Skip to main content
SpringerLink
Log in

Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Maleic anhydride–styrene–methyl methacrylate (MA–S–MM) terpolymer was prepared. It was modified by ethylenediamine (EDA) and diethylenetriamine (DETA) in order to get cross-linked polymers bearing carboxyl and amine groups. Modified polymers used as an adsorbent for the removal of UO2 2+ from water. The characterizations of structures of all the polymers were performed by Fourier transform infrared. The adsorptive features of adsorbents were then investigated for UO2 2+ in view of dependency on ion concentration, pH, temperature and kinetics. Experimentally obtained isotherms were evaluated with reference to Langmuir, Freundlich and Dubinin–Radushkevich models. The maximum monolayer adsorption capacity for UO2 2+ was found to be 1.59 and 2.43 mol kg−1 for EDA–MA–S–MM and DETA–MA–S–MM, respectively. It can be said that the new modified polymers prepared in our laboratory have been suggested as new adsorbents for uranyl ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Keith LS, Faroon OM, Fowler BA (2007) In: Nordberg GF, Fowler BA, Nordberg M, Friberg LT (eds) Handbook on the toxicology of metals. Academic Press, Denmark

    Google Scholar 

  2. Mohapatra PK, Manchanda VK (1998) Talanta 47:1271

    Article  CAS  Google Scholar 

  3. Renninger N, McMahon KD, Knopp R, Nitsche H, Clark DS, Keasling JD (2001) Biodegradation 12:401

    Article  CAS  Google Scholar 

  4. Kimaro A, Kelly LA, Murray GM (2005) Sep Sci Technol 40:2035

    Article  CAS  Google Scholar 

  5. Anirudhan TS, Radhakrishnan PG (2009) J Environ Radioact 100:250

    Article  CAS  Google Scholar 

  6. Chabalala S, Chirwa EMN (2010) Miner Eng 23:526

    Article  CAS  Google Scholar 

  7. Lee SY, Baik MH, Lee YJ, Lee YB (2009) Appl Clay Sci 46:255

    Article  CAS  Google Scholar 

  8. Humelnicu D, Bulgariu L, Macoveanu M (2010) J Hazard Mater 174:782

    Article  CAS  Google Scholar 

  9. Simsek S, Ulusoy U, Ceyhan O (2003) J Radioanal Nucl Chem 256:315

    Article  CAS  Google Scholar 

  10. Ulusoy U, Simsek S, Ceyhan O (2003) Adsorption 9:165

    Article  CAS  Google Scholar 

  11. Pang C, Liu YH, Cao XH, Li M, Huang GL, Hua R, Wang CX, Liu YT (2011) Chem Eng J 170:1

    Article  CAS  Google Scholar 

  12. Donia AM, Atia AA, Moussa EMM, El-Sherif AM, El-Magied MOA (2009) Hydrometallurgy 95:183

    Article  CAS  Google Scholar 

  13. Wang JS, Peng RT, Yang JH, Liu YC, Hu XJ (2011) Carbohydr Polym 84:1169

    Article  CAS  Google Scholar 

  14. Choi SH, Nho YC (2000) Radiat Phys Chem 57:187

    Article  CAS  Google Scholar 

  15. Hazer O, Kartal S (2010) Talanta 82:1974

    Article  CAS  Google Scholar 

  16. Metilda P, Gladis JM, Venkateswaran G, Rao TP (2007) Anal Chim Acta 587:263

    Article  CAS  Google Scholar 

  17. Boztug A, Basan S (2007) J Mol Struct 830:126

    Article  CAS  Google Scholar 

  18. Mullet M, Fievet P, Szymczyk A, Foissy A, Reggiani JC, Pagetti J (1999) Desalination 121:41

    Article  CAS  Google Scholar 

  19. Van der Maas JH (1972) Basic infrared spectroscopy. Heyden & Son Ltd, London

    Google Scholar 

  20. Pretsch E, Buhlmann P, Affolter C (2000) Structure determination of organic compounds tables of spectral data. Springer, New York

    Book  Google Scholar 

  21. Nguyen-Trung C, Palmer DA, Begun GM, Peiffert C, Mesmer RE (2000) J Solution Chem 29:101

    Article  CAS  Google Scholar 

  22. Gurgel LVA, Gil LF (2009) Water Res 43:4479

    Article  CAS  Google Scholar 

  23. Baybaş D, Ulusoy U (2011) J Hazard Mater 187:241

    Article  Google Scholar 

  24. Scheckel KG, Sparks DL (2001) Soil Sci Soc Am J 65:719

    Article  CAS  Google Scholar 

  25. Anirudhan TS, Suchithra PS, Radhakrishnan PG (2009) Appl Clay Sci 43:336

    Article  CAS  Google Scholar 

  26. Ho YS, McKay G (1999) Process Biochem 34:451

    Article  CAS  Google Scholar 

  27. Yun L, Xing S, Haidong C, Huixian Z, Shixiang G (2006) J Hazard Mater 137:1149

    Article  Google Scholar 

  28. Ulusoy U, Akkaya R (2009) J Hazard Mater 163:93

    Article  Google Scholar 

  29. Atun G, Ortaboy S (2009) J Appl Polym Sci 114:3793

    Article  CAS  Google Scholar 

  30. Atta AM, Abd El Wahab ZH, El Shafey ZA, Zidan WI, Akl ZF (2010) J Dispersion Sci Technol 31:1601

    Article  CAS  Google Scholar 

  31. Mun SP, Ku CS, Kim JP (2010) Wood Sci Technol 44:283

    Article  CAS  Google Scholar 

  32. Raj L, Chauhan GS (2010) Polym Bull 64:363

    Article  CAS  Google Scholar 

  33. Liu YH, Cao XH, Hua R, Wang YQ, Liu YT, Pang C, Wang Y (2010) Hydrometallurgy 104:150

    Article  CAS  Google Scholar 

  34. Kam E, Tasdelen B, Osmanlioglu AE (2012) Radiat Phys Chem 81:618

    Article  CAS  Google Scholar 

  35. Şimşek S, Ulusoy U (2012) J Radioanal Nucl Chem 292:41

    Article  Google Scholar 

  36. Chi F, Wang X, Xiong J, Hu Ş, (2012) J Radioanal Nucl Chem. doi:10.1007/s10967-012-2303-z

  37. Liu Y, Liu Y, Cao X, Hua R, Wang Y, Pang C, Hua M, Li X (2011) J Radioanal Nucl Chem 290:231

    Article  CAS  Google Scholar 

  38. Ferrah N, Abderrahim O, Didi MA, Villemin D (2011) J Radioanal Nucl Chem 289:721

    Article  CAS  Google Scholar 

  39. Zhang Z, Cao X, Liang P, Liu Y (2012) J Radioanal Nucl Chem. doi:10.1007/s10967-012-2017-2

  40. Cheng H, Zeng K, Yu J (2013) J Radioanal Nucl Chem. doi:10.1007/s10967-012-2406-6

  41. Yi Z, Yao J, Wang F, Chen H, Liu H, Yu C (2012) J Radioanal Nucl Chem. doi:10.1007/s10967-012-2277-x

  42. Li Q, Liu Y, Cao X, Pang C, Wang Y, Zhang Z, Liu Y, Hua M (2012) J Radioanal Nucl Chem 293:67

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by The Research Fund of Cumhuriyet University (Project No: F-290) to which the authors are grateful.

Author information

Authors and Affiliations

  1. Department of Chemistry, Cumhuriyet University, Sivas, Turkey

    Selçuk Şimşek & Ersen Yılmaz

  2. Faculty of Engineering, Tunceli University, Tunceli, Turkey

    Ali Boztuğ

Authors
  1. Selçuk Şimşek
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ersen Yılmaz
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ali Boztuğ
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Selçuk Şimşek.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Şimşek, S., Yılmaz, E. & Boztuğ, A. Amine-modified maleic anhydride containing terpolymers for the adsorption of uranyl ion in aqueous solutions. J Radioanal Nucl Chem 298, 923–930 (2013). https://doi.org/10.1007/s10967-013-2529-4

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-013-2529-4

Keywords

Search

Navigation