Skip to main content

Advertisement

Log in

Morphology, crystal structure and hydration of calcined and modified anhydrite

  • Published:
International Journal of Minerals, Metallurgy, and Materials Aims and scope Submit manuscript

Abstract

The effects of calcination and modification on the morphology (shapes and textures) and crystal structure of anhydrite powders were studied. The results show that, calcination at 100°C causes anhydrite to disintegrate into smaller crystals, accompanied by a slight increase in d-spacing. Without calcination and modification, the solidification time and curing time of anhydrite are 15 and 77 h, respectively. After the treatment, however, the solidification time and curing time are shortened significantly to 9.5 and 14 min, respectively. The compressive and flexural strengths of hydration products made from the treated anhydrite reach 10.2 and 2.0 MPa, respectively. The much shorter solidification and curing time make it possible to use anhydrite as a building and construction material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H.L. Luo, J.C. Chen, X.Q. Li, and X.Y. Zheng, Study on composite modification, Shandong Build. Mater., 24(2003), No. 4, p. 45.

    Google Scholar 

  2. J.H. Peng, J.X. Zhang, L. Bai, and Q. Li, Hydration and hardening characteristics of anhydrite binder modified with slag, J. Tongji Univ. Nat. Sci., 37(2009), No. 7, p. 934.

    Google Scholar 

  3. K. Ohenoja, J. Saari, M. Illikainen, and J. Niinimaki, Effect of the molecular structure of polymer dispersants on limestone suspension properties in fine grinding, J. Chem. Chem. Eng., 7(2013), p. 606.

    Google Scholar 

  4. X.Y. Yang, S.B. Mu, and K.G. Qin, Effect of grinding method on activity of anhydrite, Bull. Chin. Ceram. Soc., 23(2004), No.1, p. 50.

    Google Scholar 

  5. J.X. Zhang, J.H. Peng, J. Dong, L. Bai, and J.D. Qu, Study on anhydrite activated by grinding and aid-grinding/dispersive action of water reducing agent, Non Metall. Mines, 31(2008), No. 6, p. 30.

    Google Scholar 

  6. X.Y. Yang, S.Z. Yang, and W.Y. Chen, Study on the solubility and the structure of calcined anhydrite, J. Wuhan. Univ. Technol., 22(2000), No. 2, p. 21.

    Google Scholar 

  7. Y.L. Fu, B. Li, and P. Cui, Research on the technology of uniting calcining with acid-leaching for anhydrite, Appl. Chem. Ind., 41(2012), No. 1, p. 16.

    Google Scholar 

  8. Q.X. Pan, Mechanism of the activation of fly ash by calcined anhydrite, New Build. Mater., 2001, No. 12, p. 9.

    Google Scholar 

  9. J.H. Peng, J. Dong, J.X. Zhang, L. Bai, and T.Z. Wan, Dissolution and hydration performance of calcined anhydrite and its calcination activation mechanism, J. Build. Mater., 13(2010), No. 1, p. 111.

    Google Scholar 

  10. F.X. Wang, The influence of calcination temperature on the activity of anhydrite, Sichuan Water Conservancy, 2010, No. 5, p. 44.

    Google Scholar 

  11. H.X. Zhai, F.Q. Chen, and X.H. Zhang, The influence of the activator on the hydration property of natural anhydrite, Acta Petrol. Mineral., 30(2011), No. 2, p. 301.

    Google Scholar 

  12. J.H. Peng, G.H. Zhang, L. Bai, J.X. Zhang, and J.D. Qu, Study on anhydrite binder activated by sulfate salt and modified with slag, Bull. Chin. Ceram. Soc., 27(2008), No. 4, p. 837.

    Google Scholar 

  13. J.C. Chen and H.L. Luo, Properties of anhydrite modified at different conditions, J. Chin. Ceram. Soc., 33(2005), No. 2, p. 249.

    Google Scholar 

  14. M. Yang, J.X. Cao, and Y. Xie, Activation of anhydrite: II. Phosphogypsum by hemihydrate, J. Wuhan Univ. Technol., 82(2010), No. 18, p. 63.

    Google Scholar 

  15. Y.H. Huang, Impact of water on physical and mechanical characteristics of anhydrite, Min. Technol., 8(2008), No. 6, p. 31.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiao-qing Niu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Niu, Xq., Chen, Jc. Morphology, crystal structure and hydration of calcined and modified anhydrite. Int J Miner Metall Mater 21, 1028–1032 (2014). https://doi.org/10.1007/s12613-014-1004-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-014-1004-8

Keywords

Navigation