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Ullmann homocoupling of aryl iodides catalyzed by gold nanoparticles stabilized on magnetic mesoporous silica

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Abstract

We demonstrated a convenient new procedure of the Ullmann homocoupling reaction for the synthesis of symmetrical biaryls via homocoupling of aryl iodides over a recyclable gold catalyst comprising Au nanoparticles supported on functional magnetic mesoporous silica (α-Fe2O3)-MCM-41-HS-Au. The catalyst was easily separated by an external magnet, and the recovered catalyst was reused in six successive reaction cycles without any significant loss of activity. So, using this catalyst is affordable. Also, the reaction time is much shorter than a few previously reported work.

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Acknowledgements

We gratefully acknowledge the partial support of this work to K. N. Toosi University of Technology.

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Authors and Affiliations

  1. Department of Chemistry, K. N. Toosi University of Technology, P. O. Box 15875-4416, Tehran, Iran

    Shahnaz Rostamizadeh, Hamid Estiri & Mohammad Azad

Authors
  1. Shahnaz Rostamizadeh
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  2. Hamid Estiri
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  3. Mohammad Azad
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Correspondence to Shahnaz Rostamizadeh.

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Rostamizadeh, S., Estiri, H. & Azad, M. Ullmann homocoupling of aryl iodides catalyzed by gold nanoparticles stabilized on magnetic mesoporous silica. J IRAN CHEM SOC 14, 1005–1010 (2017). https://doi.org/10.1007/s13738-017-1050-z

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