Skip to main content
Log in

Barrier photovoltaic effects in PZT ferroelectric thin films

  • Magnetism and Ferroelectricity
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The photoelectric characteristics (independent of ferroelectric polarization) of metal-ferroelectric-metal thin film structures upon exposure to radiation in different ranges of mercury arc lamp spectrum are studied for the Pb(Zr0.52Ti0.48)O3 (PZT) ferroelectrics. The PZT films on platinized silicon substrates were prepared by the sol-gel technique. The relaxations of the short-circuit current and the open-circuit voltage are investigated at different intensities of light with wavelengths in the range 300–1200 nm. It is found that the open-circuit voltage returns to its original value after the cessation of light exposure and a short-term holding of structures in the short-circuited state. The factors responsible for the photocurrent and the photoemf are analyzed, and the conclusion is made that they are predominantly contributed by the barrier photovoltaic effects associated with the presence of the p-n junction in the bulk of films and the Schottky barrier in the film region adjacent to the lower platinum electrode.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. V. M. Fridkin, Ferroelectrics-Semiconductors (Nauka, Moscow, 1976).

    Google Scholar 

  2. P. S. Brody and B. J. Rod, Integr. Ferroelectrics 2, 1 (1992).

    Google Scholar 

  3. J. Lee, S. Esayan, J. Prohaska, et al., Appl. Phys. Lett. 64, 294 (1994).

    ADS  Google Scholar 

  4. S. Thakoor, J. Perry, and J. Maserjian, Integr. Ferroelectrics 4, 333 (1994).

    Google Scholar 

  5. V. V. Lemanov, A. V. Sotnikov, and N. K. Yushin, Pis’ma Zh. Tekh. Fiz. 19, 61 (1993).

    Google Scholar 

  6. V. K. Yarmarkin, N. V. Zaitseva, S. V. Shtel’makh, et al., Fiz. Tverd. Tela (St. Petersburg) 37, 324 (1995).

    Google Scholar 

  7. S. M. Ryvkin, Photoelectric Phenomena in Semiconductors (Fizmatgiz, Moscow, 1963).

    Google Scholar 

  8. K. Sreenivas, M. Sayer, and P. Garrett, Thin Solid Films 172, 251 (1989).

    Article  Google Scholar 

  9. W. Ruppel, R. V. Baltz, and P. Wurfel, Ferroelectrics 43, 109 (1982).

    Google Scholar 

  10. S. Thakoor and J. Maserjian, J. Vac. Sci. Technol. A 12, 295 (1994).

    Article  ADS  Google Scholar 

  11. V. K. Yarmarkin and S. P. Teslenko, Fiz. Tverd. Tela (St. Petersburg) 40, 1915 (1998).

    Google Scholar 

  12. T. Mihara, H. Watanabe, H. Yoshimori, et al., Integr. Ferroelectrics 1, 269 (1992).

    Google Scholar 

  13. S. K. Dey, J.-J. Lee, and P. Alluri, Jpn. J. Appl. Phys., Part 1 34(6A), 3142 (1995).

    Google Scholar 

  14. M. K. Sheinkman and A. Ya. Shik, Fiz. Tekh. Poluprovodn. (Leningrad) 10, 209 (1976).

    Google Scholar 

  15. J. F. Scott, Ferroelectrics Rev. 1, 1 (1998).

    Google Scholar 

  16. A. K. Tagantsev, Cz. Pawlaczyk, K. Brooks, et al., Integr. Ferroelectrics 4, 1 (1994).

    Google Scholar 

  17. S. K. Dey and R. Zuleeg, Ferroelectrics, Part B 112, 309 (1990).

    Google Scholar 

  18. B. N. Melnick, J. F. Scott, C. A. Paz De Araujo, et al., Ferroelectrics 135, 163 (1992).

    Google Scholar 

  19. K. A. Vorotilov, M. I. Yanovskaya, and O. A. Dorochova, Integr. Ferroelectrics 3, 33 (1993).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Translated from Fizika Tverdogo Tela, Vol. 42, No. 3, 2000, pp. 511–516.

Original Russian Text Copyright © 2000 by Yarmarkin, Gol’tsman, Kazanin, Lemanov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yarmarkin, V.K., Gol’tsman, B.M., Kazanin, M.M. et al. Barrier photovoltaic effects in PZT ferroelectric thin films. Phys. Solid State 42, 522–527 (2000). https://doi.org/10.1134/1.1131242

Download citation

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.1131242

Keywords

Navigation