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Phenylhydrosilocane as a source of silatranylium cations

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Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)3N]+ (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.

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References

  1. S. Lee, C. Bae, Y. Do, Y. S. Lee, Bull. Korean Chem. Soc., 2002, 23 (2), 215.

    Article  CAS  Google Scholar 

  2. S. Belyakov, L. Ignatovich, E. Lukevics, J. Organomet. Chem., 1999, 577, 205.

    Article  CAS  Google Scholar 

  3. S. S. Karlov, D. A. Turin, M. V. Zabalov, A. V. Churakov, G. S. Zaitseva, J. Mol. Struct. (TEOCHEM), 2005, 724, 31.

    Article  CAS  Google Scholar 

  4. I. S. Ignatyev, T. Sundius, T. A. Kochina, D. V. Vrazhnov, M. G. Voronkov, J. Organomet. Chem., 2007, 692, 5697.

    Article  CAS  Google Scholar 

  5. I. S. Ignatyev, M. G. Voronkov, T. A. Kochina, D. V. Vrazhnov, Russ. J. Gen. Chem. (Engl. Transl.), 2010, 80, 2274 [Zh. Obshch. Khim., 2010, 80, 1810].

    Article  Google Scholar 

  6. M. G. Voronkov, R. G. Mirskov, A. L. Kuznetsov, V. Yu. Vitkovskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1979, 28, 1708 [Izv. Akad. Nauk SSSR, Ser. Khim., 1979, 1846].

    Article  Google Scholar 

  7. M. Zeldin, J. Ochs, J. Organomet. Chem., 1975, 86, 369.

    Article  CAS  Google Scholar 

  8. T. A. Kochina, D. V. Vrazhnov, E. N. Sinotova, M. G. Voronkov, Russ. Chem. Rev. (Engl. Transl.), 2006, 75, 95 [Usp. Khim., 2006, 75, 107].

    Article  CAS  Google Scholar 

  9. A. A. Alferova, V. V. Avrorin, E. N. Sinotova, T. A. Kochina, Russ._J. Gen. Chem. (Engl. Transl.), 2012, 82, 1888 [Zh. Obshch. Khim., 2012, 82, 1925].

    Article  CAS  Google Scholar 

  10. T. A. Kochina, E. N. Sinotova, D. V. Vrazhnov, M. G. Voronkov, Russ. Chem. Bull. (Int. Ed.), 2012, 61, 984 [Izv. Akad. Nauk, Ser. Khim., 2012, 979].

    Article  CAS  Google Scholar 

  11. I. P. Urtane, G. I. Zelchan, E. Lukevics, Z. Anorg. Allg. Chem., 1985, 520, 179.

    Article  CAS  Google Scholar 

  12. E. A. Shishigin, T. A. Kochina, V. V. Avrorin, I. S. Ignatyev, E. N. Sinotova, Russ. J. Gen. Chem. (Engl. Transl.), 2005, 75, 1393 [Zh. Obshch. Khim., 2005, 75, 1465].

    Article  CAS  Google Scholar 

  13. V. V. Avrorin, G. E. Fominykh, I. S. Ignatyev, E. N. Sinotova, T. A. Kochina, Russ. J. Gen. Chem. (Engl. Transl.), 2014, 84, 2125 [Zh. Obshch. Khim., 2014, 84, 1828].

    Article  CAS  Google Scholar 

  14. I. S. Ignatyev, T. A. Kochina, V. V. Avrorin, V. V. Gurzhiy, V. S. Fundamensky, J. Mol. Struct., 2015, 169.

    Google Scholar 

  15. A. A. Selina, S. S. Karlov, G. S. Zaitseva, Chem. Heterocycl. Compd. (Engl. Transl.), 2006, 42, 1518 [Khim. Geterotsikl. Soedin., 2006, 1777].

    Article  CAS  Google Scholar 

  16. A. Korlyukov, K. Lyssenko, M. Antipov, E. Grebneva, A. Albanov, O. Trofimova, E. Zel´bst, M. Voronkov, J. Organomet. Chem., 2009, 694, 607.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 2 nab. Makarova, 199034, St. Petersburg, Russian Federation

    T. A. Kochina

  2. St. Petersburg State University, 7/9 Universitetskaya nab., 198504, St. Petersburg, Russian Federation

    V. V. Avrorin & I. S. Ignatyev

  3. St. Petersburg State Institute of Technology, Technical University, 26 Moskovskii prosp., 190013, St. Petersburg, Russian Federation

    V. S. Fundamensky

Authors
  1. T. A. Kochina
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  2. V. V. Avrorin
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  3. V. S. Fundamensky
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  4. I. S. Ignatyev
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Corresponding author

Correspondence to T. A. Kochina.

Additional information

Based on the materials of the XIII Andrianov Conference "Organosilicon Compounds: Synthesis, Properties, and Application" (June 28—July 1, 2015, Moscow).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1047—1052, April, 2016.

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Kochina, T.A., Avrorin, V.V., Fundamensky, V.S. et al. Phenylhydrosilocane as a source of silatranylium cations. Russ Chem Bull 65, 1047–1052 (2016). https://doi.org/10.1007/s11172-016-1411-2

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  • DOI: https://doi.org/10.1007/s11172-016-1411-2

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