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Adduct formation of cadmium(II) N,N-cyclo-hexamethylenedithiocarbamate, [Cd2{S2CN(CH2)6}4], with morpholine: Synthesis, molecular structure, and thermal behavior of a crystalline adduct cis-[Cd{NH(CH2)4O}2{S2CN(CH2)6}2]

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Abstract

The reaction of [Cd2{S2CN(CH2)6}4] (I) with morpholine gives a crystalline adduct of cadmium N,N-cyclo-hexamethylenedithiocarbamate [Cd{NH(CH2)4O}2{S2CN(CH2)6}2] (II), whose coordination sphere includes two molecules of the donor base. The structural organization and thermal behavior of II is studied by X-ray diffraction analysis and simultaneous thermal analysis in comparison with the original binuclear cadmium complex I. The central cadmium atom (coordination number 6) coordinates two morpholine molecules and two structurally equivalent S,S’-anisobidentate ligands HmDtc to form a chromophore [CdN2S4] with the structure of a distorted octahedron. The thermal destruction of II proceeds in two stages and includes consecutive steps of dissociation of the Cd-N bonds followed by the desorption of morpholine and thermolysis of the dithiocarbamate moiety of the adduct to form CdS as the final product. The structure of binuclear [Cd2{S2CN(CH2)6}4] is refined for a correct refinement of the geometric characteristics of compounds I and II.

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Blagoveshchensk, 675000, Russia

    A. S. Zaeva & A. V. Ivanov

  2. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, 690022, Russia

    A. V. Gerasimenko

Authors
  1. A. S. Zaeva
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  2. A. V. Ivanov
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  3. A. V. Gerasimenko
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Correspondence to A. V. Ivanov.

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Original Russian Text © A.S. Zaeva, A.V. Ivanov, A.V. Gerasimenko, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 1, pp. 39–48.

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Zaeva, A.S., Ivanov, A.V. & Gerasimenko, A.V. Adduct formation of cadmium(II) N,N-cyclo-hexamethylenedithiocarbamate, [Cd2{S2CN(CH2)6}4], with morpholine: Synthesis, molecular structure, and thermal behavior of a crystalline adduct cis-[Cd{NH(CH2)4O}2{S2CN(CH2)6}2]. Russ J Coord Chem 40, 34–42 (2014). https://doi.org/10.1134/S1070328414010102

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