Skip to main content
SpringerLink
Log in

Electrochemical simulation of friction interactionson the basis of anti-wear behaviour of metallo-dibutyldithiophosphate complexes[(DTP)zMA z+] innon-aqueous media

  • Published:
Tribology Letters Aims and scope Submit manuscript

Abstract

The aim of the present study was to propose a new electrochemicalmodel of anti-wear behaviour of dibutyldithiophosphate complexes[(DTP)zMA z+](where MA z+=Au+,Ag+ or Zn2+) in a non-aqueous model solventon the basis of electrochemical experiments compared withclassical four-ball machine tests on standard 100Cr6 steel. Theelectrochemical behaviour of [(DTP)zMA z+] wasobserved on bronze, copper and 100Cr6 steel electrodes innon-aqueous acetonitrile solutions containing 0.05 M NaClO4 as a supporting electrolyte. Potential peaks(1Ep,c) of the underpotentialdeposition (UPD) of MA metals were observed, and thesequence of 1Ep,c: Au>Ag>Zn valueswas identified. A similar sequence of effectiveness of the[(DTP)zMA z+]anti-wear agents was obtained in the four-ball machine tests.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F.P. Bowden and D. Tabor, in: The Friction and Lubrication of Solids (Clarendon Press, Oxford, 1964).

    Google Scholar 

  2. J. O’M. Bockris and S.D. Gileadi, Electrochim Acta 14 (1969) 1259.

    Google Scholar 

  3. G.H. Kelsall, Y. Zhu and H.A. Spikes, J. Chem. Soc. Faraday Trans. 89 (1993) 267.

    Google Scholar 

  4. N.P. Brandon, N. Bonanos, P.O. Fogarty, M.N. Mahmood, A.J. Moore and P.J.K. Wood, J. Appl. Electrochem. 23 (1993) 456.

    Google Scholar 

  5. S.C. Tung and S.S. Wang, ASLE Trans. 34 (1991) 23.

    Google Scholar 

  6. S.S. Wang, S.P. Maheswari and S.C. Tung, ASLE Trans. 30 (1987) 394.

    Google Scholar 

  7. S.S. Wang, S.P. Maheswari and S.C. Tung, ASLE Trans. 31 (1988) 381.

    Google Scholar 

  8. I.L. Goldblatt, in: The Importance of Electron Transfer Processes to the Wear Processes, Proc. 34th Int. Meeting Soc. de Chimie, Tribology Series,Vol. 7 (1981) p. 521.

  9. S.N. Postnikov, Electrophysical and Electrochemical Phenomena in Friction, Cutting, and Lubrication (Van Nostrand Reinhold, NewYork,1978).

    Google Scholar 

  10. J. O’M. Bockris, Surface Electrochemistry. A Molecular Level Approach (Plenum Press, New York, 1993) ch. 8.12.11, pp. 831 833, and references therein.

    Google Scholar 

  11. J.W. Fu, ASLE Trans. 31 (1988) 497.

    Google Scholar 

  12. A.M. Homola et al., Trans. ASMEJ. Tribol. 112 (1990) 567.

    Google Scholar 

  13. S.C. Tung and S.S. Wang, Tribol. Trans. 34 (1991) 479.

    Google Scholar 

  14. C. Kajdas and I. Fodor, Tribol. Trans. 31 (1988) 476.

    Google Scholar 

  15. D. Ozimina, in: Proc. 6th Int. Congr. on Tribology, Budapest 1993, Vol. 2, p. 41.

    Google Scholar 

  16. H. Czichos, Tribology (Elsevier, Amsterdam, 1978) p. 10; W. Morales, ASLE Trans. 29 (1986) 67.

    Google Scholar 

  17. H. Scholl, S. Płaza and D. Ozimina, Mat. of 35th IUPAC Congress, 1419August 1995, Istanbul, Abstr. I, Phys P054.

  18. D. Ozimina, in: Proc. 6th Nordic Symp. on Tribology NORTRIB '94, 12-15 June 1994,Uppsala,Vol. 2, pp. 381387.

    Google Scholar 

  19. H.M. Koepp, H. Wendt and H. Strehlow, Zh. Fiz. Khim. 64 (1960) 483.

    Google Scholar 

  20. H. Strehlow, in: The Chemistry of Non-Aqueous Solvents, Vol. 1, ed. L. Lagowski (Academic Press, NewYork, 1967) p. 129.

    Google Scholar 

  21. Y. Marcus, PureAppl. Chem. 55 (1983) 977.

    Google Scholar 

  22. H. Scholl and K. Sochaj, Electrochim. Acta 34 (1989) 915.

    Google Scholar 

  23. D. Bauer and M. Bréant, Electroanal. Chem., Vol. 8, ed. A.I. Bard (Dekker, NewYork, 1975) pp. 248-281.

    Google Scholar 

  24. H. Scholl, Solvation and Electrode Processes in Non-Aqueous Solvents (University Press Office, Ł ódź, 1992) p. 133, in Polish.

    Google Scholar 

  25. H. Scholl and K. Sochaj, Electrochim. Acta 36 (1991) 689.

    Google Scholar 

  26. M.I. Montenegro, M.A. Queiros and J.L. Daschbach, eds., Microelectrodes: Theory and Application, NATO ASI Ser. E (1987) p. 197.

  27. J. Heinze, Angew. Chem. Int. Ed. Engl. 32 (1993) 1268, and references therein.

  28. M. Fleischman, S. Pons and D.R. Rolison, in: Ultramicroelectrodes, ed. P.P. Schmidt (Datatech System, Morganton, 1987).

    Google Scholar 

  29. D.M. Kolb, in: Advances in Electrochemistry and Electrochemical Engineering, Vol. 11, ed. C.W. Tobias (Wiley, NewYork, 1978).

    Google Scholar 

  30. J. O'M. Bockris and S.U.M. Khan, Surface Electrochemistry. A Molecular Level Approach (Plenum Press, New York, 1993) ch. 3.24.18, pp. 377380, and references therein.

    Google Scholar 

  31. S. Swateiharajan and S. Bruckstein, Electrochim. Acta 28 (1983) 865.

    Google Scholar 

  32. G. Kokkinidis, J. Electroanal. Chem. 210 (1986) 217.

    Google Scholar 

  33. M. Hepel, K. Kanige and S. Bruckstein, J. Electroanal. Chem. 266 (1986) 697.

    Google Scholar 

  34. C.P.M. Bongenaar, A.G. Remijnse, M. Sluyters-Rehbach and J.H. Sluyters, J. Electroanal. Chem. 111 (1980) 150.

    Google Scholar 

  35. J. Strujis, M. Sluyters-Rehbach and J.H. Sluyters, J. Electroanal. Chem. 171 (1984) 177.

    Google Scholar 

  36. M. Hepel and S. Bruckstein, Electrochim. Acta 34 (1989) 1499.

    Google Scholar 

  37. C.P. Wilde and M. Zhang, J. Electroanal. Chem. 327 (1992) 307.

    Google Scholar 

  38. T. B. aszczyk, W. Olejniczak and P. Kobierski, Pomiary, Automatyka,Kontrola 40 (1995) 342.

    Google Scholar 

Download references

Authors
  1. D. Ozimina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Scholl
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Plaza
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ozimina, D., Scholl, H. & Plaza, S. Electrochemical simulation of friction interactionson the basis of anti-wear behaviour of metallo-dibutyldithiophosphate complexes[(DTP)zMA z+] innon-aqueous media. Tribology Letters 3, 147–155 (1997). https://doi.org/10.1023/A:1019124920583

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019124920583

Keywords

Search

Navigation