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Synthesis of Hexagonal Boron Nitride Coatings Using Concentrated Solutions of Alkali Metal Borates

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Abstract

Continuous nanocrystalline coatings of hexagonal boron nitride (h-BN) with a thickness of ~1000‒350 nm are prepared from highly concentrated aqueous solutions of lithium and sodium borates, which display good film-forming properties. The borate solutions were applied on silicon substrates by spin coating followed by drying in air and treatment in ammonia at a temperature of 1300°C. This method is deemed promising for creating protective coatings (e.g., for protecting carbon products from oxidation at elevated temperatures).

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REFERENCES

  1. D. V. Shtansky, K. L. Firestein, and D. V. Golberg, Nanoscale 10, 17477 (2018).

    Article  Google Scholar 

  2. A. Pakdel, Y. Bando, and D. Golberg, Langmuir 29, 7529 (2013).

    Article  Google Scholar 

  3. X. Li, J. Yin, J. Zhou, and W. Guo, Nanotechnology 25, 105701 (2014).

    Article  ADS  Google Scholar 

  4. Z. Liu, Y. Gong, W. Zhou, L. Ma, J. Yu, J. C. Idrobo, J. Jung, A. H. MacDonald, R. Vajtai, J. Lou, and P. M. Ajayan, Nat. Commun. 4, 2541 (2013).

    Article  ADS  Google Scholar 

  5. H. Zhao, J. Song, X. Song, Z. Yan, and H. Zeng, J. Mater. Chem. A 3, 6679 (2015).

    Article  Google Scholar 

  6. H. Chou, S. Majumder, A. Roy, M. Catalano, P. Zhuang, M. Quevedo-Lopez, L. Colombo, and S. K. Banerjee, ACS Appl. Mater. Interfaces 10, 44862 (2018).

    Article  Google Scholar 

  7. M. Singh, H. Vasudev, and R. Kumar, Mater. Today: Proc. 26, 2277 (2020).

    Google Scholar 

  8. Y. Zhou, W. Zhou, F. Luo, and D. Zhu, Trans. Nonferr. Met. Soc. China 24, 1400 (2014).

    Google Scholar 

  9. A. T. Matveev, E. S. Permyakova, A. M. Kovalskii, D. Leibo, I. V. Shchetinin, K. I. Maslakov, D. V. Golberg, D. V. Shtansky, and A. S. Konopatskya, Ceram. Int. 46, 19866 (2020).

    Article  Google Scholar 

  10. A. T. Matveev, K. L. Firestein, A. E. Steinman, A. M. Kovalskii, I. V. Sukhorukova, O. I. Lebedev, D. V. Shtansky, and D. Golberg, J. Mater. Chem. A 3, 20749 (2015).

    Article  Google Scholar 

  11. A. M. Kovalskii, A. T. Matveev, O. I. Lebedev, I. V. Sukhorukova, K. L. Firestein, A. E. Steinman, D. V. Shtansky, and D. Golberg, CrystEngComm 18, 6689 (2016).

    Article  Google Scholar 

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Funding

I.N. Volkov is grateful to the Ministry of Education and Science of Russian Federation for support of the structural investigation part of this work (program K2A-2018-039 for increasing the competitiveness of National University of Science and Technology “MISiS”).

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Correspondence to A. T. Matveev.

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Translated by A. Kukharuk

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Volkov, I.N., Koval’skii, A.M., Ermekova, Z.S. et al. Synthesis of Hexagonal Boron Nitride Coatings Using Concentrated Solutions of Alkali Metal Borates. Tech. Phys. Lett. 47, 122–125 (2021). https://doi.org/10.1134/S1063785021020152

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  • DOI: https://doi.org/10.1134/S1063785021020152

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