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An expedient and green ultrasound-promoted synthesis of fused α-pyrones from Baylis–Hillman acetates using basic ionic liquid [bdmim]OH

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Abstract

Fused α-pyrones were obtained in a convenient and green protocol from Baylis–Hillman acetates and various cyclic dicarbonyl compounds in the presence of basic ionic liquid 1-butyl-2,3-dimethylimidazolium hydroxide ([bdmim]OH) under ultrasonic irradiation. This method provided the desired α-pyrones in good to high yields (82–98 %) and lower reaction times (5–15 min).

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Acknowledgments

Financial support for this work by the research council of Islamic Azad University, Rasht Branch is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Islamic Azad University, Rasht Branch, P.O. Box 41335-3516, Rasht, Iran

    Manouchehr Mamaghani & Fatemeh Alavi

  2. Department of Chemistry, Faculty of Sciences, University of Guilan, P.O. Box 41335-1914, Rasht, Iran

    Manouchehr Mamaghani

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  1. Manouchehr Mamaghani
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  2. Fatemeh Alavi
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Correspondence to Manouchehr Mamaghani.

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Mamaghani, M., Alavi, F. An expedient and green ultrasound-promoted synthesis of fused α-pyrones from Baylis–Hillman acetates using basic ionic liquid [bdmim]OH. J IRAN CHEM SOC 12, 2161–2167 (2015). https://doi.org/10.1007/s13738-015-0693-x

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