Skip to main content
SpringerLink
Log in

Acidities of 3d and 4f element sulfides are the key factor governing the type of phase diagram in MS-Ln2S3 (M = Mn, Fe; Ln = La-Lu) systems

  • Theoretical Inorganic Chemistry
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

An equation to calculate the acidity of simple sulfides and a relative acidity scale are proposed. A correlation between the type of phase diagram and the acid-base properties of constituent simple sulfides of the system is postulated. The similarity of the acid-base properties of simple sulfides provides that they have a eutectic-type diagram. Complex sulfides are formed when the difference between the relative acidities of simple sulfides exceeds some threshold value. The complex compounds formed in MnS-Ln2S3 (Ln = La, Ce) systems, namely Mn2La6S11 and MnCe2S4, are classified with thiomanganates. The compounds formed in FeS-Ln2S3 (Ln = La, Ce, Pr) systems, namely FeLn2S4 (Ln = La, Ce) and FeLn4S7 (Ln = La-Pr), are classified with thioferrates. The strengthening of acidic properties in the Ln2S3 (Ln = La-Lu) series results in the formation of thiolanthanates: MnLn2S4 (Ln = Dy-Lu), MnLn4S7 (Ln = Tb-Tm), FeLu2S4, FeLn4S7 (Ln = Ho-Yb), and Fe4Ln2S7 (Ln = Tm, Yb, Lu).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Inorganic Chemistry, Ed. by Yu. D. Tret’yakov (Akademiya, Moscow, 2004), Vol. 1 [in Russian].

    Google Scholar 

  2. O. V. Andreev, O. Yu. Mitroshin, N. A. Khritokhin, and I. A. Razumkova, Russ. J. Inorg. Chem. 53, 440 (2008).

    Article  Google Scholar 

  3. O. V. Andreev, O. Yu. Mitroshin, and I. A. Razumkova, Russ. J. Inorg. Chem. 53, 323 (2008).

    Article  Google Scholar 

  4. O. V. Andreev, O. Yu. Mitroshin, and I. A. Razumkova, Russ. J. Inorg. Chem. 52, 1161 (2007).

    Article  Google Scholar 

  5. O. V. Andreev and N. N. Parshukov, Zh. Neorg. Khim. 36, 2106 (1991).

    CAS  Google Scholar 

  6. O. V. Andreev, I. A. Razumkova, O. Yu. Mitroshin, et al., Phase Formation in Sulfide Systems of ns (Sr, Ba), 3d (Sc, Cu), and 4f (La-Lu) Elements (Izd-vo Tyumen. Gos. Univ., Tyumen, 2008).

    Google Scholar 

  7. O. V. Andreev, Zh. Neorg. Khim. 38, 687 (1993).

    CAS  Google Scholar 

  8. P. P. Fedorov and P. I. Fedorov, Zh. Neorg. Khim. 18, 205 (1973).

    CAS  Google Scholar 

  9. L. N. Monina, Candidate Dissertation in Chemistry (Tyumen, 2010).

    Google Scholar 

  10. O. V. Andreev, L. N. Monina, and A. V. Elyshev, Proceedings of the 6th All-Russia Conference “Physicochemical Processes in Condensed Media and at Interfaces” (Voronezh, 2012), p. 289 [in Russian].

    Google Scholar 

  11. O. V. Andreev, L. N. Monina, A. V. Elyshev, and V. B. Kharitontsev, Proceedings of the 10th International Kurnakov’s Congress on Physicochemical Analysis (Samara, 2013), Vol. 1, p. 6 [in Russian].

    Google Scholar 

  12. V. O. Andreev, Candidate Dissertation in Technical Sciences (Tyumen, 2007).

    Google Scholar 

  13. O. V. Andreev and L. N. Monina, Russ. J. Inorg. Chem. 57, 1393 (2012).

    Article  CAS  Google Scholar 

  14. O. V. Andreev and L. N. Monina, Vestn. Tyumen Gos. Univ, No. 5, 162 (2011).

    Google Scholar 

  15. O. V. Andreev and L. N. Monina, Russ. J. Inorg. Chem. 55, 658 (2010).

    Article  Google Scholar 

  16. O. V. Andreev, V. M. Andreeva, and V. G. Bamburov, Zh. Neorg. Khim. 36, 2393 (1991).

    CAS  Google Scholar 

  17. O. V. Andreev and V. M. Andreeva, Izv. Akad. Nauk SSSR, Neorg. Mater. 36, 2261 (1991).

    Google Scholar 

  18. O. V. Andreev, N. N. Parshukov, and V. G. Bamburov, Zh. Neorg. Khim. 37, 1882 (1992).

    CAS  Google Scholar 

  19. V. P. Bystrov, I. S. Babashev, and A. V. Vanyukov, Tsvetn. Metally, No. 6, 5 (1971).

    Google Scholar 

  20. M. Husain, A. Batra, and K. S. Srivastava, Polyhedron 8, 1233 (1989).

    Article  CAS  Google Scholar 

  21. R. D. Shannon, Acta Crystallogr., Sect. A 32, 751 (1976).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tyumen State University, ul. Semakova 10, Tyumen, 625003, Russia

    O. V. Andreev & L. N. Monina

Authors
  1. O. V. Andreev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. N. Monina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. V. Andreev.

Additional information

Original Russian Text © O.V. Andreev, L.N. Monina, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 9, pp. 1202–1209.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Andreev, O.V., Monina, L.N. Acidities of 3d and 4f element sulfides are the key factor governing the type of phase diagram in MS-Ln2S3 (M = Mn, Fe; Ln = La-Lu) systems. Russ. J. Inorg. Chem. 59, 971–978 (2014). https://doi.org/10.1134/S0036023614090034

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023614090034

Keywords

Search

Navigation