Abstract
This study determined the mobility of sulfentrazone in soils used for reforestation (Haplic Planosol, Ultisol, Humic Cambisol, and Regolithic Neosol) in the south of Brazil. To form the soil columns, previously prepared PVC tubes (10-cm diameter and 50-cm long) were filled with soil samples. Sulfentrazone was applied on top of the columns, which contained soil with moisture close to the field capacity. Subsequently, simulated 60-mm rainfall was applied to the columns. After draining the water, the columns were opened, and soil samples of each segment of 5.0 cm of the columns were taken for analysis of sulfentrazone by high-performance liquid chromatography. The herbicide was extracted from the soils by the solid–liquid extraction method with low temperature partition (SLE-LTP), which was adapted and validated. Sulfentrazone showed high mobility in the four soils analyzed, but presented lower mobility in the Humic Cambisol due to its lower rate of desorption. In this soil, the herbicide remained in the upper layers of the column, while in the other soils the herbicide was distributed throughout the columns. The soil that held the highest concentration of the compound in the first two segments of the column (0–5 and 5–10 cm) was the one with the highest clay content. Thus, it was concluded that the sulfentrazone leaching process in the soils analyzed is dependent on the chemical and physical characteristics of the soils, particularly, the contents of clay, sand, and organic matter.
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References
ABRAF—Associação Brasileira de Produtores de Florestas Plantadas (2013) Statistical Yearbook ABRAF—Base year (2012). http://www.abraflor.org.br. Accessed 18 Dec 2013
ANVISA—Agência Nacional de Vigilância Sanitária (2003) Resolution—RE no. 899
Costa AIG, Queiroz MERL, Neves AA, Assis RC, Soares CES, Silva AA, D’Antonino L, Oliveira AF, Bellato CR (2014) Mobility and persistence of the herbicide fomesafen in soils cultivated with bean plants using SLE/LTP and HPLC/DAD. Environ Sci Pollut Res. doi:10.1007/s11356-014-3557-5
De Paula RT (2007) Atrazine and ametryn mobility in Red-Yellow Latosol. Dissertation, Universidade Federal de Viçosa
EMBRAPA—Centro Nacional de Pesquisa de Solos (1997) Manual methods of soil analysis. Rio de Janeiro: EMBRAPA
Goulart SM, Queiroz MELR, Neves AA, Queiroz JH (2008) Low-temperature clean-up method for the determination of pyrethroids in milk using gas chromatography with electron capture detection. Talanta 75:1320–1323
Grey TL, Walker RH, Wehtje GR, Hancock HG (1997) Sulfentrazone adsorption and mobility as affected by soil and pH. Weed Sci 45:733–738
Grey TL, Walker RH, Wehtje GR, Adams J, Dayan FE, Weete JD, Hancock HG, Kwon O (2000) Behavior of sulfentrazone in ionic exchange resins, electrophoresis gels and cation-saturated soils. Weed Sci 48:239–247
INMETRO—Instituto Nacional de Metrologia, Normalização e Qualidade Industrial (2003) Guidelines on validation of methods for chemical testing, DOQ-CGCRE-008
Melo CAD, Medeiros WN, Tuffi Santos LD, Ferreira FA, Tibúrcio RAS, Ferreira LR (2010) Leaching of sulfentrazone, isoxaflutole and oxyfluorfen in three soil profiles. Planta Daninha 28:385–392
Monquero PA, Silva PV, Silva Hirata AC, Tablas DC, Orzari I (2010) Leaching and persistence of sulfentrazone and imazapic. Planta Daninha 28:185–195
Ohmes GA, Mueller TC (2007) Sulfentrazone adsorption and mobility in surface soil of the southern United States. Weed Technol 21:796–800
Oliveira RS Jr, Koskinen WC, Ferreira FA (2001) Sorption and leaching potential of herbicides on Brazilian soils. Weed Res 41:97–110
Passos ABRJ, Freitas MAM, Torres LG, Silva AA, Queiroz MELR, Lima CF (2013) Sorption and desorption of sulfentrazone in Brazilian soils. J Environ Sci Health Part B 48:646–650
Ribani M, Bottoli CBG, Collins CH, Jardim ICSF, Melo LFC (2004) Validation for chromatographic and electrophoretic methods. Quim Nova 27:771–780
Rossi CVS, Alves PLCA, Marques Júnior J (2003) Mobility of Sulfentrazone in Red Nitosol and Quartzarenic Neosol. Planta Daninha 21:111–120
Rossi CVS, Dias TCS, Alaves PLCA, Marques Júnior J (2007) Liming effects on sulfentrazone availability in the profile of a Dusky Red Latosol and a Red Nitosol. Científica 35:106–114
Silva AA, Vivian R, Oliveira RS Jr (2007) Herbicides: behaviour in soil. In: Silva AA, Silva JF (eds) Topics in weed management. Editora UFV, Viçosa, pp 189–248
Souza AP, Prates HT, Ferreira FA, Reis EL, Jordão CP (1999) Glyphosate and imazapyr leaching in soils with different textures and chemical composition: II. Analytical method. Planta Daninha 17:245–262
Vieira HP, Neves AA, Queiroz MELR (2007) Optimization and validation of liquid-liquid extraction with the low temperature partition technique (LLE-LTP) for pyrethroids in water and GC analysis. Quim Nova 30:535–540
Vivian R, Reis MR, Jakelaitis A, Silva AF, Guimarães AA, Santos JB, Silva AA (2006) Persistence and residual effect of sulfentrazone on Typic Hapludalf with sugar-cane. Planta Daninha 24:741–750
Vivian R, Queiroz MERL, Jakelaitis A, Guimarães AA, Reis MR, Carneiro PM, Silva AA (2007) Persistence and leaching of ametryn and trifloxysulfuron-sodium on sugar-cane soil. Planta Daninha 25:111–124
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This work was supported by Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES), and the Fundação de Amparo à Pesquisa do estado de Minas Gerais (FAPEMIG).
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Passos, A.B.R.J., Freitas, M.A.M., Gonçalves, V.A. et al. Leaching of sulfentrazone in soils of reforestation in Brazil. Environ Earth Sci 74, 1211–1215 (2015). https://doi.org/10.1007/s12665-015-4110-7
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DOI: https://doi.org/10.1007/s12665-015-4110-7