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Direct electrochemical oxidation and detection of hydrazine on a boron doped diamond (BDD) electrode

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Abstract

The direct electrochemical oxidation and detection of hydrazine in phosphate buffer (pH 7.0) were investigated on a boron doped diamond (BDD) electrode using cyclic voltammetry (CV) and differential pulse voltammetry (DPV) techniques. The experimental results demonstrated that a one electron transfer process was the rate-limiting step and the overall number of electrons involved in the direct electrochemical oxidation of hydrazine was four. In addition, on the proposed BDD electrode, hydrazine could be well determined by the DPV technique. The peak current linearly depended on the concentration of hydrazine in the range of 0.002–4.0 mM, and the detection limit was 1 μM. The approach proposed here might be a potential method for the determination of hydrazine.

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Authors and Affiliations

  1. School of Urban and Environmental Sciences, Northeast Normal University, Changchun, 130024, China

    Hongwei Sun, Long Dong, Hongbin Yu & Mingxin Huo

Authors
  1. Hongwei Sun
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  2. Long Dong
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  3. Hongbin Yu
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  4. Mingxin Huo
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Correspondence to Hongbin Yu or Mingxin Huo.

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Published in Russian in Elektrokhimiya, 2013, Vol. 49, No. 9, pp. 987–991.

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Sun, H., Dong, L., Yu, H. et al. Direct electrochemical oxidation and detection of hydrazine on a boron doped diamond (BDD) electrode. Russ J Electrochem 49, 883–887 (2013). https://doi.org/10.1134/S1023193513030154

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  • DOI: https://doi.org/10.1134/S1023193513030154

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