Abstract
This study examined the adhesive bond strength and thermal performance of the anodized aluminum 6061 in phosphoric acid electrolyte to improve the adhesive bond strength and thermal performance for use in metal core printed circuit boards (MCPCB). The electrolyte temperature and applied voltage were altered to generate varied pore structures. The thickness, porosity and pore diameter of the anodized layer were measured. The pore morphologies were affected most by temperature, which was the driving force for ion transportation. The mechanism of adhesive bond was penetration of the epoxy into the pores. The optimal anodization conditions for maximum adhesive bond strength, 27 MPa, were 293 K and 100V. The maximum thermal conductivity of the epoxy-treated anodized layer was 1.6 W/m·K at 273 K. Compared with the epoxy-treated Al layer used for conventional MCPCBs, the epoxy-treated anodized layer showed advanced thermal performance due to a low difference of thermal resistance and high heat dissipation.
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E. Juntunen, A. Sitomaniemi, O. Tapaninen, R. Persons, M. Challingsworth, and V. Heikkinen, IEEE. T. Compon. Pack. Man. 2, 1957 (2012).
E. Juntunen, O. Tapaninen, A. Sitomaniemi, M. Jamsa, V. Heikkinen, M. Karppinen, and P. Karioja, IEEE. T. Power. Electr. 29, 1410 (2014).
H.-M. Cho and H. Joon Kim, IEEE. Electr. Device. L. 29, 991 (2008).
J.-P. K. Y.-W. Kim, J.-B. Kim, M.-S. Kim, J.-M. Sim, S.-B. Song, and N. Hwang, J. Korean. Phys. Soc. 54, 1873 (2009).
W. K. C. Yung, J. HKPCA. Q2, 12 (2007).
L. Z. Feiyue Li, Robert M. Metzger, J. Am. Chem. Soc. 10, 2470 (1998).
M. Miyagi, Y. Hiratani, T. Taniguchi, and S. Nishida, OAS. 26, 970 (1987).
M. A. Páez, T. M. Foong, C. T. Ni, G. E. Thompson, K. Shimizu, H. Habazaki, P. Skeldon, and G. C. Wood, Corros. Sci. 38, 59 (1996).
K.-J. Heo, J.-S. Eom, and S.-J. Kim, Korean J. Met. Mater. 53, 655 (2015).
Y. K. Kim, I. S. Park, S. J. Lee, and M. H. Lee, Met. Mater. Int. 19, 353 (2013).
B.-Y. Jeong and E. H. Jung, Met. Mater. Int. 19, 617 (2013).
S. J. Garcia-Vergara, P. Skeldon, G. E. Thompson, and H. Habazaki, Electrochim. Acta. 52, 681 (2006).
G. E. Thompson, Thin Solid Films. 297, 192 (1997).
T. P. Hoar and N. F. Mott, J. Phys. Chem. Solids. 9, 97 (1959).
S. Mohagheghi, A. Hatefi, and A. Kianvash, Surf. Eng. 29, 737 (2013).
D. E. Packham, K. Bright, and B. W. Malpass, J. Appl. Polym. Sci. 18, 3237 (1974).
A. Belwalkar, E. Grasing, W. Van Geertruyden, Z. Huang, and W. Z. Misiolek, J. Membrane. Sci. 319, 192 (2008).
J.-C. K. Woo Lee, and Ulrich Gösele, Adv. Funct. Mater. 40, 21 (2010).
L. Zaraska, G. D. Sulka, and M. Jaskula, Surf. Coat. Tech. 204, 1729 (2010).
J. Lee, Y. Kim, U. Jung, and W. Chung, Mater. Chem. Phys. 141, 680 (2013).
P. Skeldon, K. Shimizu, G. E. Thompson, and G. C. Wood, Thin Solid Films 123, 127 (1985).
Y. Xu, G. E. Thompson, G. C. Wood, and B. Bethune, Corros. Sci. 27, 83 (1987).
L. I.-R. S. J. Garcia-Vergara, C. E. Blanco-Pinzon, P. Skeldon, G. E. Thompson, and P. Campestrini, P. Roy. Soc. A-Math. Phy. 462, 2345 (2006).
S. Z. Chu, K. Wada, S. Inoue, and S. Todoroki, Surf. Coat. Tech. 169-170, 190 (2003).
A. O. Araoyinbo, M. N. Ahmad Fauzi, S. Sreekantan, and A. Aziz, J. Non-Cryst. Solids. 356, 1057 (2010).
N. F. M. N. Cabrera, Rep. Prog. Phys. 12, 163 (1948-1949).
J.-S. Zhang, X.-H. Zhao, Y. Zuo, and J.-P. Xiong, Surf. Coat. Tech. 202, 3149 (2008).
R. P. Digby and D. E. Packham, Int. J. Adhes. Adhes. 15, 61 (1995).
O. Lunder, B. Olsen, and K. Nisancioglu, Int. J. Adhes. Adhes. 22, 143 (2002).
P. Chowdhury, A. N. Thomas, M. Sharma, and H. C. Barshilia, Electrochim. Acta. 115, 657 (2014).
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Lee, S., Kim, D., Kim, Y. et al. Effect of aluminum anodizing in phosphoric acid electrolyte on adhesion strength and thermal performance. Met. Mater. Int. 22, 20–25 (2016). https://doi.org/10.1007/s12540-015-5426-2
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DOI: https://doi.org/10.1007/s12540-015-5426-2