Grobosch, M. Knupfer, J. Chem. Phys. 126, 214702 (2007)
E. Clar, Berichte der deutschen chemischen Gesellschaft (A and B Series) 76, 257 (1943)
E. Clar, Z. Chemie 2, 35 (1962)
H.H. Perkampus, L. Pohl, Theoretical Chemistry Accounts: Theory, Computation, and Modeling (TCA) 1, 116 (1963)
M. Pope, C.E. Swenberg, Electronic Processes in Organic Crystals and Polymers, 2nd edn. (Oxford University Press, New York, 1999)
R.W. Lof, M.A. van Veenendaal, B. Koopmans, H.T. Jonkman, G.A. Sawatzky, Phys. Rev. Lett. 68, 3924 (1992)
I. Hill, A. Kahn, Z. Soos, R. Pascal, Chem. Phys. Lett. 327, 181 (2000)
B. Mahns, F. Roth, M. Knupfer, J. Chem. Phys. 136, 134503 (2012)
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Roth, F., König, A., Mahns, B. et al. Evidence for phase formation in potassium intercalated 1,2;8,9-dibenzopentacene. Eur. Phys. J. B 85, 242 (2012). https://doi.org/10.1140/epjb/e2012-30247-3
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DOI: https://doi.org/10.1140/epjb/e2012-30247-3