Abstract
Water activities in solutions of basic aluminum chlorides were determined by measurements of the vapor pressure. There is a marked dependence of the activities on the total concentration of aluminum and on the basicity of the solutions. By means of the measured data and the quantities derived from them, it is possible to distinguish between three types of solutions. These probably differ from one another in the content of different kinds of hydrolysis and condensation products.
Similar content being viewed by others
REFERENCES
G. Johansson, Acta Chim. Scand. 16, 403 (1962).
C. E. Baes and R. E. Mesmer, The Hydrolysis of Cations (Wiley, New York, 1976), pp. 112–123.
J. J. Aveston, J. Chem. Soc., p. 4438 (1965).
J. W. Akitt et al., J. Chem. Soc., Dalton Trans., p. 1889 (1989).
J. W. Akitt and A. Farthing, J. Chem. Soc., Dalton Trans., p. 1606 (1981).
T. Angermann, Diplomarbeit, TU Bergakademie Freiberg, unpublished (1992).
J. J. Fitzgerald, L. E. Johnson, and J. S. Frye, J. Magn. Reson. 84, 12 (1989).
A. R. Thompson et al., J. Chem. Soc., Dalton Trans., p. 2317 (1987); J. Y. Bottero et al., J. Chem. Phys. 84, 2933 (1980).
G. Fu, L. F. Nazar, and A. D. Bain, Chem. Mater. 3, 602 (1991).
D. A. Riesgraf and M. L. May, Appl. Spectrosc. 32, 326 (1978).
D. L. Teagarden, J. Pharm. Sci. 70, 762 (1981).
S. Schönherr and R. Bertram, Z. Chem. 23, 105 (1983).
W. Gessner and M. Winzer, Z. Anorg. Allg. Chem. 452, 151 (1979).
S. Schönherr et al., Z. Anorg. Allg. Chem. 476, 1985 (1981).
S. Schönherr et al., Z. Chem. 23, 429 (1983).
H. Görz, Ph.D. Thesis, TU Bergakademie Freiberg (1982).
P. M. Bertsch, J. Soil Sci. Soc. Am. 50, 825 (1986).
P. M. Bertsch, W. J. Layton, and R. I. Barnhisel, J. Soil Sci. Soc. Am. 50, 1449(1986).
S. Schönherr and P. Frey, Z. Anorg. Allg. Chem. 452, 167 (1979).
J. J. Fitzgerald, in Antiperspirants and Deodorants, Cosmetic Science and Technology Series 7, K. Laden and C. B. Felger, eds. (Marcel Dekker, New York, 1988).
T. Angermann, P. Brand, and H.-J. Mögel, Freiberger Forschungsh. A 832, 60 (1993).
D. A. Palmer and J. W. Wesolowski, Geochim. Cosmochim. Acta 57, 2929 (1993).
S. Münkner, Diplomarbeit, TU Bergakademie, Frieberg, unpublished (1988).
A. Saul and W. Wagner, J. Phys. Chem. Ref. Data 16, 893 (1987).
D. L. Teagarden. S. L. Hem, and J. L. White, J. Soc. Cosmet. Chem. 33, 281 (1982).
U. Richter, P. Brand, K. Bohmhammel, and T. Könnecke, in preparation.
W. Seichter, H. Mögel, P. Brand, and D. Salah, Eur. J. Inorg. Chem., p. 795 (1998).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Richter, U., Brand, P. & Bohmhammel, K. Water Activities in Solutions of Basic Aluminum Chlorides. Journal of Solution Chemistry 28, 61–72 (1999). https://doi.org/10.1023/A:1021751324240
Issue Date:
DOI: https://doi.org/10.1023/A:1021751324240