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Magnetic Anisotropy in K0.4[Cr(CN)6][Mn(S)-pn](S)-pnH0.6 Molecular Ferrimagnets

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Abstract

The deviation of the temperature dependence of the magnetocrystalline anisotropy in a K0.4[Cr(CN)6][Mn(S)-pn](S)-pnH0.6 uniaxial ferrimagnetic molecular magnet from the theoretical predictions for this dependence are revealed and discussed. The Dzyaloshinskii–Moriya interaction, which becomes significant at low temperatures and causes non-collinear ordering of spins, is shown to be the source of this deviation.

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ACKNOWLEDGMENTS

The authors are grateful to Prof. R.B. Morgunov for discussing the results.

Funding

The work was supported by the Presidium of the Russian Academy of Sciences (grant within the program 18-030 II, topic 1 “Nanostructures: physics, chemistry, biology, and basics of technology”).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    M. V. Kirman & E. I. Kunitsyna

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  1. M. V. Kirman
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  2. E. I. Kunitsyna
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Correspondence to M. V. Kirman.

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Translated by S. Efimov

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Kirman, M.V., Kunitsyna, E.I. Magnetic Anisotropy in K0.4[Cr(CN)6][Mn(S)-pn](S)-pnH0.6 Molecular Ferrimagnets. Russ. J. Phys. Chem. B 13, 408–412 (2019). https://doi.org/10.1134/S1990793119030187

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  • DOI: https://doi.org/10.1134/S1990793119030187

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