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The investigation of cooperative binding between p-sulfonatocalix[6]arene and fluorescein with transition metal ions by spectrometrically

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Abstract

The ternary complexes are formed by self-assembly through cooperative hydrogen bonding between p-SCX6-FL and M2+ through water molecule which is reinforced by columbic and electrostatic interactions. The binding efficiency of Cu2+ and Zn2+ is observed at a greater extent than Co2+ and Ni2+. Furthermore, the kinetic study of p-SCX6-FL-Cu2+ and Zn2+ reveals that the process of complexation is slower than the binary system (FL+p-SCX6).

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Synopsis. Herein we report the systematic complexation study of ternary model i.e., p-SCX6-FL-M2+ by IR, NMR and UV-Visible and florescence technique.

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Acknowledgement

We thank the University Grants Commission, New Delhi for financial support. We also thank Central Instrumentation Facility, Savitribai Phule Pune University for NMR analysis.

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Authors and Affiliations

  1. Department of First year Engineering, PICT, Pune, 411 043, Maharashtra, India

    Sharadchandra Gawhale

  2. Department of Chemistry, R A Arts Shri M K Commerce and Shri S R Rathi Science College, Washim, 444 505, Maharashtra, India

    Nilesh Rathod

  3. Department of Chemical Tech, SGB Amravati University, Amravati, 444 602, Maharashtra, India

    Rajesh Sapkal & Vilas Sapkal

  4. Department of Chemistry, Shri Shivaji Science College, Amravati, 444 603, Maharashtra, India

    Gajanan Chaudhari

  5. Department of Chemistry, Savitribai Phule Pune University, Pune, 411 007, Maharashtra, India

    Sanhita Patil, Rupali Thorave, Vrashali Kalyani & Dipalee Malkhede

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  1. Sharadchandra Gawhale
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  2. Nilesh Rathod
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  3. Sanhita Patil
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Correspondence to Gajanan Chaudhari or Dipalee Malkhede.

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Gawhale, S., Rathod, N., Patil, S. et al. The investigation of cooperative binding between p-sulfonatocalix[6]arene and fluorescein with transition metal ions by spectrometrically. J Chem Sci 132, 16 (2020). https://doi.org/10.1007/s12039-019-1717-3

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  • DOI: https://doi.org/10.1007/s12039-019-1717-3

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