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Study of acid pyridine-3-carboxylic acid dodecatungstenphosphate of the composition (C6NO2H5)2H[PW12O40]·2H2O

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Abstract

Acid pyridine-3-carboxylic acid dodecatungstenphosphate (C6NO2H5)2H[PW12O40]·2H2O is synthesized. The compound is studied by chemical analysis, IR spectroscopy, X-ray crystallography, and thermogravimetry. The compound is found to crystallize at 290 K in a hexagonal crystal system (space group \(R\bar 3\)) (I) with the unit cell parameters: a = 33.015(6) Å, c = 12.010(2) Å, γ = 120°, V = 11337(4) Å3, Z = 9. When the temperature decreases to 100 K, a phase transition is observed leading to an increase in symmetry to \(R\bar 3m\) (II), with the unit cell parameters: a = 33.072(1) Å, c = 24.234(1) Å, γ = 120°, V = 22955(2) Å3, Z = 18.

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Authors and Affiliations

  1. Moscow State Pedagogical University, Moscow, Russia

    G. Z. Kaziev, O. A. Kirichenko & E. A. Solov’eva

  2. Karpov Institute of Physical Chemistry, Moscow, Russia

    A. I. Stash

  3. UAM, Ascapotzalco, Mexico

    Saul H. Quinones

  4. The University of Chicago, Chicago, Illinois, USA

    Y. S. Chen

Authors
  1. G. Z. Kaziev
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  2. O. A. Kirichenko
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  3. A. I. Stash
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  4. Saul H. Quinones
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  5. E. A. Solov’eva
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  6. Y. S. Chen
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Correspondence to G. Z. Kaziev.

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Original Russian Text © 2014 G. Z. Kaziev, O. A. Kirichenko, A. I. Stash, Saul H. Quinones, E. A. Solov’eva, Y. S. Chen.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 708–715, July–August, 2014.

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Kaziev, G.Z., Kirichenko, O.A., Stash, A.I. et al. Study of acid pyridine-3-carboxylic acid dodecatungstenphosphate of the composition (C6NO2H5)2H[PW12O40]·2H2O. J Struct Chem 55, 674–681 (2014). https://doi.org/10.1134/S002247661404012X

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  • DOI: https://doi.org/10.1134/S002247661404012X

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