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Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker

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Abstract

A new Cu(II) based metal-organic framework (MOF) having formula [Cu3(H2Tar)(Tar)-(H2O)(Bpa)] · 3H2O (I) (H4Tar = tartaric acid, Bpa = 1,2-bis(4-pyridyl)ethane) has been characterized by elemental analysis, FT-IR spectra, thermal analysis, and single-crystal X-ray diffraction (CIF file CCDC no. 1575136). In I, the Cu(II) center are connected by four symmetry-related tartrate ligands into a 2D layer encapsulating trinuclear cluster, which are further bridged by Bpa molecules into a 3D framework. Complex I exhibits strong ferromagnetic behavior between metal centers.

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Authors and Affiliations

  1. Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University, Anhui, 237012, P.R. China

    E. H. Zhou & J. C. Jin

  2. West Anhui Health Vocational College, Anhui, 237012, P.R. China

    E. H. Zhou & J. C. Jin

  3. Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy, Guangdong Medical University, Dongguan, 523808, P.R. China

    B. H. Li, H. R. Zhong, H. D. Zeng, J. X. Zhang, J. Q. Liu & M. M. Luo

  4. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University Xi’an, Xi’an, 710069, P.R. China

    Y. Y. Wang

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  1. E. H. Zhou
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  2. B. H. Li
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  3. H. R. Zhong
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  4. H. D. Zeng
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  6. J. Q. Liu
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  9. J. C. Jin
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Correspondence to J. Q. Liu.

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Zhou, E.H., Li, B.H., Zhong, H.R. et al. Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker. Russ J Coord Chem 44, 432–438 (2018). https://doi.org/10.1134/S1070328418070072

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  • DOI: https://doi.org/10.1134/S1070328418070072

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