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Zirconia Supported on Rice Husk Silica from Biowaste: A Novel, Efficient, and Recoverable Nanocatalyst for the Green Synthesis of Tetrahydro-1-benzopyrans

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Abstract

Zirconia supported silica from rice husk (an agricultural waste) has been utilized as a novel and efficient heterogeneous catalyst for the synthesis of bioactive tetrahydro-1-benzopyran derivatives via multicomponent condensation of various aldehydes with dimedone and malononitrile. This protocol offers various advantages such as high yields, simple experimental work-up procedure, short reaction time, no by-products, economic availability, easy purification, and reusability of the catalyst.

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ACKNOWLEDGMENTS

The authors gratefully acknowledge CHRIST (Deemed to be University) for the support and for the facilities to carry out this project. We are thankful for IISc and St. Joseph’s College, Bangalore, for NMR, SEM, and XRD analysis.

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Authors and Affiliations

  1. Department of Chemistry, CHRIST (Deemed to be University), 560029, Bangalore, Karnataka, India

    M. Mishra, K. R. S. Devi, D. Pinheiro & A. Nizam

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  1. M. Mishra
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  2. K. R. S. Devi
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  3. D. Pinheiro
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  4. A. Nizam
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Correspondence to A. Nizam.

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Mishra, M., Devi, K.R.S., Pinheiro, D. et al. Zirconia Supported on Rice Husk Silica from Biowaste: A Novel, Efficient, and Recoverable Nanocatalyst for the Green Synthesis of Tetrahydro-1-benzopyrans. Russ J Org Chem 56, 1784–1789 (2020). https://doi.org/10.1134/S107042802010019X

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