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Hydrothermal synthesis of titanosilicate type zeolitic layered PLS-1 and CDS-1 molecular sieve with CDO topology

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Abstract

The titanosilicate type CDS-1 zeolite ([Ti]CDS-1) with CDO topology can be prepared from the corresponding zeolitic layered titanosilicate [Ti]PLS-1 via dehydrative condensation of interlayers’ Q 3 silanols. The precursor [Ti]PLS-1 is successfully synthesized from the mixture of an acidified kanemite, titanium tetraisopropoxide (Ti(OiPr)4), a small amount of hydrogen peroxide (H2O2), tetramethylammonium hydroxide (TMAOH) and water (H2O) under hydrothermal synthesis. The obtained samples were characterized by powder-XRD, TG–DTA, N2 adsorption, solid state NMR and UV–Vis analyses. Further oxidation reaction of terminal alkenes was examined by using H2O2 as an oxidant.

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Acknowledgments

This work is supported by JSPS KAKENHI Grant Number 15K05586.

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Authors and Affiliations

  1. Department of Materials Science Technology, Faculty of Engineering, Gifu University, Gifu City, 501-1193, Japan

    Tomoyuki Murase & Kenichi Komura

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  1. Tomoyuki Murase
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  2. Kenichi Komura
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Correspondence to Kenichi Komura.

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Murase, T., Komura, K. Hydrothermal synthesis of titanosilicate type zeolitic layered PLS-1 and CDS-1 molecular sieve with CDO topology. J Porous Mater 24, 203–209 (2017). https://doi.org/10.1007/s10934-016-0253-5

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  • DOI: https://doi.org/10.1007/s10934-016-0253-5

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