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Anthrone complexation with aliphatic amines in an aprotic medium

  • Chemical Kinetics and Catalysis
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Abstract

Aromatic ketone (anthrone) complexation with aliphatic amines is studied by UV-Vis, 1H, 1H-1H COSY NMR spectroscopy. It is found that the catalytic activity of aliphatic amine is observed in the reaction of anthrone oxidation by molecular oxygen in aprotic media due to the formation of intermolecular complexes consisting of two anthrone molecules and one aliphatic amine molecule.

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Authors and Affiliations

  1. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, 83001, Ukraine

    A. A. Serdyuk, A. A. Abakumov, I. V. Kapitanov, M. G. Kasianczuk & I. A. Opeida

Authors
  1. A. A. Serdyuk
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  2. A. A. Abakumov
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  3. I. V. Kapitanov
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  4. M. G. Kasianczuk
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  5. I. A. Opeida
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Corresponding author

Correspondence to A. A. Serdyuk.

Additional information

Original Russian Text © A.A. Serdyuk, A.A. Abakumov, I.V. Kapitanov, M.G. Kasianczuk, I.A. Opeida, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 9, pp. 1477–11481.

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Serdyuk, A.A., Abakumov, A.A., Kapitanov, I.V. et al. Anthrone complexation with aliphatic amines in an aprotic medium. Russ. J. Phys. Chem. 87, 1470–1473 (2013). https://doi.org/10.1134/S0036024413090203

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  • DOI: https://doi.org/10.1134/S0036024413090203

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