Abstract
The properties of ASD-1 aluminum powder and its oxidation with water at 100°C were studied. It was found that the microstructure of a surface oxide film and the conditions of oxidation significantly affected the dynamics of changes in the pH of the solution and in the degree of aluminum conversion into the hydroxide. Experimental data on the oxidation in combination with electron-microscopic measurements and the determination of adsorption and texture characteristics resulted in the conclusion that colloid-chemical processes, which include the dissolution of aluminum and the formation and precipitation of the hydroxo complexes of aluminum, are fundamental for the synthesis of porous metal ceramics.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
USSR Inventor's Certificate no. 1444080, Byull. Izobret., 1988, no. 46.
Anan'in, V.N., Belyaev, V.V., Romanenkov, V.E., et al., Vestn. Akad Nauk BSSR. Ser. Khim. Nauk, 1988, no. 5, p. 17.
Azarov, S.M., Romanenkov, V.E., and Smirnova, T.A., Poroshkovaya Metallurgiya (Powder Metallurgy), 1988, no. 12, p. 62.
USSR Inventor's Certificate no. 1532201, Byull. Izobret., 1989, no. 48.
Tikhov, S.F., Sadykkov, V.A., Potapova, Yu.V., et al., Stud. Surf. Sci. Catal., 1998, vol. 118, p. 797.
Tikhov, S.F., Sadykov, V.A., Salanov, A.N., et al., Mater. Res. Soc. Symp. Ser., 1998, vol. 497, p. 200.
Tikhov, S.F., Salanov, A.N., and Palesskaya, Yu.Vs., React. Kinet. Catal. Lett., 1998, vol. 64,no. 2, p. 301.
Rat'ko, A.I., Romanenkov, V.E., Stankevich, M.V., and Smirnov, V.G., Dokl. Nat. Akad. Nauk Bel., Ser. Khim., 2000, no. 1, p. 57.
Yakerson, V.I., Dykh, Zh.L., Subbotin, A.N., et al., Kinet. Katal., 1995, vol. 36,no. 6, p. 918.
Tikhov, S.F., Fenelonov, V.B., Sadykov, V.A., Potapov, Yu.V., and Salanov, A.N., Kinet. Katal., 2000, vol. 41,no. 6, p. 907 [Kinet. Catal. (Engl. Transl.) vol. 41, no. 6, p. 826].
Tikhov, S.F. Zaikovskii, V., Fenelonov V.B., Potapova Yu.V., Kolomiichuk V.N., and Sadykov V.A., Kinet. Katal., 2000, vol. 41,no. 6, p. 916 [Kinet. Catal. (Engl. Transl.) vol. 41, no. 6, p. 835].
Lokenbakh, A.K., Strod, V.V., Lepin', L.K., et al., Izv. Akad. Nauk Latv. SSR. Ser. Khim., 1981, no. 1, p. 50.
Lepin', L.K., Lokenbakh, A.K., Zhilinskii, V.V., et al., Tez. dokl. VIII Vsesoyuz. soveshch. po kinetike i mekhanizmu khimicheskikh reaktsii v tverdom tele (Proc. VIII All-Union Workshop on the Kinetics and Mechanism of Chemical Reactions), Chernogolovka: Inst. of Chemical Physics, 1982, p. 166.
Zhilinskii, V.V., Lokenbakh, A.K., and Lepin', L.K., Izv. Akad. Nauk Latv. SSR. Ser. Khim., 1982, no. 6, p. 663.
Lepin', L.K., Lokenbakh, A.K., and Zhilinskii, V.V., Fizikokhimiya i tekhnologiya dispersnykh poroshkov (Physical Chemistry and Technology of Dispersed Powders), Kiev: IPM AN USSR, 1984, p. 112.
Zhilinskii, V.V., Zaporina, N.A., and Romanovska, B.Yu., Abstracts of papers, Tezisy nauchnykh soobshchenii ural'skoi konferentsii “Poverkhnost' i novye materialy” (Ural Conf. on Surfaces and New Materials), Sverdlovsk: Ural. Nauchn. Tsentr Akad. Nauk SSSR, 1984, part 1, p. 168.
Zhilinskii, V.V., Shcherbakov, V.K., Lokebakh, A.K., and Abele, R.Yu., Sovershenstvovanie protsessov lit'ya i obrabotki alyuminiya i proizvodstva kremniya (Advances in the Process of Casting and Processing of Aluminum and Silicon Production), Ostanin, Yu.A., Ed., Leningrad: VAMI, 1985, p. 45.
Zhilinskii, V.V., Lokenbakh, A.K., and Lepin', L.K., Izv. Akad. Nauk Latv. SSR. Ser. Khim., 1986, no. 2, p. 151.
Zhilinskii, V.V., Lokenbakh, A.K., and Lepin', L.K., Izv. Akad. Nauk Latv. SSR. Ser. Khim., 1986, no. 2, p. 157.
Zaporina, N.A., Ushpele, I.P., Romanovska, B.Yu., et al., Intersifikatsiya proizvodstva produktsii iz alyuminiya, kremniya i ikh splavov (Intensification of Production Based on Aluminum, Silicon, and Their Alloys), Leningrad: VAMI, 1987, p. 17.
Zhilinskii, V.V. and Lokenbakh, A.K., Izv. Akad. Nauk Latv. SSR. Ser. Khim., 1988, no. 5, p. 622.
Romanenkov, V.E., Cand. Sci. (Eng.) Dissertation, Minsk: Byelorussian State Polytechnic Academy, 1996.
Vityaz', P.A., Sheleg, V.K., Anan'in, V.N., et al., Dokl. Akad. Nauk BSSR. Ser. Khim., 1986, vol. 30,no. 3, p. 240.
Reut, O.P. and Romanenkov, V.E., Vesti Nat Akad. Nauk Bel., Ser. Fiz.-Tekh. Nauk, 1998, no. 1, p. 11.
Nechitailov, A.P., Plakhotnikova, N.A., and Shitova, T.A., in Lit'e i obrabotka alyuminiya (Casting and Processing of Aluminum), Leningrad: VAMI, 1977, no. 99, p. 96.
Thompson, G.E., Shimizu, K., and Wood, G.C., Nature, 1980, vol. 286, p. 471.
Eksperimental'nye metody v adsorbtsii i molekulyarnoi khromatografii (Experimental Methods in Adsorption and Molecular Chromatography), Kiseleva, A.V. and Dreving, V.P., Eds., Moscow: Mos. Gos. Univ., 1973.
Singer, A.R.E., Coombs, J.S., and Leatham, A.G., Modern Dev. Pov. Met., 1974, vol. 34, p. 263.
Ananin, V.N., Vityaz, P.A., Glukhova, N.P., et al., React. Kinet. Catal. Lett., 1985, vol. 27,no. 2, p. 393.
Anan'in, V.N., Romanenkov, V.E., and Smirnova, T.A., Dokl. Akad. Nauk BSSR, 1987, vol. 31,no. 9, p. 818.
Shevchenko, V.G., Bulatov, M.A., Kononenko, V.I., et al., Poroshkovaya metallurgiya (Powder Metallurgy), 1988, no. 2, p. 1.
Shevchenko, V.G., Kononeko, V.I., Latosh, I.N., et al., Poroshkovaya metallurgiya (Powder Metallurgy), 1991, no. 5, p. 80.
Il'in, A.P. and Proskurovskaya, L.T., Poroshkovaya metallurgiya (Powder Metallurgy), 1990, no. 9, p. 32.
Panchenkov, G.M. and Lebedev, V.P., Khimicheskaya kinetika i kataliz (Chemical Kinetics and Catalysis), Moscow: Khimiya, 1985.
Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, London: Academic, 1967.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rat'ko, A.I., Romanenkov, V.E., Bolotnikova, E.V. et al. Hydrothermal Synthesis of Porous Al2O3/Al Metal Ceramics: I. Oxidation of Aluminum Powder and Structure Formation of Porous Al(OH)3/Al Composite. Kinetics and Catalysis 45, 141–148 (2004). https://doi.org/10.1023/B:KICA.0000016114.78885.00
Issue Date:
DOI: https://doi.org/10.1023/B:KICA.0000016114.78885.00