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Analytical study of rhenium complexes with pyrogallol and catechol

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Abstract

Selected rhenium complexes with pyrogallol (1,2,3-trihydroxybenzene) and catechol (1,2-dihydroxybenzene) as strongly bound ligands were prepared by a reaction of rhenium precursor tetrabutylammonium-tetrachlorooxorhenate with twofold molar excess of ligand in presence of various amounts of triethylamine. The structures of formed complexes and their consequent reaction products were estimated by means of mass spectrometry with electrospray ionization. The kinetics of reactions in course of complex formation and consequent decomposition were primarily followed by UV–Vis absorption spectra measurement, complemented by single or continuous electrospray mass spectrometry analyses.

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Abbreviations

SI:

Similarity index

PG:

Pyrogallol

Cat:

Catechol

Re:

Rhenium

O:

Oxygen

Cl:

Chlorine

Bu:

Butyl

ESI-MS:

Mass spectrometry with electrospray ionization

TEA:

Triethylamine

UV–vis:

Ultraviolet–visible absorption spectrometry

EIC:

Extracted ion current

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Acknowledgements

This research was carried out within the framework of the project of the Specific University Research (SVV 260317). The Norwegian Financial Mechanism project CZ01116 is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Charles University in Prague, Hlavova 8, 128 43, Prague 2, Czech Republic

    Martin Štícha & Jana Poláková

  2. Department of Analytical Chemistry, Faculty of Science, Charles University in Prague, Hlavova 8, 128 43, Prague 2, Czech Republic

    David Kaliba & Ivan Jelínek

Authors
  1. Martin Štícha
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  2. David Kaliba
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  3. Ivan Jelínek
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  4. Jana Poláková
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Correspondence to Martin Štícha.

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Štícha, M., Kaliba, D., Jelínek, I. et al. Analytical study of rhenium complexes with pyrogallol and catechol. Chem. Pap. 71, 819–830 (2017). https://doi.org/10.1007/s11696-016-0088-1

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  • DOI: https://doi.org/10.1007/s11696-016-0088-1

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