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Enrichment characteristics and sources of the critical metal yttrium in Zhijin rare earth-containing phosphorites, Guizhou Province, China

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Abstract

Yttrium (Y) is a critical metallic element that is used widely in modern scientific, technological, and industrial applications. Phosphorites in the Zhijin area of Guizhou Province, China, are famous for Y enrichment, but the enrichment characteristics and sources remain unclear. Previous studies suggested that the sources of rare earth elements (REEs, La–Lu) and Y (REYs, La–Lu+Y) were related to hydrothermal deposition. However, this study presents evidence refuting that hypothesis, with major and trace elemental data collected with quadrupole–inductively coupled plasma–mass spectrometry (Q–ICP–MS) analysis. These data show that Y in Zhijin REYs-containing phosphorites has a normal distribution and is particularly enriched relative to other REYs. The Y enrichment degree is different at different ∑REY intervals. Specifically, the Y enrichment degree is higher at lower ∑REY values and lower at higher ∑REY values. The REYs-containing phosphorites show features of primary phosphorites. Both REEs and Y have good correlations with P2O5 in the phosphorites with low REYs contents (total REYs < 535 ppm), whereas at high REYs contents (total REYs ≥ 535 ppm), REEs have a good correlation with P2O5 but Y does not. Inconsistent enrichment processes of REYs are suggestive of complex sources of Y. Thus, seafloor hydrothermal fluids were not the direct source of Y. Normal seawater mixed with terrestrial sources might have contributed to the origin of Y here. This study could lead to improvements in Y mineral resource explorations and the situation involving the global REYs supply crisis.

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References

  • Abedini A, Calagari AA (2017) REEs geochemical characteristics of lower Cambrian phosphatic rocks in the Gorgan-Rasht Zone, northern Iran: Implications for diagenetic effects and depositional conditions. J Afr Earth Sci 135:115–124

    Article  Google Scholar 

  • Adachi M, Yamamoto K, Sugisaki R (1986)Hydrothermal chert and associated siliceous rocks from the northern Pacific their geological significance as indication of ocean ridge activity. Sediment Geol 47:125–148

  • Bau M, Dulski P (1996) Distribution of yttrium and rare-earth elements in the Penge and Kuruman iron-formations, Transvaal Supergroup, South Africa. Precambrian Res 79:37–55

    Article  Google Scholar 

  • Bau M, Möller P, Dulski P (1997)Yttrium and lanthanides in eastern Mediterranean seawater and their fractionation during redox-cycling. Mar Chem 56:123–131

  • Bau M, Dulski P (1999) Comparing yttrium and rare earths in hydrothermal fluids from the Mid-Atlantic Ridge: implications for Y and REE behaviour during near-vent mixing and for the Y/Ho ration of Proterpozoic seawater. Chem Geol 155:77–90

    Article  Google Scholar 

  • Borkowski M, Siekierski S (1992)Factors affecting the position of Y and actinides (III) with respect to lanthanides in the NH4SCN-Adogen-564SCN extraction system. Radiochim Acta 56:31–35

  • Chen JY, Yang RD, Wei HR, Gao JB (2013) Rare earth element geochemistry of Cambrian phosphorites from the Yangtze Region. J Rare Earths 31:101–112

    Article  Google Scholar 

  • Chen JY (2019) Study on the occurrence state of rare earth element yttrium in Zhijin phosphate deposit-bearing rare earth based on synchrotron radiation XAFS experiment. Proc 17th Ann Conf Chin Soc Mineral Petrol Geochem 2:208–209 (in Chinese)

  • Chew DM, Babechuk MG, Cogné N et al (2016) (LA, Q)-ICPMS trace-element analyses of Durango and McClure Mountain apatite and implications for making natural LA-ICPMS mineral standards. Chem Geol 435:35–48

    Article  Google Scholar 

  • Douville E, Bienvenu P, Charlou JL, Donval JP, Fouquet Y, Appriou P, Gamo T (1999) Yttrium and rare earth elements in fluids from various deep-sea hydrothermal systems. Geochimica et Cosmochimica Acta 63:627–643

  • Duan KB, Wang DH, He HJ, Zheng GD, Xiong XX, Yuan JG, He BB, Qu YY (2015) Study on geochemical characteristics of rare earth elements of xinhua phosphate rocks in the Upper Yangtze, South China by ICP-MS/AES and Its Sedimentology Implications. Rock and Mineral Analysis 34:261–267 (in Chinese with English abstract)

    Google Scholar 

  • Fazio AM, Scasso RA, Castro LN, Carey S (2007) Geochemistry of rare earth elements in early-diagenetic Miocene phosphatic concretions of Patagonia, Argentina:phosphogenetic implications.Deep Sea Res. Part II 54:1414–1432

    Google Scholar 

  • Ge DY, Liu YX, Zeng YF (1994) A discussion on weathering indexes of phosphorus ore from eastern Yunnan and the weathering process of phosphorite. J Mineral Petrol 14:29–42 (in Chinese with English abstract)

    Google Scholar 

  • George D, Mallery P (2019) IBM SPSS statistics 26 step by step: a simple guide and reference. Routledge, London

  • Guo HY (2017) Geological Features and REE Ore-controlling Factors of Xinhua Phosphorite Type Rare-earth Deposit. Guiyang, Guizhou Province. Institute of Geochemistry, Chinese Academy of Sciences, Guizhou Province (in Chinese with English abstract)

    Google Scholar 

  • Guo HY, Xia Y, He S, Xie ZJ, Wei DT, Lei B (2017) Geochemical Characteristics of Zhijin Phosphorite Type Rare-earth Deposit, Guizhou Province, China. Acta Mineral Sin 37:755–763 (in Chinese with English abstract)

    Google Scholar 

  • Hein JR, Perkins RB, McIntyre BR (2004)Chapter 2 Evolution of thought concerning the origin of the phosphoria formation, western US phosphate field. Handbook Explor Environ Geochem 8:19–42

  • Hein JR, Koschinsky A, Mikesell M, Mizell K, Glenn CR, Wood R (2016) Marine phosphorites as potential resources for heavy rare earth elements and Yttrium. Minerals 6:1–22

    Article  Google Scholar 

  • Hekinian R, Fouquet Y (1985) Volcanism and metallogenesis of axial and off-axial structures on the East Pacific Rise near 13°N. Econ Geol 80:221–249

    Article  Google Scholar 

  • Ilyin AV (1998) Rare-earth geochemistry of ‘old’ phosphorites and probability of syngenetic precipitation and accumulation of phosphate. Chem Geol 144:243–256

    Article  Google Scholar 

  • Jiang XD, Sun XM, Chou YM, et al (2020)Geochemistry and origins of carbonate fluorapatite in seamount Fe-Mn crusts from the Pacific Ocean. Marine Geology 423

  • Li LY, Li L, Zhao ZX, Li XK (2008) The basic trellis and its characters of the geologic structure in Zhijin. Guizhou Geology 25:35–40 (in Chinese with English abstract)

    Google Scholar 

  • Marchig V, Gundlach H, Möller P, Schley F (1982) Some geochemical indicators for discrimination between diagenetic and hydrothermal metalliferous sediments. Mar Geol 50:241–256

    Article  Google Scholar 

  • Mao T, Yang RD, Gao JB, Mao JR (2015) Study of sedimentary feature of Cambrian phosphorite and ore-controlling feature of old karst surface of the Dengying formation in Zhijin. Guizhou Acta Geol Sin 89:2374–2388 (in Chinese with English abstract)

    Google Scholar 

  • McArthur JM, Coleman ML, Bremner JM (1980) Carbon and oxygen isotopic composition of structural carbonate in sedimentary francolite. J Geol Soc London 137:669–673

    Article  Google Scholar 

  • McArthur JM, Walsh JN (1984) Rare-earth geochemistry of phosphorites. Chem Geol 47:191–220

    Article  Google Scholar 

  • McArthur JM, Benmore RA, Coleman ML, Soldi C, Yeh HW, O’Brien GW (1986) Stable isotopic characterisation of francolite formation.Earth Planet. Sci Lett 77:20–34

    Google Scholar 

  • McLennan SM (1989)Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. Rev Mineral Geochem 21:169–200

  • Meng QT, et al. (2016) Complete exploration report of phosphorite (rare earth) ore in Zhijin area, Guizhou province. Guizhou Guiyang: 104 Geological Brigade of Bureau of Geology and Mineral Exploration and Development of Guizhou Province (in Chinese)

  • Morad S, Felitsyn S (2001)Identification of primary Ce-anomaly signatures in fossil biogenic apatite: implication for the Cambrian oceanic anoxia and phosphogenesis. Sediment Geol 143:259–264

  • Nozaki Y, Zhang J, Amakawa H (1997) The fractionation between Y and Ho in the marine environment. Earth Planet. Sci Lett 148:329–340

    Google Scholar 

  • Emsbo P, McLaughlin PI, Breit GN, du Bray EA, Koenig AE (2015) Rare earth elements in sedimentary phosphate deposits: solution to the global REE crisis? Gondwana Res 27:776–785

    Article  Google Scholar 

  • Quinn KA, Byrne RH, Schijf J (2004) Comparative scavenging of yttrium and the rare earth elements in seawater: competitive influences of solution and surface chemistry. Aquat Geochem 10:59–80

    Article  Google Scholar 

  • Shields G, Stille P (2001) Diagenetic constraints on the use of cerium anomalies as palaeoseawater redox proxies: an isotopic and REE study of Cambrian phosphorites. Chem Geol 175:29–48

    Article  Google Scholar 

  • Siekierski S (1981) The position of yttrium within lanthanides with respect to unit cell volumes of isostructural compounds as an indication of covalency in lanthanide compounds. J Solid State Chem 37(3):279–283

    Article  Google Scholar 

  • Stine RA (2016) Explaining Normal Quantile-Quantile Plots Through Animation: The Water-Filling Analogy. Am Stat 71:145–147

    Article  Google Scholar 

  • Takaya Y, Yasukawa K, Kawasaki T et al (2018) The tremendous potential of deep-sea mud as a source of rare-earth elements. Sci Rep 8:3406–3414

    Article  Google Scholar 

  • Tan QP, Wang XQ (2017) Temporal-spatial distributions of gold in drainage sediments and rocks in the Qinling region, China. Bull Mineral Petrol Geochem 36:132–141 (in Chinese with English abstract)

    Google Scholar 

  • Tan QP, Wang XQ et al. (2018) Identifying ore-related anomalies using singularity mapping of stream sediment geochemical data, a case study of Pb mineralization in the Qinling region, China. Geochem Explor Environ A 18:177–184

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell, Oxford, p. 321

  • Tian JC, Zhang X (2016) Sedimentary geochemistry. Geological Publishing House, Beijing, pp 46–47 (in Chinese)

  • Wu SW(2019)Study on REE enrichment characteristics and economic index of mineral exploration in phosphorite-type REE deposit in Zhijin, Guizhou province. Dissertation, Institute of Geochemistry, Chinese Academy of Sciences (in Chinese with English abstract)

  • Wu SW, Xia Y, Tan QP, Xu JB, Xie ZJ, Yang HY, He S (2019) The REE geochemical characteristics and REE enrichment of ore-bearing rocks of the Zhijin phosphorite-type REE deposit, Guizhou, China. Acta Mineral Sin 39:359–370 (in Chinese with English abstract)

    Google Scholar 

  • Xia Y, Xie ZJ, Zhang H, Xiao JF (2019) A report on the results of research on ore-forming rules and economic indexes of ore exploration technology and deposit exploration in Zhijin phosphorite-type rare earth ore in Guizhou Province. Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou Province (in Chinese)

    Google Scholar 

  • Xu JB (2019) The Research of the Law and Paleogeographic Environmental Constraints of Rare Earth Element Enrichment of Phosphorite-type Rare Earth Ore in Zhijin, Guizhou Province. Dissertation, Institute of Geochemistry, Chinese Academy of Sciences (in Chinese with English abstract)

  • Xu JB, Xiao JF, Yang HY, Xia Y, Wu SW, Xie ZJ (2019) The REE enrichment characteristics and constraints of the phophorite in Zhijin, Guizhou: a case study of No. 2204 drilling cores in the Motianchong ore block. Acta Mineral Sin 39:371–379 (in Chinese with English abstract)

    Google Scholar 

  • Yang WD, Qi L, Lu XY (1995) Geochemical characteristics and genesis of rare earth elements in the early Cambrian of eastern Yunnan. Acta Mineral Sin 4:224–227 (in Chinese)

    Google Scholar 

  • Yang J, He TY (2013) Zhjin county Guizhou province Xinhua containing-rare earth phosphorate rock deposit geological characteristics and reasons discussed. Geol Chem Miner 35:27–33 (in Chinese with English abstract)

    Google Scholar 

  • Yang HY (2020) A comparative study on metallogenic paleo-environments of phoshorites of the Doushantu and Gezhongwu formations in the Central Guizhou and their constrains on the enrichment of rare earth elements. Dissertation, Institute of Geochemistry, Chinese Academy of Sciences (in Chinese with English abstract)

  • Ye LJ (1963) Study on ore-forming and extracting of exogenic deposits from continental sources. Sci Geol Sin 2:67–87(in Chinese)

  • Yi HS, Peng J, Xia WJ (1995) The late precambrian paleo-ocean evolution of the southeast Yangtze continental margin: REE record. Acta Sedimentol Sin 13:131–137 (in Chinese with English abstract)

    Google Scholar 

  • Zhang J, Chen DL (2000) Scanning electron microscope study of the ore-bearing REE in Xinhua phosphorite, Zhijin, Guizhpu. J Mineral Petrol 20:59–64 (in Chinese with English abstract)

    Google Scholar 

  • Zhang J, Chen JY, Chen DL (2004) Characteristics of main material composition of phosphorite in Guizhou Province. China Non-Metallic Miner Ind 43:91–92 (in Chinese)

    Google Scholar 

  • Zhang J, Sun CM, Gong ML, Zhang Q, Chen DL, Chen JY (2007a) Geochemical characteristics and occurrence states of the REE elements of the phosphorite in Xinhua, Zhijin. Guizhou J Rare Earths 28:75–79 (in Chinese with English abstract)

    Google Scholar 

  • Zhang YB, Gong ML, Li H (2007b) Occurrence of REE in rare earth phosphorite in Zhijin area, Guizhou. J Earth Sci Environ 29:362–368 (in Chinese with English abstract)

    Google Scholar 

  • Zhang XL, Cui LH (2016) Oxygen requirements for the Cambrian explosion. J Earth Sci 27:187–195

    Article  Google Scholar 

  • Zhang KF, Liu ZQ, Sun CY, Cao HY, Zhu KC, Zhu W, Li W (2018) Recovery of yttrium from deep-sea mud.J. Rare Earths 36:863–872

    Article  Google Scholar 

Download references

Acknowledgements

We thank Prof. Jianzhong Liu for his helpful comments. This work is jointly supported by the National Natural Science Foundation of China (No. U1812402) and the Public Beneficial and Basic Geological Project from the Department of Land and Resources of Guizhou Province (No. 2016-09-1).

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Author notes

  1. Xingxiang Gong and Shengwei Wu contribute equally to this work.

Authors and Affiliations

  1. Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081, China

    Xingxiang Gong, Shengwei Wu, Yong Xia, Zhengwei Zhang, Shan He, Zhuojun Xie, Jiafei Xiao, Haiying Yang & Qingping Tan

  2. University of Chinese Academy of Sciences, Beijing, 100049, China

    Xingxiang Gong, Shengwei Wu, Yong Xia, Zhengwei Zhang, Shan He, Zhuojun Xie, Jiafei Xiao & Qingping Tan

  3. Technology Innovation Center of Mineral Resources Explorations in Bedrock Zones, Ministry of Natural Resources, Guiyang, 550081, China

    Xingxiang Gong, Yi Huang & Yuhong Yang

  4. Reserve Bureau of Land and Mineral Resources of Guizhou Province, Guiyang, 550081, China

    Xingxiang Gong, Yi Huang & Yuhong Yang

  5. School of Earth Sciences, Yunnan University, Kunming, 650500, China

    Haiying Yang

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Correspondence to Yong Xia.

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Gong, X., Wu, S., Xia, Y. et al. Enrichment characteristics and sources of the critical metal yttrium in Zhijin rare earth-containing phosphorites, Guizhou Province, China. Acta Geochim 40, 441–465 (2021). https://doi.org/10.1007/s11631-021-00460-8

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