Skip to main content
SpringerLink
Log in

Iodide ion selective poly(aniline) solid contact electrode based on quinine-cu ionophores

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Iodide ion selective poly(aniline) solid contact electrode based on quinine-Cu ionophore as a sensing material has been successfully developed. The electrode exhibits good linear response of 52.0 mV/decade (at 20 ± 0.2°C, r 2 = 0.9998) within the concentration range of 1 × 10−6.4–1 × 10−1.0 M KI. The composition of this electrode was quinine-Cu 2.0: PVC 30.0: bis(2-ethylhexyl)sebacate 68.0 (mass). This plasticizer provides the best response characteristics. The electrode shows good selectivity for iodide ion in comparison with any other anions and is suitable for use with aqueous solutions of pH 3.3–9.4. The standard deviations of the measured EMF difference were ±1.4 and ±1.3 mV for iodide sample solutions of 1.0 × 10−2 M and 1.0 × 10−3 M, respectively. The stabilization time was less than 10 min and response time was less than 15 sec.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Greenwood, N.N. and Earnsltaw, A., Chem. Elem., 1984, p. 933.

  2. Calligaris, R.M., Wilkinson, G., and Gillard, R.D. (Eds.), Comprehensive Coordination Chemistry, Oxford, 1987, p. 10.

  3. Yäbu, Y., Miyai, K., Hayashizaki, S., Endo, Y., Hata, N., Tijima, Y., and Fushimi, R., Endocrinol. Jpn., 1986, vol. 33, p. 905.

    Google Scholar 

  4. Buinovskii, A.S., Bezrukova, S.A., Kolpakova, N.A., and Maslyuk, A.I., Diagnostika Materialov, 2004, vol. 70, p. 3.

    CAS  Google Scholar 

  5. Ying, M., Yuan, R., Zhang, X.M., Song, Y.Q., Li, Z.Q., Shen, G.L., and Yu, R.Q., Analyst, 1997, vol. 122, p. 1143.

    Article  CAS  Google Scholar 

  6. Aamrani, F.E., Raurich, J.G., Sastre, A., Beyer, L., and Florido, A., Anal. Chim. Acta, 1999, vol. 402, p. 129.

    Article  Google Scholar 

  7. Aamrani, F.El, Raurich, J.G., Sastre, A., Beyer, L., and Florido, A., Anal. Chim. Acta, 1996, vol. 329, p. 247.

    Article  CAS  Google Scholar 

  8. Changqing, S., Jinghong, Z., Hongding, X., Yipeng, X., and Xi, Z., Jiacong, S., Talanta, 1998, vol. 46, p. 15.

    Article  Google Scholar 

  9. Li, Z., Yuan, R., Ying, M., Song, Y., Shen, G., and Yu, R., Anal. Lett., 1990, vol. 30, p.1455

    Google Scholar 

  10. Coetzee, C.J. and Freser, H., Anal. Chem., 1969, vol. 41, p. 1128.

    Article  CAS  Google Scholar 

  11. Umezawa, Y. CRC Handbook of Ion Selective Electrodes: electivity Coefficients, CRC Press, Boca Raton, FL, 1990.

    Google Scholar 

  12. AbdelLatif, M.S. and AlSaraj, M.R., Anal. Lett., 2007, vol. 40, p. 729.

    Article  CAS  Google Scholar 

  13. Worting, V.J., Johnson, D.M., and Bachas, L.G., Anal. Chem., 1990, vol. 62, p. 1506.

    Article  Google Scholar 

  14. Yuan, R., Chai, Y.Q., Liu, D., Gao, D., Li, J.Z., and Yu, R.Q., Anal. Chem., 1993, vol. 65, p. 2572.

    Article  CAS  Google Scholar 

  15. Shamsipur, M., Sadeghi, S., Naeimi, H., and Sharghi, H., Polish. J. Chem., 2000, vol. 74, p. 231.

    CAS  Google Scholar 

  16. Daunert, S. and Bachas, L.Q., Anal. Chem., 1989, vol. 61, p. 499.

    Article  CAS  Google Scholar 

  17. Worting, V.J., Johnson, D.M., and Bachas, L.G., Anal. Chem., 1990, vol. 62, p. 1506.

    Article  Google Scholar 

  18. Yuan, R., Chai, Y.Q., Liu, D., Gao, D., Li, J.Z., and Yu, R.Q., Anal. Chem., 1993, vol. 65, p. 2572.

    Article  CAS  Google Scholar 

  19. Shamsipur, M., Sadeghi, S., Naeimi, H., and Sharghi, H., Polish. J. Chem., 2000, vol. 74, p. 231.

    CAS  Google Scholar 

  20. Yeom, J.S., Won, M.S., Shim, Y.B., J. Electroanal. Chem., 1999, vol. 463, p. 16.

    Article  CAS  Google Scholar 

  21. Alizadeh, N., Ershad, S., Naeimi, H., and Sharghi, H., Shamsipur, M., Polish. J. Chem., 1999, vol. 73, p. 915.

    CAS  Google Scholar 

  22. Yuan, R., Chai, Y.Q., Shen, G.L., and Yu, R.Q., Talanta, 1993, vol. 40, p. 1255.

    Article  CAS  Google Scholar 

  23. Saraswathi, R., Kuwabata, S., and Yoneyama, H., J. Electroanal. Chem., 1992, vol. 335, p. 223.

    Article  CAS  Google Scholar 

  24. Biallozor, S. and Kupniewska, A., Synth. Met., 2005, vol. 155, p. 443.

    Article  CAS  Google Scholar 

  25. Shamsipur, M., Soleymanpour, A., Akhond, M., Sharghi, H., and AliNaseri, M., Anal. Chim. Acta, 2001, vol. 450, p. 37.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. The Research Center of Conservation Science for Cultural Heritage, Hanseo University, Seosan, Choong-Nam, Korea

    Won-Sik Han

  2. Dept. of Chemistry, Hanseo University Seosan, Choong-Nam, Korea

    Young-Hoon Lee, Soon-Nyeo Lee & Tae-Kee Hong

Authors
  1. Won-Sik Han
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Young-Hoon Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Soon-Nyeo Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Tae-Kee Hong
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Han, WS., Lee, YH., Lee, SN. et al. Iodide ion selective poly(aniline) solid contact electrode based on quinine-cu ionophores. J Anal Chem 66, 854–858 (2011). https://doi.org/10.1134/S106193481109019X

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106193481109019X

Keywords

Search

Navigation