Abstract
A microfluidic system of capillary electrophoresis with electrochemical detection is developed. The process of manufacturing a chip based on polydimethylsiloxane and glass for the determination of electroactive compounds is described. We studied the possibilities of the treatment of the chip channel surface in a gas discharge with sodium dodecyl sulfate, sodium deoxycholate, and an ionic liquid of 1-dodecyl-3-trimethylimidazolium chloride, used as additives to the background electrolyte. It was found that the developed microfluidic system can be used for the determination of polyphenolic antioxidants in green tea and red wine.
Similar content being viewed by others
References
Slyadnev, M.N., Ross. Khim. Zh., 2011, vol. 55, p. 118.
Belen’kii, B.G., Nauchn. Priborostr., 2003, vol. 13, p. 3.
Landers, J.P., Handbook of Capillary and Microchip Electrophoresis and Associated Microtechniques, CRC Press, 2008, 3rd ed.
Vandaveer, W.R.I.V., Pasas, S.A., Martin, R.S., and Lunte, S.M., Electrophoresis, 2002, vol. 23, p. 3667.
Yashin, Ya.I., Ryzhnev, V.Yu., Yashin, A.Ya., and Chernousova, N.I., Prirodnye antioksidanty. Soderzhanie v pishchevykh produktakh i ikh vliyanie na zdorov’e i starenie cheloveka (Natural Antioxidants. Concentrations in Foods and Their Effect on Human Health and Aging), Moscow: TransLit, 2009.
Nikolaev, A.V., Kartsova, L.A., Filimonov, V.V., and Sukhanov, V.L., J. Anal. Chem., 2013, vol. 68, no. 12, p. 1093.
Blasco, A., Compr. Anal. Chem., 2005, vol. 45, p. 703.
Guber, A.E., Chem. Eng. J., 2004, vol. 101, p. 447.
Wang, J., Electroanalysis, 2005, vol. 17, p. 1133.
Plambeck, J., Electroanalytical Chemistry: Basic Principles and Applications, New York: Wiley, 1982.
Zhou, J., Ellis, A.V., and Voelcker, N.H., Electrophoresis, 2020, vol. 31, p. 2.
Martin, I.T., Dressen, B., Boggs, M., Liu, Y., Henry, C.S., and Fisher, E.R., Plasma Processes Polym., 2007, vol. 4, p. 414.
Mourzina, Y., Kalyagin, D., Steffen, A., and Offenhaeusser, A., Talanta, 2006, vol. 70, p. 489.
Garcia, C.D., Dressen, B.M., Henderson, A., and Henry, C.S., Electrophoresis, 2005, vol. 26, p. 703.
Kartsova, L.A. and Ganzha, O.V., J. Anal. Chem., 2010, vol. 65, no. 3, p. 280.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.V. Nikovaev, L.A. Kartsova, V.V. Filimonov, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 8, pp. 863–869.
Rights and permissions
About this article
Cite this article
Nikovaev, A.V., Kartsova, L.A. & Filimonov, V.V. A microfluidic chip for the determination of polyphenolic antioxidants. J Anal Chem 70, 983–988 (2015). https://doi.org/10.1134/S1061934815060118
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934815060118