Abstract
The technique of nanoindentation coupled with an atomic force microscope has been used to measure mechanical properties of Cu-Sn and Ag-Sn intermetallics at length scales similar to those observed in real solder joints. This article describes the experiment and discusses the results in terms of the effect of intermetallics on the reliability of microelectronic packages. The results show that, despite their high hardness, the intermetallics deform plastically without cracking at the small loads and length scales of nanoindentation testing.
Similar content being viewed by others
References
D.W. Henderson et al., “Ag3Sn Plate Formation in the Solidification of Near Ternary Eutectic Sn-Ag-Cu Alloys,” J. Mater. Res., 17 (2002), p. 2775.
T.Y. Lee et al., “Morphology, Kinetics, and Thermodynamics of Solid-State Aging of Eutectic SnPb and Pb-free Solders (Sn-3.5Ag, Sn-3.8Ag-0.7Cu and Sn-0.7Cu) on Cu,” J. Mater. Res., 17 (2002), p. 291.
K.S. Kim, S.H. Huh, and K. Suganuma, “Effects of Cooling Speed on Microstructure and Tensile Properties of Sn-Ag-Cu Alloys,” Mater. Sci. Eng. A, 333 (2002), p. 106.
S.A. Langer, E.R. Fuller, Jr., and W.C. Carter, “OOF: An Image-Based Finite-Element Analysis of Material Microstructures,” Comput. Sci. Eng., 3 (2001), p. 15.
N. Chawla et al., “Microstructure-Based Simulation of Thermomechanical Behavior of Composite Materials by Object Oriented (OOF) Finite Element Analysis,” Submitted to Materials Characterization (2003).
D.T. Vonk et al., “Object Oriented Finite Element Analysis of Composite Microstructures” (Paper presented to OOF Workshop, NIST, Gaithersburg, MD, 21–22 June 2001).
J.L. Marshall, L. Ann Foster, and J.A. Sees, “Interfaces and Intermetallics,” The Mechanics of Solder Alloy Interconnects, ed. D. Frear et al. (New York: ITP, 1994), pp. 42–86.
R.J. Fields, S.R. Low III, and G.K. Lucey, Jr., “Physical and Mechanical Properties of Intermetallic Compounds Commonly Found in Solder Joints,” The Metal Science of Joining, ed. M.J. Cieslak et al. (Warrendale, PA: TMS, 1991), pp. 165–174.
L.M. Ostrovskaya, V.N. Rodin, and A.I. Kuznetsov, “Elastic Properties of Intermetallic Compounds Produced by Vacuum Deposition,” Soviet J. of Non-Ferrous Metallurgy (TSVETNYE METALLY), 26 (1985), p. 90.
B. Subrahmanyan, “Elastic Moduli of Some Complicated Binary Alloy Systems,” Trans. Jpn. Inst. Metals, 130 (1972), p. 93.
R. Cabaret, L. Guillet, and R. LeRoux, “The Elastic Properties of Metallic Alloys,” J. Inst. Metals, 75 (1949), p. 391.
L. Revay, “Interdiffusion and Formation of Intermetallic Compounds in Tin-Copper Alloy Surface Coatings,” Surface Technology, 5 (1977), p. 57.
B. Bhushan et al., “Nanoindentation and Picoindentation Measurements Using a Capacitive Transducer System in Atomic Force Microscopy,” Phil. Mag. A, 74 (1996), p. 1117.
W.C. Oliver and G.M. Pharr, “An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments,” J. Mater. Res., 7 (1992), p. 1564.
A.C. Fischer-Cripps, Nanoindentation (New York: Springer-Verlag, 2002).
J.P. Lucas et al., “Nanoindentation Characterization of Microphases in Sn-3.5Ag Eutectic Solder Joints,” Fundamentals of Nanoindentation and Nanotribology, Proc. 522, ed. B.N. Lucas, W.C. Oliver, and J.E. Swindeman (Warrendale, PA: Mater. Res. Soc., 1998), pp. 339–345.
T.Y. Tsui, J. Vlassak, and W.D. Nix “Indentation Plastic Displacement Field: Part I. The Case of Soft Films on Hard Substrates,” J. Mater. Res., 14 (1999), p. 2196.
T.Y. Tsui, J. Vlassak, and W.D. Nix, “Indentation Plastic Displacement Field: Part II. The Case of Hard Films on Soft Substrates,” J. Mater. Res., 14 (1999), p. 2204.
R.R. Chromik and E.J. Cotts, “Thermodynamic and Kinetic Study of Phase Transformations in Solder/Metal Systems,” Electronic Packaging Materials Science IX, Proc. 445, ed. S.K. Groothuis et al. (Warrendale, PA: Mater. Res. Soc., 1997), pp. 31–36.
W.K. Warburton and D. Turnbull, “Fast Diffusion in Alloys,” Thin Solid Films, 25 (1975), p. 71.
D. Lewis et al., “Determination of the Eutectic Structure in the Ag-Cu-Sn System,” J. Electron. Mater., 31 (2002), p. 161.
R.R. Chromik et al., “Investigation of the Mechanical Properties of Pb-free Solder Joints by Nanoindentation,” Proc. SMTA International (Edina, MN: SMTA, 2002), p. 786.
R.R. Chromik et al., “Nanoindentation Measurements on Cu-Sn and Ag-Sn Intermetallics Formed in Pb-free Solder Joints,” Submitted to J. Mater. Res. (March 2003).
A. Bolshakov and G.M. Pharr, “Influences of Pileup on the Measurement of Mechanical Properties by Load and Depth Sensing Indentation,” J. Mater. Res., 13 (1998), p. 1049.
D. Tabor, The Hardness of Metals (Oxford, U.K.: Oxford University Press, 1951), pp. 67–83.
P.T. Vianco, J.A. Rejent, and A.C. Kilgo, “Time-Independent Mechanical and Physical Properties of the Ternary 95.5Sn-3.9Ag-0.6Cu Solder,” J. Electron. Mater., 32 (2003), p. 142.
F.A. Stam and E. Davitt, “Effects of Thermomechanical Cycling on Lead and Lead-Free (SnPb and SnAgCu) Surface Mount Solder Joint,” Microelectronics Reliability, 41 (2001), p. 1815.
M.R. Harrison, J.H. Vincent, and H.A.H. Steen, “Lead-Free Reflow Soldering for Electronics Assembly,” Soldering & Surface Mount Technology, 13 (2001), p. 21.
G. Ghosh, “Phase Stability and Elastic Properties of Intermetallics Relevant to Electronics Packaging” (Paper presented at TMS Annual Meeting, San Diego, CA, 2–6 March 2003).
Author information
Authors and Affiliations
Additional information
For more information, contact Richard R. Chromik, Lehigh University, Materials Research Center, 5 East Packer Avenue, Bethlehem, Pennsylvania 18015; (610) 758-6879, fax (610) 758-3526, email chromik@lehigh.edu.
Rights and permissions
About this article
Cite this article
Chromik, R.R., Vinci, R.P., Allen, S.L. et al. Measuring the mechanical properties of Pb-free solder and Sn-based intermetallics by nanoindentation. JOM 55, 66–69 (2003). https://doi.org/10.1007/s11837-003-0144-5
Issue Date:
DOI: https://doi.org/10.1007/s11837-003-0144-5