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Influence of the origin of H2O2 on the rate of its reaction with Pu(VI) and Am(V) in acid solutions

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Abstract

Analysis of published data shows that H2O2 arising in radiolysis of acidic aqueous solutions is in the excited state and reacts with Pu(VI) and Am(V) faster than in the case when in it is introduced into the system with actinide ions from the outside.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, Moscow, 119071, Russia

    V. P. Shilov, A. M. Fedoseev & A. V. Gogolev

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  1. V. P. Shilov
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  2. A. M. Fedoseev
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  3. A. V. Gogolev
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Correspondence to A. M. Fedoseev.

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Original Russian Text © V.P. Shilov, A.M. Fedoseev, A.V. Gogolev, 2012, published in Radiokhimiya, 2012, Vol. 54, No. 5, pp. 419–421.

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Shilov, V.P., Fedoseev, A.M. & Gogolev, A.V. Influence of the origin of H2O2 on the rate of its reaction with Pu(VI) and Am(V) in acid solutions. Radiochemistry 54, 455–458 (2012). https://doi.org/10.1134/S1066362212050062

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  • DOI: https://doi.org/10.1134/S1066362212050062

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